GB928412A - Preparation of aryloxysulphur pentafluorides - Google Patents
Preparation of aryloxysulphur pentafluoridesInfo
- Publication number
- GB928412A GB928412A GB258061A GB258061A GB928412A GB 928412 A GB928412 A GB 928412A GB 258061 A GB258061 A GB 258061A GB 258061 A GB258061 A GB 258061A GB 928412 A GB928412 A GB 928412A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aryloxysulphur
- pentafluorides
- pentafluoride
- substituted
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises aryloxysulphur pentafluorides having the general formula ROSF5 wherein R represents the phenyl radical, which may be substituted, for example, by chlorine or bromine atoms. The novel compounds may be made by heating bispentafluorosulphur pentoxide with an aromatic hydrocarbon of the benzene series, which may be substituted, for example benzene, toluene, monochlorobenzene, monobromobenzene and o-xylene. The reaction may be effected in the absence of a solvent or carbon tetrachloride or trichlorofluoromethane may be used to provide a homogeneous reaction medium. The reaction takes place at a temperature between 50 DEG and 250 DEG C., under autogenous pressure. The aryloxysulphur pentafluorides can be nitrated and the nitro groups reduced to amino groups. Examples describe the preparation of phenoxysulphur pentafluoride, p-methylphenoxysulphur pentafluoride and p-chlorophenoxysulphur pentafluoride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB258061A GB928412A (en) | 1961-01-23 | 1961-01-23 | Preparation of aryloxysulphur pentafluorides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB258061A GB928412A (en) | 1961-01-23 | 1961-01-23 | Preparation of aryloxysulphur pentafluorides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB928412A true GB928412A (en) | 1963-06-12 |
Family
ID=9742079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB258061A Expired GB928412A (en) | 1961-01-23 | 1961-01-23 | Preparation of aryloxysulphur pentafluorides |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB928412A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7339081B2 (en) * | 2006-07-10 | 2008-03-04 | Air Products And Chemicals, Inc. | Route to prepare 4-bromo-1-oxypentafluorosulfanylbenzene |
-
1961
- 1961-01-23 GB GB258061A patent/GB928412A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7339081B2 (en) * | 2006-07-10 | 2008-03-04 | Air Products And Chemicals, Inc. | Route to prepare 4-bromo-1-oxypentafluorosulfanylbenzene |
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