GB892781A - Process and apparatus for the continuous production of cyanohydrins - Google Patents
Process and apparatus for the continuous production of cyanohydrinsInfo
- Publication number
- GB892781A GB892781A GB4415559A GB4415559A GB892781A GB 892781 A GB892781 A GB 892781A GB 4415559 A GB4415559 A GB 4415559A GB 4415559 A GB4415559 A GB 4415559A GB 892781 A GB892781 A GB 892781A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reaction
- carbonyl compounds
- cyanohydrin
- cyanohydrins
- crotonaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Cyanohydrins are prepared in a continuous manner by reacting aliphatic carbonyl compounds with hydrocyanic acid in the presence of a catalyst having an alkaline reaction, wherein the carbonyl compounds and the hydrocyanic acid are continuously introduced into a reaction unit containing the catalyst and a diluent in 10- to 400-fold excess of the starting substances and are conducted in a cycle, temperatures of 5 DEG C. to 20 DEG C. and a pH of 6 to 8 being maintained, the resulting reaction mixture being continuously drawn off and conducted into a sojourn zone maintained at 0 DEG C. to 10 DEG C. where it remains until the reaction is complete. Diluents may be water, hydrocarbons or the cyanohydrin obtained as a reaction product. Carbonyl compounds exemplified are acetaldehyde, crotonaldehyde and acetone, yielding lactic nitrile, crotonaldehyde cyanohydrin and acetone cyanohydrin, respectively, as final products.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4415559A GB892781A (en) | 1959-12-29 | 1959-12-29 | Process and apparatus for the continuous production of cyanohydrins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4415559A GB892781A (en) | 1959-12-29 | 1959-12-29 | Process and apparatus for the continuous production of cyanohydrins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB892781A true GB892781A (en) | 1962-03-28 |
Family
ID=10432038
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4415559A Expired GB892781A (en) | 1959-12-29 | 1959-12-29 | Process and apparatus for the continuous production of cyanohydrins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB892781A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2655715A1 (en) * | 1976-12-09 | 1978-06-15 | Basf Ag | METHOD FOR MANUFACTURING CYANHYDRINES |
EP1371632A1 (en) * | 2002-06-14 | 2003-12-17 | Rohm And Haas Company | Process for producing acetone cyanohydrin |
US8263796B2 (en) | 2007-10-23 | 2012-09-11 | Nippoh Chemicals Co., Ltd. | Process for production of cyanohydrin compound, and process for production of α-hydroxyester compound |
US8471053B2 (en) | 2007-10-23 | 2013-06-25 | Nippoh Chemicals Co., Ltd. | Process and apparatus for production of cyanohydrin compound, and process for production of α-hydroxyester compound |
-
1959
- 1959-12-29 GB GB4415559A patent/GB892781A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2655715A1 (en) * | 1976-12-09 | 1978-06-15 | Basf Ag | METHOD FOR MANUFACTURING CYANHYDRINES |
EP1371632A1 (en) * | 2002-06-14 | 2003-12-17 | Rohm And Haas Company | Process for producing acetone cyanohydrin |
SG124256A1 (en) * | 2002-06-14 | 2006-08-30 | Rohm & Haas | Improved process for producing acetone cyanohydrin |
US8263796B2 (en) | 2007-10-23 | 2012-09-11 | Nippoh Chemicals Co., Ltd. | Process for production of cyanohydrin compound, and process for production of α-hydroxyester compound |
US8471053B2 (en) | 2007-10-23 | 2013-06-25 | Nippoh Chemicals Co., Ltd. | Process and apparatus for production of cyanohydrin compound, and process for production of α-hydroxyester compound |
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