GB892557A - Purification process - Google Patents
Purification processInfo
- Publication number
- GB892557A GB892557A GB4439559A GB4439559A GB892557A GB 892557 A GB892557 A GB 892557A GB 4439559 A GB4439559 A GB 4439559A GB 4439559 A GB4439559 A GB 4439559A GB 892557 A GB892557 A GB 892557A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyethers
- acid
- propylene oxide
- acids
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/30—Post-polymerisation treatment, e.g. recovery, purification, drying
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyethers (AREA)
Abstract
Polyethers contaminated with basic inorganic materials are purified by treating with an acid of the formula HxMFy where M is an element of Group 3 or 4 of the Periodic Table, x is 1 to 3 and y is 4 to 6. The polyethers are particularly those obtained by polymerizing a b -alkylene oxides, optionally in the presence of a compound containing reactive hydrogen, and in the presence of an alkaline catalyst, e.g. KOH and NaOH. Examples of the fluoro-acids are fluoroboric, fluorosilicic, fluorotitanic and fluoroaluminic acids. They may be added as aqueous solutions or as solutions or suspensions of metal fluoride, e.g.titanium tetrafluoride or aluminium trifluoride, in hydrofluoric acid. The amount of acid is preferably sufficient to produce a pH of 3 to 5. The temperature may be from 25 DEG to 150 DEG C., preferably 90 DEG to 110 DEG C. where the polyether is liquid. The resultant insoluble matter is removed by filtration. Prior to this, a further treatment with an acid-acceptor is preferably effected. Suitable acceptors are basic compounds insoluble in polyethers, e.g. silicates and carbonates of alkaline earth metals. In the examples, the polyethers are prepared from: (1) glycerol and propylene oxide; (2) trimethylolpropane and propylene oxide and then with ethylene oxide; (3) ethylene oxide and isooctanol; (4) trimethylolpropane and propylene oxide. These polyethers have hydroxyl values ranging from 59 to 542 mg. KOH per gm., the upper limit corresponding to a molecular weight of 310.ALSO:Polyethers contaminated with basic inorganic materials are purified by treating with an acid of the formula HxMFy where M is an element of Group 3 or 4 of the Periodic Table, x is 1 to 3 and y is 4 to 6. The polyethers are particularly those obtained by polymerising a b -alkylene oxides, optionally in the presence of a compound containing reactive hydrogen, such as water, monohydric alcohols, e.g. butanol, diols, pentaerythritol, sorbitol, sucrose and others mentioned hereinafter, and in the presence of an alkaline catalyst, e.g. KOH and NaOH. Examples of the fluoro-acids are fluoroboric, flourosilicic, fluorotitanic and fluoroaluminic acids. They may be added as aqueous solutions or as solutions or suspensions of metal fluoride, e.g. titanium tetrafluoride or aluminium trifluoride, in hydrofluoric acid. The amount of acid is preferably sufficient to produce a pH of 3 to 5. The temperature may be from 25 DEG to 150 DEG , preferably 90 DEG to 110 DEG C. where the polyether is liquid. The resultant insoluble matter is removed by filtration. Prior to this, a further treatment with an acid-acceptor is preferably effected, suitable acceptors being basic compounds insoluble in polyethers, e.g. silicates and carbonates of alkaline earth metals. In the examples, the polyethers are prepared from (1) glycerol and propylene oxide; (2) trimethyl propane and propylene oxide and then with ethylene oxide; (3) ethylene oxide and isooctanol; (4) trimethylpropane and propylene oxide. These polyethers have hydroxyl values ranging from 59 to 542 mg.K.O.H. per gm., the upper limit corresponding to a molecular weight of 310.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4439559A GB892557A (en) | 1959-12-31 | 1959-12-31 | Purification process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4439559A GB892557A (en) | 1959-12-31 | 1959-12-31 | Purification process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB892557A true GB892557A (en) | 1962-03-28 |
Family
ID=10433096
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4439559A Expired GB892557A (en) | 1959-12-31 | 1959-12-31 | Purification process |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB892557A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2173108A1 (en) * | 1972-02-24 | 1973-10-05 | Basf Ag | |
EP0094014A1 (en) * | 1982-05-06 | 1983-11-16 | The B.F. GOODRICH Company | Process for preparing colorless hydroxyl epihalohydrin polymers |
GB2135322A (en) * | 1983-01-21 | 1984-08-30 | Vyzk Ustav Petrochem | A process for purifying at least partially water-soluble polyethers and/or copolymers |
-
1959
- 1959-12-31 GB GB4439559A patent/GB892557A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2173108A1 (en) * | 1972-02-24 | 1973-10-05 | Basf Ag | |
EP0094014A1 (en) * | 1982-05-06 | 1983-11-16 | The B.F. GOODRICH Company | Process for preparing colorless hydroxyl epihalohydrin polymers |
GB2135322A (en) * | 1983-01-21 | 1984-08-30 | Vyzk Ustav Petrochem | A process for purifying at least partially water-soluble polyethers and/or copolymers |
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