GB921050A - New phthalocyanine dyestuffs - Google Patents

New phthalocyanine dyestuffs

Info

Publication number
GB921050A
GB921050A GB3908859A GB3908859A GB921050A GB 921050 A GB921050 A GB 921050A GB 3908859 A GB3908859 A GB 3908859A GB 3908859 A GB3908859 A GB 3908859A GB 921050 A GB921050 A GB 921050A
Authority
GB
United Kingdom
Prior art keywords
formula
exceed
dyes
phthalocyanine
dyestuffs
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3908859A
Inventor
Peter Frederick Clark
George Albert Gamlen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3908859A priority Critical patent/GB921050A/en
Priority to ES0262527A priority patent/ES262527A1/en
Priority to CH1289160A priority patent/CH402235A/en
Publication of GB921050A publication Critical patent/GB921050A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/523Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl amido or hydroxyalkyl amino sulfonyl group, a quaternised or non-quaternised amino alkyl sulfonyl amido group, or a substituted alkyl amino sulfonyl group, or a halogen alkyl sulfonyl amido or halogen alkyl amino sulfonyl group or a vinyl sulfonylamido or a substituted vinyl sulfonamido group
    • C09B62/537Porphines; Azaporphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The invention comprises dyestuffs or mixtures of dyestuffs which, in the form of the free acids, have the formula:- <FORM:0921050/IV(a)/1> where Pc is a phthalocyanine radical, R1 and R2 are each hydrogen, a hydrocarbon radical or a hydroxy alkyl radical or R1 and R2 together with the nitrogen atom form a 5- or 6-membered heterocyclic ring, X is chlorine or bromine, A is hydroxy, chlorine or bromine and a, b and c are each values of from 1 to 2 provided that a+b+c does not exceed 4. The phthalocyanine radicals include metal-free, cobalt, nickel and copper phthalocyanine radicals. The dyes are made by treating an aqueous suspension of a sulphochloride of the formula:- <FORM:0921050/IV(a)/2> when n is a value from 0 to 2 and d is a value from 2 to 4 provided that n+d does not exceed 4, with a compound of the formula:- <FORM:0921050/IV(a)/3> and with a compound of the formula:- <FORM:0921050/IV(a)/4> and hydrolysing those sulphochloride groups which have not been converted to sulphonamide groups. Amines which are specified are, on the one hand, ammonia, methylamine, dimethylamine, ethylamine, p-hydroxyethylamine, cyclohexylamine, benzylamine, aniline, di-(b -hydroxyethyl)amine, N - methyl - N - b - hydroxyethylamine, N-methylglucamine, piperidine and morpholine and on the other hand, g -chloro-b -hydroxypropylamine, g -bromo-b -hydroxypropylamine and b :g -dichloro- or dibromopropylamine. The dyes dye, pad or print cellulose textile materials in conjunction with a treatment with an acid-binding agent and colour wool, silk, leather, synthetic polyamides and polyacrylonitriles from a weakly alkaline, neutral or acid solution giving greenish-blue shades. The Provisional Specification also refers to dyes of the above general formula wherein a is 0, 1 or 2 and b and c are each 1, 2 or 3, provided that a+b+c does not exceed 4 and that when a is 0 at least one of R1 and R2 is hydrogen. Specifications 708,543, 784,843, 785,629 and 830,847 are referred to.
GB3908859A 1959-11-18 1959-11-18 New phthalocyanine dyestuffs Expired GB921050A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB3908859A GB921050A (en) 1959-11-18 1959-11-18 New phthalocyanine dyestuffs
ES0262527A ES262527A1 (en) 1959-11-18 1960-11-17 New phthalocyanine dyestuffs
CH1289160A CH402235A (en) 1959-11-18 1960-11-17 Process for the preparation of phthalocyanine dyes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3908859A GB921050A (en) 1959-11-18 1959-11-18 New phthalocyanine dyestuffs

Publications (1)

Publication Number Publication Date
GB921050A true GB921050A (en) 1963-03-13

Family

ID=10407563

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3908859A Expired GB921050A (en) 1959-11-18 1959-11-18 New phthalocyanine dyestuffs

Country Status (3)

Country Link
CH (1) CH402235A (en)
ES (1) ES262527A1 (en)
GB (1) GB921050A (en)

Also Published As

Publication number Publication date
ES262527A1 (en) 1961-01-01
CH402235A (en) 1965-11-15

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