GB907070A - Tertiary alcohols and process for their manufacture - Google Patents
Tertiary alcohols and process for their manufactureInfo
- Publication number
- GB907070A GB907070A GB425061A GB425061A GB907070A GB 907070 A GB907070 A GB 907070A GB 425061 A GB425061 A GB 425061A GB 425061 A GB425061 A GB 425061A GB 907070 A GB907070 A GB 907070A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- radical
- stands
- radicals
- converting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Pyridine Compounds (AREA)
Abstract
The invention comprises t-alcohols of the formula: <FORM:0907070/IV (b)/1> in which R stands for a polyalkylmethyl radical which contains at least 3 carbon atoms and Ph represents a phenyl radical, which contains an alkoxy group containing from 1 to 4 carbon atoms in the 3-position and/or the 4-position and salts and N-oxides thereof, by reacting a ketone of the formula: <FORM:0907070/IV (b)/2> with an organo-metallic reagent of the formula: <FORM:0907070/IV (b)/3> wherein one of the radicals X, Y and Z stands for the radical Ph. another for R, and the third for the radical <PICT:0907070/IV (b)/1> the radicals Ph and R having the previously given meanings and M\sL represents the positively charged ion of a metal of the Ia Group of the Periodic table or the positively charged ion of the formula Met-Hal\sL, in which Met represents a bivalent metal of the II Group of the Periodic table and Hal stands for halogen, and if desired, converting a resulting salt into the free base and/or converting a free base into a salt thereof and/or separating the resulting mixture of isomers into individual isomers. The preparation of 1-(4-methoxyphenyl)-2-methyl-1-(3-pyridyl) propanol is described. Pharmaceutical compositions having an adrenal inhibiting effect and incorporating the above compounds are administered enterally or parenterally as capsules, tablets, dragees, solutions, suspensions and emulsions. 4-Methoxy-phenyl 3-pyridyl ketone is obtained by treating nicotinic acid with thionyl chloride followed by condensation of the product with anisole.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US636060A | 1960-02-03 | 1960-02-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB907070A true GB907070A (en) | 1962-10-03 |
Family
ID=21720514
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB425061A Expired GB907070A (en) | 1960-02-03 | 1961-02-03 | Tertiary alcohols and process for their manufacture |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE599773A (en) |
CH (1) | CH396906A (en) |
GB (1) | GB907070A (en) |
-
1961
- 1961-01-26 CH CH91161A patent/CH396906A/en unknown
- 1961-02-02 BE BE599773A patent/BE599773A/en unknown
- 1961-02-03 GB GB425061A patent/GB907070A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CH396906A (en) | 1965-08-15 |
BE599773A (en) | 1961-05-29 |
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