GB900752A - Polymer-dyestuff reaction products - Google Patents
Polymer-dyestuff reaction productsInfo
- Publication number
- GB900752A GB900752A GB510860A GB510860A GB900752A GB 900752 A GB900752 A GB 900752A GB 510860 A GB510860 A GB 510860A GB 510860 A GB510860 A GB 510860A GB 900752 A GB900752 A GB 900752A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reactive
- dyestuff
- soluble
- reaction
- coupling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0056—Dyeing with polymeric dyes involving building the polymeric dyes on the fibres
- D06P1/0064—Dyeing with polymeric dyes involving building the polymeric dyes on the fibres by using reactive polyfunctional compounds, e.g. crosslinkers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/20—Post-etherification treatments of chemical or physical type, e.g. mixed etherification in two steps, including purification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/06—Dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Structural Engineering (AREA)
- Coloring (AREA)
- Paper (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Polymer-dyestuff reaction products are obtained by reacting, in an aqueous medium and in the presence of an acid-binding agent, a natural or synthetically produced high molecular weight polymer, which is soluble in water or aqueous alkali and which contains a plurality of free hydroxyl groups, with a dyestuff containing a reactive atom or group (which is capable, in the presence of an acid-binding agent, of reacting with the hydroxyl groups of the polymer with the formation of a covalent bond), or with a dyestuff intermediate which contains such a reactive atom or group, and in the latter case, subsequently converting the polymer-dyestuff intermediate reaction product so-obtained into a polymer-dyestuff reaction product by a process appropriate to the particular dyestuff. Specified polymers are soluble cellulose ethers containing free hydroxyl groups such as methyl-, ethyl-, hydroxyethyl- and carboxyalkyl-cellulose, the sulphuric acid monester of hydroxyethyl cellulose and phosphonomethylated cellulose; soluble higher polysaccharides and derivatives thereof containing free hydroxyl groups such as soluble starches, dextrin, starch-sodium glycollate, pectins, alginates, gum arabic, guaran and like vegetable mucilages; and polyvinyl alcohol. Specified reactive dyestuffs are those of the oxazine, triphenylmethane, xanthene, nitro, acridone, perinone, azo, anthraquinone and phthalocyanine series containing as reactive groups epoxy, ethylene imino, isocyanate, carbamic acid aryl ester, propiolic acid amide, acrylamino, vinylsulphone, aliphatically bound sulphuric acid ester, aliphatically bound sulphonyloxy or halogen groups, and in the latter case, the halogen atoms may be present in an aliphatic acyl residue or in a heterocyclic residue, such as a pyrimidine ring or preferably a triazine ring. When a reactive dyestuff intermediate is employed it may be a diazotizable amine containing a reactive group, or an azo dyestuff coupling component containing a reactive group, diazotization and coupling, or coupling with a diazo compound, being subsequently effected respectively. Alternatively (as exemplified in Examples 21 and 22), the intermediate may be 2 - chloro - 4(31 - sulphophenyl) - amino - 6(31-amino-41-sulpho-phenyl)amino-1:3:5-triazine or 2 - chloro - 4(b - aminoethyl) - amino - 6 - - (21:51-disulphophenyl)-amino-1:3:5-triazine in which case the reaction product is subsequently condensed with copper phthalocyanine 3:31:311:3111-tetrasulphonyl chloride. Suitable acid-binding agents are alkali metal hydroxides, carbonates, bicarbonates and phosphates. The reaction is preferably effected at room or slightly higher temperature and the reaction product may be precipitated by the addition of alcohol or by neutralization. Insoluble reaction products may be solubilized by grinding in alcoholic suspension to a particle size of 5 microns or less. The coloured reaction products may be used for spin-dyeing viscose or cuprammonium rayon (see Example 37) and for dyeing already formed fibres (see Group