GB891868A - Improvements in and relating to the hydrogenation of coal - Google Patents

Improvements in and relating to the hydrogenation of coal

Info

Publication number
GB891868A
GB891868A GB3630059A GB3630059A GB891868A GB 891868 A GB891868 A GB 891868A GB 3630059 A GB3630059 A GB 3630059A GB 3630059 A GB3630059 A GB 3630059A GB 891868 A GB891868 A GB 891868A
Authority
GB
United Kingdom
Prior art keywords
coal
pasting
oil
per
pound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3630059A
Inventor
John Hancock Howell
Edward William Doughty
Paul Luther Alspaugh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US472016A priority Critical patent/US2913388A/en
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Priority to GB3630059A priority patent/GB891868A/en
Priority to FR808989A priority patent/FR1239296A/en
Priority to DEU6624A priority patent/DE1253691B/en
Publication of GB891868A publication Critical patent/GB891868A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/083—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts in the presence of a solvent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
    • C10G1/065—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation in the presence of a solvent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Coal is hydrogenated by pasting with an oil to form a paste containing 10-80% by weight of coal, forming a multi-phase mixture with hydrogen at 2,500-12,000 p.s.i.g., heating to at least 495 DEG C. and causing intimate contact of the gas and liquid phases to permit a reaction rate of at least 150 pounds of coal reacted per cubic foot of reactor volume per hour. The pasting oil is preferably product boiling between 330 DEG C. at atmospheric pressure and 350 DEG C. at 5-50 mm. mercury. A catalyst may be added, e.g. nickel, tin, iron, lead and their derivatives. Temperature may be 500 DEG -600 DEG C. and hydrogen consumption 0,01-0,07 pound per pound of coal introduced. Intimate mixing is necessary, e.g. by maintaining turbulent flow at 3-80 feet per second or using an agitated reactor. Tubular reactors may comprise several vertical pipes with heating jackets, the downward pipes having 25 to 75% smaller diameter to minimise film formation on the walls.
GB3630059A 1954-11-30 1959-10-27 Improvements in and relating to the hydrogenation of coal Expired GB891868A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US472016A US2913388A (en) 1954-11-30 1954-11-30 Coal hydrogenation process
GB3630059A GB891868A (en) 1959-10-27 1959-10-27 Improvements in and relating to the hydrogenation of coal
FR808989A FR1239296A (en) 1959-10-27 1959-10-30 Coal hydrogenation process
DEU6624A DE1253691B (en) 1959-10-27 1959-11-05 Process for the continuous hydrogenation of coal

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3630059A GB891868A (en) 1959-10-27 1959-10-27 Improvements in and relating to the hydrogenation of coal

Publications (1)

Publication Number Publication Date
GB891868A true GB891868A (en) 1962-03-21

Family

ID=10386865

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3630059A Expired GB891868A (en) 1954-11-30 1959-10-27 Improvements in and relating to the hydrogenation of coal

Country Status (1)

Country Link
GB (1) GB891868A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0082536A2 (en) * 1981-12-23 1983-06-29 Imhausen-Chemie Gesellschaft mit beschränkter Haftung Process for the continuous pressure-hydrogenation of coal
US4487682A (en) * 1979-07-17 1984-12-11 Coal Industry (Patents) Limited Coal extraction
CN109054903B (en) * 2018-08-24 2021-04-16 新奥科技发展有限公司 Coal hydro-gasification method and device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4487682A (en) * 1979-07-17 1984-12-11 Coal Industry (Patents) Limited Coal extraction
EP0082536A2 (en) * 1981-12-23 1983-06-29 Imhausen-Chemie Gesellschaft mit beschränkter Haftung Process for the continuous pressure-hydrogenation of coal
EP0082536A3 (en) * 1981-12-23 1983-12-14 Imhausen-Chemie Gesellschaft Mit Beschrankter Haftung Process for the continuous pressure-hydrogenation of coal
CN109054903B (en) * 2018-08-24 2021-04-16 新奥科技发展有限公司 Coal hydro-gasification method and device

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