GB914407A - Process for the improvement of the properties of polymers or co-polymers of vinyl chloride - Google Patents
Process for the improvement of the properties of polymers or co-polymers of vinyl chlorideInfo
- Publication number
- GB914407A GB914407A GB946959A GB946959A GB914407A GB 914407 A GB914407 A GB 914407A GB 946959 A GB946959 A GB 946959A GB 946959 A GB946959 A GB 946959A GB 914407 A GB914407 A GB 914407A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymers
- emulsifier
- polymerization
- metal
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Abstract
The electrical properties of vinyl chloride suspension polymers and copolymers are stated to be improved by a process in which either (a) they are washed with electrolyte-free water of conductivity less than 2 micro-Siemens-if polymerization has been effected in presence of a secondary alkyl sulphonate or a fatty acid/hydrolysed protein condensation product as emulsifier, or (b) if said emulsifier has not been used in polymerization, the polymers are pretreated with a water-soluble compound of a Group I-IV metal and/or said emulsifier in aqueous suspension prior to said washing. The Group I-IV metal compound is one that is known as an additive to polyvinyl chloride; specifically mentioned are alkaline earth metal oxides, hydroxides, acetates (e.g. of Mg or Pb), lactates and acetoacetates, especially of calcium, and alkali metal polymeta- and pyro-phosphates. Also mentioned are (i) polymer additives: titanium dioxide, tribasic lead sulphate, lead stearate and di(2-ethylhexyl) phthalate; (ii) polymerization ingredients: dilauryl peroxide, sodium diisopropyl- or diisobutyl-naphthalene sulphonate and polyvinylalcohol. Proprietary secondary alkyl sulphonates and fatty acid/protein condensates are specified.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB946959A GB914407A (en) | 1959-03-18 | 1959-03-18 | Process for the improvement of the properties of polymers or co-polymers of vinyl chloride |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB946959A GB914407A (en) | 1959-03-18 | 1959-03-18 | Process for the improvement of the properties of polymers or co-polymers of vinyl chloride |
Publications (1)
Publication Number | Publication Date |
---|---|
GB914407A true GB914407A (en) | 1963-01-02 |
Family
ID=9872571
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB946959A Expired GB914407A (en) | 1959-03-18 | 1959-03-18 | Process for the improvement of the properties of polymers or co-polymers of vinyl chloride |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB914407A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3542710A (en) * | 1965-12-21 | 1970-11-24 | Montedison Spa | Colored transparent thermoplastic sheet based on vinyl chloride polymer |
US4914154A (en) * | 1984-08-24 | 1990-04-03 | Wacker-Chemie Gmbh | Novel matting agent and its use |
-
1959
- 1959-03-18 GB GB946959A patent/GB914407A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3542710A (en) * | 1965-12-21 | 1970-11-24 | Montedison Spa | Colored transparent thermoplastic sheet based on vinyl chloride polymer |
US4914154A (en) * | 1984-08-24 | 1990-04-03 | Wacker-Chemie Gmbh | Novel matting agent and its use |
US4978718A (en) * | 1984-08-24 | 1990-12-18 | Wacker-Chemie Gmbh | Novel matting agent and its use |
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