GB8926983D0 - Preparation of alcohols from olefins - Google Patents
Preparation of alcohols from olefinsInfo
- Publication number
- GB8926983D0 GB8926983D0 GB898926983A GB8926983A GB8926983D0 GB 8926983 D0 GB8926983 D0 GB 8926983D0 GB 898926983 A GB898926983 A GB 898926983A GB 8926983 A GB8926983 A GB 8926983A GB 8926983 D0 GB8926983 D0 GB 8926983D0
- Authority
- GB
- United Kingdom
- Prior art keywords
- preparation
- olefins
- alcohols
- afford
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 150000001298 alcohols Chemical class 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A process for the preparation of an alcohol from the corresponding olefin comprises a) reacting an olefin with a perfluorinated carboxylic acid in the presence of a very strong sulphonic acid catalyst whose hydrogen-ion activity is greater than that of pure sulphuric acid at a temperature in the range of from -15 to 130 DEG C to afford an ester; and b) subsequently reacting the ester with water at a temperature in the range of from -15 to 100 DEG C to afford the alcohol and perfluorinated carboxylic acid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8926983A GB2238539A (en) | 1989-11-29 | 1989-11-29 | Preparation of alcohols from olefins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8926983A GB2238539A (en) | 1989-11-29 | 1989-11-29 | Preparation of alcohols from olefins |
Publications (2)
Publication Number | Publication Date |
---|---|
GB8926983D0 true GB8926983D0 (en) | 1990-01-17 |
GB2238539A GB2238539A (en) | 1991-06-05 |
Family
ID=10667120
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8926983A Withdrawn GB2238539A (en) | 1989-11-29 | 1989-11-29 | Preparation of alcohols from olefins |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2238539A (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5824622A (en) * | 1994-01-12 | 1998-10-20 | E. I. Du Pont De Nemours And Company | Porous microcomposite of perfluorinated ion-exchange polymer and metal oxide, a network of silica, or a network of metal oxide and silica derived via a sol-gel process |
US5872277A (en) * | 1997-03-10 | 1999-02-16 | Loyola University Of Chicago | Methods for preparing prenyl alcohol |
JP2002080422A (en) * | 2000-09-06 | 2002-03-19 | Daikin Ind Ltd | Method for synthesizing ethyl trifluoroacetate |
EP2070900A3 (en) | 2006-07-20 | 2012-01-11 | Basf Se | Method for producing isopropanol and 2-butanol from the corresponding alkanes |
-
1989
- 1989-11-29 GB GB8926983A patent/GB2238539A/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
GB2238539A (en) | 1991-06-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |