GB909051A - A method for the emulsion-polymerisation of vinyl acetate alone and in a mixed polymerisation together with esters of unsaturated mono- and dicarboxylic acids - Google Patents

A method for the emulsion-polymerisation of vinyl acetate alone and in a mixed polymerisation together with esters of unsaturated mono- and dicarboxylic acids

Info

Publication number
GB909051A
GB909051A GB13677/59A GB1367759A GB909051A GB 909051 A GB909051 A GB 909051A GB 13677/59 A GB13677/59 A GB 13677/59A GB 1367759 A GB1367759 A GB 1367759A GB 909051 A GB909051 A GB 909051A
Authority
GB
United Kingdom
Prior art keywords
esters
polymerisation
dicarboxylic acids
vinyl acetate
unsaturated mono
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13677/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ROBERT MURJAHN
Original Assignee
ROBERT MURJAHN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ROBERT MURJAHN filed Critical ROBERT MURJAHN
Publication of GB909051A publication Critical patent/GB909051A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F18/02—Esters of monocarboxylic acids
    • C08F18/04—Vinyl esters
    • C08F18/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F18/02—Esters of monocarboxylic acids
    • C08F18/04—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Vinyl esters are polymerized alone or together with esters of unsaturated mono- and dicarboxylic acids in an aqueous medium containing an emulsifying system which consists of 2-10% by weight of monomer of one or more non-ionogenic surface-active substances and 1-5% by weight of one or more weakly cationically active protective colloids. Non-ionogenic surface-active substances specified are polyalkylene oxides and adducts thereof with long chain alcohols or substituted phenols, e.g. coconut oil alcohols, n-dodecyl alcohol and p-nonyl phenol. Cationically active protective colloids specified are polyalkyleneimines, polyacrylamides, products obtained by partial or complete Hofmann's degradation of polyacrylamide and poly-N-vinylpyrrolidone, including mixtures of polyvinyl pyrrolidones of differing K-values. Also present may be anionically active sulphonates. The examples describe the homopolymerization of vinyl acetate and its copolymerization with vinyl butyrate, di-n-butyl maleate and di-n-hexyl maleate in processes which involve gradual addition of monomer to the reaction system and the addition of further quantities of the catalyst (potassium persulphate) as the reaction proceeds.
GB13677/59A 1958-04-24 1959-04-22 A method for the emulsion-polymerisation of vinyl acetate alone and in a mixed polymerisation together with esters of unsaturated mono- and dicarboxylic acids Expired GB909051A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DED27948A DE1092656B (en) 1958-04-24 1958-04-24 Process for the emulsion polymerization of vinyl acetate by itself and in mixed polymerization with esters of unsaturated mono- and dicarboxylic acids

Publications (1)

Publication Number Publication Date
GB909051A true GB909051A (en) 1962-10-24

Family

ID=7039468

Family Applications (2)

Application Number Title Priority Date Filing Date
GB13677/59A Expired GB909051A (en) 1958-04-24 1959-04-22 A method for the emulsion-polymerisation of vinyl acetate alone and in a mixed polymerisation together with esters of unsaturated mono- and dicarboxylic acids
GB12809/62A Expired GB950569A (en) 1958-04-24 1962-04-03 Aqueous emulsion polymerisation of acrylic acid esters

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB12809/62A Expired GB950569A (en) 1958-04-24 1962-04-03 Aqueous emulsion polymerisation of acrylic acid esters

Country Status (6)

Country Link
BE (1) BE577815A (en)
CH (1) CH409402A (en)
DE (1) DE1092656B (en)
FR (1) FR1405201A (en)
GB (2) GB909051A (en)
NL (2) NL125862C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2446842A1 (en) * 1979-01-22 1980-08-14 Nat Distillers Chem Corp EMULSION PROCESS FOR THE PREPARATION OF VINYL ACETATE / ETHYLENE ELASTOMERIC COPOLYMERS
CN113680274A (en) * 2021-08-25 2021-11-23 太和县芮欣生物科技有限公司 Preparation method of compound alcohol ether carboxylate

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE617324A (en) * 1961-05-06
NL281590A (en) * 1961-08-09
DE1301064B (en) * 1965-05-13 1969-08-14 Basf Ag Process for the preparation of aqueous dispersions of vinyl ester polymers

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE727955C (en) * 1934-11-20 1942-11-17 Ig Farbenindustrie Ag Process for the preparation of stable emulsions of polymerization products
DE744318C (en) * 1940-07-26 1944-06-17 Ig Farbenindustrie Ag Process for the production of high percentage stable emulsions
US2614087A (en) * 1950-08-12 1952-10-14 Du Pont Preparation of polyvinyl acetate emulsions
DE936063C (en) * 1951-07-18 1955-12-01 Wacker Chemie Gmbh Process for the production of waterproof products by means of emulsion polymerization of organic vinyl esters
DE961398C (en) * 1953-05-14 1957-04-04 Wacker Chemie Gmbh Process for the production of waterproof products by means of emulsion polymerization of organic vinyl esters

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2446842A1 (en) * 1979-01-22 1980-08-14 Nat Distillers Chem Corp EMULSION PROCESS FOR THE PREPARATION OF VINYL ACETATE / ETHYLENE ELASTOMERIC COPOLYMERS
CN113680274A (en) * 2021-08-25 2021-11-23 太和县芮欣生物科技有限公司 Preparation method of compound alcohol ether carboxylate
CN113680274B (en) * 2021-08-25 2023-03-28 三合润一新材料(广州)股份有限公司 Preparation method of compound alcohol ether carboxylate

Also Published As

Publication number Publication date
NL238361A (en)
BE577815A (en)
FR1405201A (en) 1965-07-09
CH409402A (en) 1966-03-15
NL125862C (en)
GB950569A (en) 1964-02-26
DE1092656B (en) 1960-11-10

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