GB920390A - Shaped materials containing coloured copolymers - Google Patents

Shaped materials containing coloured copolymers

Info

Publication number
GB920390A
GB920390A GB1696361A GB1696361A GB920390A GB 920390 A GB920390 A GB 920390A GB 1696361 A GB1696361 A GB 1696361A GB 1696361 A GB1696361 A GB 1696361A GB 920390 A GB920390 A GB 920390A
Authority
GB
United Kingdom
Prior art keywords
acryloylamino
coupling product
diazotized
vinyl
butyl acrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1696361A
Inventor
Guenter Lange
Guenter Krehbiel
Hans Wilhelm
Ernst Penning Gerd Louis
Hans Weidinger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB920390A publication Critical patent/GB920390A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0056—Dyeing with polymeric dyes involving building the polymeric dyes on the fibres
    • D06P1/006—Dyeing with polymeric dyes involving building the polymeric dyes on the fibres by using dyes with polymerisable groups, e.g. dye ---CH=CH2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Coloured copolymers are obtained from at least one dye containing an olefinic group and at least one other compound which contains a polymerizable olefinic group. The examples describe the polymerization in an aqueous emulsion with the aid of potassium persulphate of: (1) butyl acrylate, methyl methacrylate and the coupling product of diazotized p-aminostyrene and 1-(3-methyl-5-hydroxy - pyrazolyl - 1) - 2 - chlorophenylsulphonic acid-5; (2) as in (1) but employing the coupling product of diazotized p-aminostyrene and alpha-naphtholsulphonic acid-4; (3) methylmethacrylate and the coupling product of (2); (4) vinyl chloride, isooctyl acrylate, acrylic acid and the coupling product of diazotized 1-acryloylamino-4-aminobenzene with 1-(2-chloro - 5 - sulphophenyl) - 3 - methylpyrazolone-5; (5) butyl acrylate, acrylonitrile, methacrylamide and the coupling product of diazotized 1-acryloylamino-4-aminobenzene with 1-hydroxynaphthalene-4-sulphonic acid; (6) as in (5) but employing 1-amino-2-acetyl-4-acryloylamino-anthraquinone as the coloured monomer; (8) butyl acrylate, styrene, methacrylamide, N-vinyl imidazole quaternized with dimethyl sulphate and 4-acryloylaminoazobenzene; and also: (7) the polymerization in a butanol-toluene mixture of butyl acrylate, methacrylamide, vinyl propionate and 1-acryloylamino-5-benzoylaminoanthraquinone; (9) the bulk polymerization of a mixture of N-vinylcarbazole and 1 - acryloylamino - 4 - benzoylaminoanthraquinone containing di-tertiary butyl peroxide, azodiisobutyronitrile being sprinkled over the surface of the mixture; and (10) the bulk poly-merization of methyl methacrylate and the coupling product of diazotized 1-amino-4-acryloylamino-2,5-dimethoxybenzene and 2-hydroxynaphthalene in the presence of benzoyl peroxide and n-butyl phthalate, the reaction being carried out in two stages, the second one being in a mould. Other specified dyestuff monomers are those of Specifications 779,781, 830,876, 858,183, 875,946 and 879,071. Other specified copolymerizable monomers include methacrylic, crotonic chloroacrylic, itaconic and maleic acids and their esters, amides and nitriles, allyl esters, vinylidene halides, vinyl ethers, N-vinyl lactams, vinylamines, divinyl benzene, methylene bis-acrylamides and ethylene glycol bis-acrylate. The copolymers are used in the production of shaped materials, e.g. films, fibres, plates, coatings and laminates. Specification 524,996 also is referred to.
GB1696361A 1960-05-14 1961-05-10 Shaped materials containing coloured copolymers Expired GB920390A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB57856A DE1184949B (en) 1960-05-14 1960-05-14 Production of transparent colored molded bodies

Publications (1)

Publication Number Publication Date
GB920390A true GB920390A (en) 1963-03-06

Family

ID=6971859

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1696361A Expired GB920390A (en) 1960-05-14 1961-05-10 Shaped materials containing coloured copolymers

Country Status (5)

Country Link
BE (1) BE603733A (en)
CH (2) CH479644A (en)
DE (1) DE1184949B (en)
FR (1) FR1291903A (en)
GB (1) GB920390A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3536440A (en) * 1966-06-03 1970-10-27 Bayer Ag Process for the dyeing and printing of fibre substrates

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL287281A (en) * 1961-12-29
FR2280672A1 (en) * 1974-08-02 1976-02-27 Ugine Kuhlmann STRUCTURALLY COLORED COPOLYMERS BASED ON CYANOVINYL-AZOIC DYES

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3536440A (en) * 1966-06-03 1970-10-27 Bayer Ag Process for the dyeing and printing of fibre substrates

Also Published As

Publication number Publication date
CH479644A (en) 1969-10-15
DE1184949B (en) 1965-01-07
FR1291903A (en) 1962-04-27
CH997961A4 (en) 1964-04-30
BE603733A (en)
CH380697A (en) 1964-10-15

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