GB893439A - Improvements in compositions having oxidising properties - Google Patents
Improvements in compositions having oxidising propertiesInfo
- Publication number
- GB893439A GB893439A GB641659A GB641659A GB893439A GB 893439 A GB893439 A GB 893439A GB 641659 A GB641659 A GB 641659A GB 641659 A GB641659 A GB 641659A GB 893439 A GB893439 A GB 893439A
- Authority
- GB
- United Kingdom
- Prior art keywords
- monopersulphate
- composition
- water
- soluble
- monopersulphates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Scouring compositions suitable for removing stains from unglazed porcelain surfaces comprise a water-soluble monopersulphate and a water-soluble chloride, the cation of which is compatible (i.e. does not react or precipitate) with the monopersulphate. Specified chlorides are the alkali and alkaline-earth metal chlorides and magnesium and ammonium chlorides, and specified monopersulphates are the alkali-metal monopersulphates and ammonium, calcium, barium, zinc and aluminium monopersulphates. The preferred monopersulphate obtained is by reacting a mixture of monopersulphuric and sulphuric acids with potassium carbonate or hydroxide and drying the resulting mixture, the acids being in the proportions to give KHSO5: KHSO4: K2SO4 in molar proportions of about 2:1:1. The composition may be prepared by intimately mixing the solid, water-soluble monopersulphate and the solid, water-soluble chloride in their anhydrous forms in the ratio of chloride ion (reckoned as NaCl) to active oxygen between 1:100 and 20:1. The monopersulphate content of the solid composition is preferably equivalent to 0,05-5% of active oxygen based on the total weight of the composition. A suitable abrasive filler for use in the composition comprises about 90% of ground quartz flour, 5% of sodium tripolyphosphate, 3% of a sodium alkaryl sulphonate detergent and a perfume, the remainder being sodium sulphate. Specifications 428,142, 428,148 and 893,440 are referred to.ALSO:A composition having oxidising properties and suitable for bleaching textiles comprises a water-soluble monopersulphate and a watersoluble chloride, the cation of which is compatible (i.e. does not react or precipitate) with the monopersulphate. Specified chlorides are the alkali and alkaline-earth metal chlorides and magnesium and ammonium chlorides, and specified monopersulphates are the alkali-metal monopersulphates and ammonium, calcium, barium, zinc and aluminium monopersulphates. The preferred monopersulphate is obtained by reacting a mixture of monopersulphuric and sulphuric acids with potassium carbonate or hydroxide and drying the resulting mixture, the acids being in the proportions to give KHSO5: KHSO4: K2SO4 in molar proportions of about 2 : 1 : 1. The composition may be prepared by intimately mixing the solid, water-soluble monopersulphate and the solid, water-soluble chloride in their anhydrous forms in the ratio of chloride ion (reckoned as NaCl) to active oxygen between 1 : 100 and 20 : 1. The monopersulphate content of the solid composition is preferably equivalent to 0.05%-5% of active oxygen, based on the total weight of the composition. When dissolved in water the composition preferably contains a concentration of monopersulphate corresponding to 50-700 p.p.m. of active oxygen and of chloride ion of at least 5 p.p.m. Specifications 428,142, 428,148 and 893,440 are referred to.ALSO:A composition having oxidizing and anti-bacterial properties which, in its anhydrous form, may be used as a scouring composition for removing stains from unglazed porcelain surfaces and, in aqueous solution, may be used for bleaching textiles, comprises a water-soluble monopersulphate and a water-soluble chloride, the cation of which is compatible (i.e. does not react or precipitate) with the monopersulphate. Specified chlorides are the alkali and alkaline-earth metal chlorides and magnesium and ammonium chlorides, and specified monopersulphates are the alkali metal monopersulphates and ammonium, calcium, barium, zinc and aluminium monopersulphates. The preferred monopersulphate is obtained by reacting a mixture of monopersulphuric and sulphuric acids with potassium carbonate or hydroxide and drying the resulting mixture, the acids being in the proportions to give KHSO5 : KHSO4 : K2SO4 in molar proportions of about 2 : 1 : 1. The composition may be prepared by intimately mixing the solid, water-soluble monopersulphate and the solid, water-soluble chloride in their anhydrous forms in the ratio of chloride ion (reckoned as NaCl) to active oxygen between 1 : 100 and 20 : 1. The monopersulphate content of the solid composition is preferably equivalent to 0.05-5% of active oxygen, based on the total weight of the composition. When dissolved in water the composition preferably contains a concentration of monopersulphate corresponding to 50-700 p.p.m. of active oxygen and of chloride ion of at least 5 p.p.m. A suitable abrasive filler for use in scouring compositions comprises about 90% of ground quartz flour, 5% of sodium tripolyphate, 3% of a sodium alkaryl sulphonate detergent and a perfume, the remainder being sodium sulphate. Specifications 428,142, 428,148 and 893,440 are referred to.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE576754D BE576754A (en) | 1959-02-24 | ||
GB641659A GB893439A (en) | 1959-02-24 | 1959-02-24 | Improvements in compositions having oxidising properties |
FR789611A FR1222027A (en) | 1959-02-24 | 1959-03-17 | Monopersulfate-based compositions and their use |
CH360048D CH360048A (en) | 1959-02-24 | 1959-04-22 | Solid, durable bleach |
US44018A US3048546A (en) | 1959-02-24 | 1960-07-20 | Bleaching compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB641659A GB893439A (en) | 1959-02-24 | 1959-02-24 | Improvements in compositions having oxidising properties |
Publications (1)
Publication Number | Publication Date |
---|---|
GB893439A true GB893439A (en) | 1962-04-11 |
Family
ID=9814111
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB641659A Expired GB893439A (en) | 1959-02-24 | 1959-02-24 | Improvements in compositions having oxidising properties |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE576754A (en) |
CH (1) | CH360048A (en) |
GB (1) | GB893439A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113614155A (en) * | 2019-03-29 | 2021-11-05 | 汉高股份有限及两合公司 | Method for modifying the surface polarity of a rubber substrate |
-
0
- BE BE576754D patent/BE576754A/xx unknown
-
1959
- 1959-02-24 GB GB641659A patent/GB893439A/en not_active Expired
- 1959-04-22 CH CH360048D patent/CH360048A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113614155A (en) * | 2019-03-29 | 2021-11-05 | 汉高股份有限及两合公司 | Method for modifying the surface polarity of a rubber substrate |
Also Published As
Publication number | Publication date |
---|---|
BE576754A (en) | |
CH360048A (en) | 1962-02-15 |
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