GB2041364B - Producing secbutanol from linear butenes - Google Patents

Producing secbutanol from linear butenes

Info

Publication number
GB2041364B
GB2041364B GB8001408A GB8001408A GB2041364B GB 2041364 B GB2041364 B GB 2041364B GB 8001408 A GB8001408 A GB 8001408A GB 8001408 A GB8001408 A GB 8001408A GB 2041364 B GB2041364 B GB 2041364B
Authority
GB
United Kingdom
Prior art keywords
secbutanol
producing
linear butenes
butanol
sec
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8001408A
Other versions
GB2041364A (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anic SpA
Original Assignee
Anic SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anic SpA filed Critical Anic SpA
Publication of GB2041364A publication Critical patent/GB2041364A/en
Application granted granted Critical
Publication of GB2041364B publication Critical patent/GB2041364B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C07C29/82—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by azeotropic distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/86—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The process comprises the steps of esterifying one or more linear butene in the liquid phase with an organic acid in the presence of a cation exchange resin; hydrolyzing the resulting ester to sec-butanol in the presence of a cation exchange resin; and recovering the sec-butanol by azeotropic distillation.
GB8001408A 1979-01-30 1980-01-16 Producing secbutanol from linear butenes Expired GB2041364B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT19706/79A IT1110745B (en) 1979-01-30 1979-01-30 PROCEDURE FOR THE SYNTHESIS OF SEC-BUTANOL FROM LINEAR BUTENI

Publications (2)

Publication Number Publication Date
GB2041364A GB2041364A (en) 1980-09-10
GB2041364B true GB2041364B (en) 1983-03-23

Family

ID=11160539

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8001408A Expired GB2041364B (en) 1979-01-30 1980-01-16 Producing secbutanol from linear butenes

Country Status (11)

Country Link
JP (1) JPS55102530A (en)
BE (1) BE881437A (en)
DE (1) DE3003126A1 (en)
DK (1) DK35080A (en)
ES (1) ES8103006A1 (en)
FR (1) FR2447896A1 (en)
GB (1) GB2041364B (en)
IT (1) IT1110745B (en)
NL (1) NL8000580A (en)
NO (1) NO800215L (en)
SE (1) SE8000742L (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3067219D1 (en) * 1980-12-18 1984-04-26 Union Explosivos Rio Tinto Process for producing esters from olefins
US4384148A (en) * 1982-02-26 1983-05-17 Uop Inc. Hydration of olefins
US4927954A (en) * 1983-06-28 1990-05-22 Union Carbide Chemicals And Plastics Company, Inc. Continuous process for producing secondary alcohols and carboxylic acid esters
DE69117871T2 (en) * 1990-10-31 1996-11-07 Daicel Chem Process for the preparation of a lower alkyl acetate
WO2008009648A1 (en) * 2006-07-20 2008-01-24 Basf Se Process for preparing isopropanol and 2-butanol from the corresponding alkanes
CN102264685A (en) * 2008-12-15 2011-11-30 吉坤日矿日石能源株式会社 Method for producing acetic acid ester
CN104311390A (en) * 2014-10-17 2015-01-28 深圳市飞扬实业有限公司 Method for synthesizing sec-butyl alcohol
RU2570818C1 (en) 2015-01-12 2015-12-10 Открытое акционерное общество "Газпромнефть - Московский НПЗ" Method of obtaining carbonyl compounds c2-c4

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1374368A (en) * 1972-08-15 1974-11-20 Bp Chem Int Ltd Production of secbutanol

Also Published As

Publication number Publication date
FR2447896A1 (en) 1980-08-29
BE881437A (en) 1980-07-30
GB2041364A (en) 1980-09-10
IT7919706A0 (en) 1979-01-30
IT1110745B (en) 1986-01-06
SE8000742L (en) 1980-07-31
ES488741A0 (en) 1981-02-16
NL8000580A (en) 1980-08-01
NO800215L (en) 1980-07-31
DE3003126A1 (en) 1980-07-31
ES8103006A1 (en) 1981-02-16
DK35080A (en) 1980-07-31
JPS55102530A (en) 1980-08-05

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee