FR2447896A1 - METHOD FOR SYNTHESIS OF SECONDARY BUTANOL FROM RIGHT CHAIN BUTENES - Google Patents

METHOD FOR SYNTHESIS OF SECONDARY BUTANOL FROM RIGHT CHAIN BUTENES

Info

Publication number
FR2447896A1
FR2447896A1 FR8001798A FR8001798A FR2447896A1 FR 2447896 A1 FR2447896 A1 FR 2447896A1 FR 8001798 A FR8001798 A FR 8001798A FR 8001798 A FR8001798 A FR 8001798A FR 2447896 A1 FR2447896 A1 FR 2447896A1
Authority
FR
France
Prior art keywords
secondary butanol
synthesis
right chain
chain butenes
cation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR8001798A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anic SpA
Original Assignee
Anic SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anic SpA filed Critical Anic SpA
Publication of FR2447896A1 publication Critical patent/FR2447896A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C07C29/82—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by azeotropic distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/86—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

LA PRESENTE INVENTION DECRIT UN PROCEDE DE PREPARATION DU BUTANOL SECONDAIRE, CARACTERISE PAR LE FAIT QU'IL COMPREND LES STADES D'ESTERIFICATION DES BUTENES A CHAINE DROITE EN PHASE LIQUIDE EN PRESENCE DE RESINES ECHANGEUSES DE CATIONS, L'HYDROLYSE DE L'ESTER AINSI OBTENU EN BUTANOL SECONDAIRE EN PRESENCE D'UNE RESINE ECHANGEUSE DE CATIONS, ET LA RECUPERATION DU BUTANOL SECONDAIRE FORME PAR DISTILLATION AZEOTROPIQUE. UTILISATION DE CE PROCEDE POUR PREPARER DU BUTANOL SECONDAIRE PLUS PUR ET AVEC UN MEILLEUR RENDEMENT.THE PRESENT INVENTION DESCRIBES A PROCESS FOR THE PREPARATION OF SECONDARY BUTANOL, CHARACTERIZED BY THE FACT THAT IT INCLUDES THE STAGES OF ESTERIFICATION OF STRAIGHT CHAIN BUTENES IN THE LIQUID PHASE IN THE PRESENCE OF CATION-EXCHANGING RESINS, THE HYDROLYSIS OF THE ESTER THUS OBTAINED IN SECONDARY BUTANOL IN THE PRESENCE OF A CATION-EXCHANGING RESIN, AND THE RECOVERY OF SECONDARY BUTANOL FORMED BY AZEOTROPIC DISTILLATION. USE OF THIS PROCESS TO PREPARE SECONDARY BUTANOL THAT IS PURER AND IN BETTER YIELD.

FR8001798A 1979-01-30 1980-01-28 METHOD FOR SYNTHESIS OF SECONDARY BUTANOL FROM RIGHT CHAIN BUTENES Withdrawn FR2447896A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT19706/79A IT1110745B (en) 1979-01-30 1979-01-30 PROCEDURE FOR THE SYNTHESIS OF SEC-BUTANOL FROM LINEAR BUTENI

Publications (1)

Publication Number Publication Date
FR2447896A1 true FR2447896A1 (en) 1980-08-29

Family

ID=11160539

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8001798A Withdrawn FR2447896A1 (en) 1979-01-30 1980-01-28 METHOD FOR SYNTHESIS OF SECONDARY BUTANOL FROM RIGHT CHAIN BUTENES

Country Status (11)

Country Link
JP (1) JPS55102530A (en)
BE (1) BE881437A (en)
DE (1) DE3003126A1 (en)
DK (1) DK35080A (en)
ES (1) ES8103006A1 (en)
FR (1) FR2447896A1 (en)
GB (1) GB2041364B (en)
IT (1) IT1110745B (en)
NL (1) NL8000580A (en)
NO (1) NO800215L (en)
SE (1) SE8000742L (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3067219D1 (en) * 1980-12-18 1984-04-26 Union Explosivos Rio Tinto Process for producing esters from olefins
US4384148A (en) * 1982-02-26 1983-05-17 Uop Inc. Hydration of olefins
US4927954A (en) * 1983-06-28 1990-05-22 Union Carbide Chemicals And Plastics Company, Inc. Continuous process for producing secondary alcohols and carboxylic acid esters
EP0483826B1 (en) * 1990-10-31 1996-03-13 Nippon Petrochemicals Company, Limited Method for producing lower alkyl acetate
US7750194B2 (en) 2006-07-20 2010-07-06 Basf Aktiengesellschaft Process for preparing isopropanol and 2-butanol from the corresponding alkanes
WO2010071011A1 (en) * 2008-12-15 2010-06-24 新日本石油株式会社 Method for producing acetic acid ester
CN104311390A (en) * 2014-10-17 2015-01-28 深圳市飞扬实业有限公司 Method for synthesizing sec-butyl alcohol
RU2570818C1 (en) 2015-01-12 2015-12-10 Открытое акционерное общество "Газпромнефть - Московский НПЗ" Method of obtaining carbonyl compounds c2-c4

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2196310A1 (en) * 1972-08-15 1974-03-15 Bp Chem Int Ltd

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2196310A1 (en) * 1972-08-15 1974-03-15 Bp Chem Int Ltd

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CA1977 *

Also Published As

Publication number Publication date
GB2041364A (en) 1980-09-10
IT7919706A0 (en) 1979-01-30
JPS55102530A (en) 1980-08-05
IT1110745B (en) 1986-01-06
DE3003126A1 (en) 1980-07-31
ES488741A0 (en) 1981-02-16
NL8000580A (en) 1980-08-01
BE881437A (en) 1980-07-30
NO800215L (en) 1980-07-31
DK35080A (en) 1980-07-31
SE8000742L (en) 1980-07-31
GB2041364B (en) 1983-03-23
ES8103006A1 (en) 1981-02-16

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Legal Events

Date Code Title Description
ST Notification of lapse