GB914407A - Process for the improvement of the properties of polymers or co-polymers of vinyl chloride - Google Patents

Process for the improvement of the properties of polymers or co-polymers of vinyl chloride

Info

Publication number
GB914407A
GB914407A GB946959A GB946959A GB914407A GB 914407 A GB914407 A GB 914407A GB 946959 A GB946959 A GB 946959A GB 946959 A GB946959 A GB 946959A GB 914407 A GB914407 A GB 914407A
Authority
GB
United Kingdom
Prior art keywords
polymers
emulsifier
polymerization
metal
fatty acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB946959A
Inventor
Hans Bauer
Joseph Heckmaier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wacker Chemie AG
Original Assignee
Wacker Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wacker Chemie AG filed Critical Wacker Chemie AG
Priority to GB946959A priority Critical patent/GB914407A/en
Publication of GB914407A publication Critical patent/GB914407A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02Monomers containing chlorine
    • C08F14/04Monomers containing two carbon atoms
    • C08F14/06Vinyl chloride

Abstract

The electrical properties of vinyl chloride suspension polymers and copolymers are stated to be improved by a process in which either (a) they are washed with electrolyte-free water of conductivity less than 2 micro-Siemens-if polymerization has been effected in presence of a secondary alkyl sulphonate or a fatty acid/hydrolysed protein condensation product as emulsifier, or (b) if said emulsifier has not been used in polymerization, the polymers are pretreated with a water-soluble compound of a Group I-IV metal and/or said emulsifier in aqueous suspension prior to said washing. The Group I-IV metal compound is one that is known as an additive to polyvinyl chloride; specifically mentioned are alkaline earth metal oxides, hydroxides, acetates (e.g. of Mg or Pb), lactates and acetoacetates, especially of calcium, and alkali metal polymeta- and pyro-phosphates. Also mentioned are (i) polymer additives: titanium dioxide, tribasic lead sulphate, lead stearate and di(2-ethylhexyl) phthalate; (ii) polymerization ingredients: dilauryl peroxide, sodium diisopropyl- or diisobutyl-naphthalene sulphonate and polyvinylalcohol. Proprietary secondary alkyl sulphonates and fatty acid/protein condensates are specified.
GB946959A 1959-03-18 1959-03-18 Process for the improvement of the properties of polymers or co-polymers of vinyl chloride Expired GB914407A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB946959A GB914407A (en) 1959-03-18 1959-03-18 Process for the improvement of the properties of polymers or co-polymers of vinyl chloride

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB946959A GB914407A (en) 1959-03-18 1959-03-18 Process for the improvement of the properties of polymers or co-polymers of vinyl chloride

Publications (1)

Publication Number Publication Date
GB914407A true GB914407A (en) 1963-01-02

Family

ID=9872571

Family Applications (1)

Application Number Title Priority Date Filing Date
GB946959A Expired GB914407A (en) 1959-03-18 1959-03-18 Process for the improvement of the properties of polymers or co-polymers of vinyl chloride

Country Status (1)

Country Link
GB (1) GB914407A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3542710A (en) * 1965-12-21 1970-11-24 Montedison Spa Colored transparent thermoplastic sheet based on vinyl chloride polymer
US4914154A (en) * 1984-08-24 1990-04-03 Wacker-Chemie Gmbh Novel matting agent and its use

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3542710A (en) * 1965-12-21 1970-11-24 Montedison Spa Colored transparent thermoplastic sheet based on vinyl chloride polymer
US4914154A (en) * 1984-08-24 1990-04-03 Wacker-Chemie Gmbh Novel matting agent and its use
US4978718A (en) * 1984-08-24 1990-12-18 Wacker-Chemie Gmbh Novel matting agent and its use

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