IV(c)). Most of the examples describe the manufacture of reaction products of various cellulose ethers with various reactive dyestuffs, or with various azo dyestuff components followed by coupling, or diazotization and coupling. Example 24 describes the reaction of polyvinyl alcohol with a reactive diazotizable amine followed by diazotization and coupling, Example 25 the reaction of a soluble starch with a reactive azo or anthraquinone dyestuff, and Examples 26, 28, 29, 30 and 31 the reaction of a soluble starch, starch sodium glycollate, dextrin, sodium alginate, the sodium salt of pectin, guaran or gum arabic with a reactive diazotizable amine followed by diazotization and coupling. Specifications 866,513 and 867,571 are referred to.ALSO:The products obtained by reacting a natural or synthetically produced high molecular weight polymer which is soluble in water or aqueous alkali and which contains a plurality of free hydroxyl groups, with a reactive dyestuff (see Group IV(a)), are employed for dyeing fibres. In Example 36 the reaction product of an alkali soluble hydroxyethyl cellulose and a reactive azo or reactive phthalocyanine dyestuff is employed in solution in aqueous caustic soda for dyeing cotton or fibres of glass, polyesters, polyamides, polyacrylonitrile, cellulose acetate or cellulose triacetate.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH6947459 | 1959-02-12 | ||
CH7459259 | 1959-06-18 | ||
CH25460A CH398835A (en) | 1960-01-12 | 1960-01-12 | Process for the preparation of polyhydroxylated dyes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB900752A true GB900752A (en) | 1962-07-11 |
Family
ID=27171947
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB510860A Expired GB900752A (en) | 1959-02-12 | 1960-02-12 | Polymer-dyestuff reaction products |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE587495A (en) |
DE (1) | DE1298658B (en) |
ES (1) | ES256010A1 (en) |
GB (1) | GB900752A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1643196A1 (en) * | 1966-01-20 | 1972-03-23 | Warner Lambert Pharmaceutical | Process for the production of a preparation for determining the amylase content |
GB2152937A (en) * | 1984-01-17 | 1985-08-14 | Bevaloid Ltd | Polymer compositions detectable in water |
EP1310533A2 (en) * | 2001-10-25 | 2003-05-14 | Agfa-Gevaert | Ink composition containing a particular type of dye, and corresponding ink jet printing process |
CN115960021A (en) * | 2023-02-09 | 2023-04-14 | 胜利油田物华化工厂 | Thickened oil viscosity reducer for improving crude oil recovery efficiency and synthesis method thereof |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE566099A (en) * | ||||
US2733236A (en) * | 1956-01-31 | Azo dyestuffs derived from dextran |
-
1960
- 1960-02-11 ES ES0256010A patent/ES256010A1/en not_active Expired
- 1960-02-11 BE BE587495A patent/BE587495A/en unknown
- 1960-02-11 DE DE1960C0020778 patent/DE1298658B/en active Pending
- 1960-02-12 GB GB510860A patent/GB900752A/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1643196A1 (en) * | 1966-01-20 | 1972-03-23 | Warner Lambert Pharmaceutical | Process for the production of a preparation for determining the amylase content |
GB2152937A (en) * | 1984-01-17 | 1985-08-14 | Bevaloid Ltd | Polymer compositions detectable in water |
EP1310533A2 (en) * | 2001-10-25 | 2003-05-14 | Agfa-Gevaert | Ink composition containing a particular type of dye, and corresponding ink jet printing process |
EP1310533A3 (en) * | 2001-10-25 | 2003-08-13 | Agfa-Gevaert | Ink composition containing a particular type of dye, and corresponding ink jet printing process |
CN115960021A (en) * | 2023-02-09 | 2023-04-14 | 胜利油田物华化工厂 | Thickened oil viscosity reducer for improving crude oil recovery efficiency and synthesis method thereof |
CN115960021B (en) * | 2023-02-09 | 2023-10-20 | 胜利油田物华化工厂 | Thickened oil viscosity reducer for improving crude oil recovery ratio and synthesis method thereof |
Also Published As
Publication number | Publication date |
---|---|
DE1298658B (en) | 1969-07-03 |
ES256010A1 (en) | 1960-08-16 |
BE587495A (en) | 1960-08-11 |
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