GB889652A - Liquid washing agent incorporating glycol derivatives containing peroxide groups - Google Patents
Liquid washing agent incorporating glycol derivatives containing peroxide groupsInfo
- Publication number
- GB889652A GB889652A GB6327/58A GB632758A GB889652A GB 889652 A GB889652 A GB 889652A GB 6327/58 A GB6327/58 A GB 6327/58A GB 632758 A GB632758 A GB 632758A GB 889652 A GB889652 A GB 889652A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mol
- ethylene oxide
- reacts
- hydroperoxide
- contain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
Abstract
A liquid washing agent incorporates the product obtainable by addition of an alkylene oxide and a hydroperoxide of the formula R-O-O-H, wherein R is an organic residue which is linked to the peroxide residue by a non-aromatic carbon atom (for preparation see Group IV(b)). Preferred hydroperoxides contain 1-30 carbon atoms and preferred alkylene oxides contain 2-10 carbon atoms. The term alkylene oxide includes styrene oxide. Peroxide stabilizers, e.g. silicates of calcium, magnesium, aluminium, and tin, and hydrated oxides or hydroxides of tin, and heavy metal chelating compounds such as ethylenediamine tetracetic acid, nitrilo-triacetic acid and their salts may be incorporated in the peroxides during their preparation. In an example, a washing agent consisting of alkylbenzene sulphonate, oleyl sulphate, coconut fatty acid ethanolamide, coconut alcohol, Na2-CO3, Na4P2O7, Na5P3O10, MgSiO3, Na2-O3,3SiO2, Na2SO4, an optical brightener and water is dissolved in water so that the solution contains 6 gms. per litre of the washing agent and to this is added an addition product of ethylene oxide and tert.-butylhydroperoxide and the solution is used for washing with boiling of linen or cotton. The bleaching action may be intensified by addition of benzoic anhydride.ALSO:Glycol ethers or polyethers containing peroxide groups are prepared by adding alkylene oxides to organic hydroperoxides in the presence of boron fluoride etherates which are derived from ethers containing 2 to 8 carbon atoms. The hydroperoxides used have the general formula R-OOH where R signifies an organic residue which is linked to the peroxide residue by a non-aromatic p carbon atom, and may contain 1-30, preferably 1 to 20, carbon atoms and be derived from saturated or unsaturated, straight or branched chain compounds or aromatic or nonaromatic cyclic compounds. The hydroperoxides with cyclic organic residues may have 4- to 8-membered rings which may be fused together and which may contain hetero atoms, such as oxygen or sulphur. The hydroperoxides may contain hydrocarbon residues only or may be substituted by different hetero-atoms or hetero-atoms groups, such as ether groups, thioether groups, carboxylic ester groups and halogen atoms, and may contain several peroxide groups. A list of suitable hydroperoxides is given. Preferred alkylene oxides are those containing 2-10 carbon atoms and including styrene oxide, ethylene oxide being the most preferred. The alkylene oxides are generally used in amounts of at least one mol and not exceeding 25 mol per mol of hydroperoxide. Temperatures up to 100 DEG C., preferably in the range 40 DEG C.-80 DEG C., are suitable. The catalysts are used in amounts of 0.1% to 10% by weight, preferably 0.5% to 1% by weight, referred to the hydroperoxide, the compound of boron fluoride with diethyl ether being the preferred catalyst. Known stabilizers for peroxides can be added to the reaction mixture, such as silicates of calcium, magnesium or aluminium or the hydrated oxides, hydroxides or silicates of tin, nitrilotriacetic acid or ethylenediamine tetraacetic acid or their salts. The products which contain 1-4 glycol residues may be used as emulsifiers and are particularly suitable as peroxidic catalysts for emulsion polymerisations. In Examples (1) t-butyl hydroperoxide reacts with 1.95 mol of ethylene oxide per mol of hydroperoxide; (2) a mixture of t-butylhydroperoxide and di-t-butyl-peroxide reacts with 1.6 mol of ethylene oxide per mol, giving glycol ethers containing 1 to 5 glycol ether residues per molecule; (3) the same mixture reacts with 4.95 mol ethylene oxide per mol; (4) t-amylhydroperoxide reacts with 3.95 mol ethylene oxide per mol; (5) n-octylhydroperoxide reacts with 5.65 mol of ethylene oxide per mol; (6) tbutylhydroperoxide reacts with 7.7 mol ethylene oxide per mol; (7) sec-butyl-hydroperoxide reacts with 5.65 mol ethylene oxide per mol; (8) sec-butyl-hydroperoxide reacts with 13 mol ethylene oxide per mol; (9) n-octylhydroperoxide reacts with 12.2 mol ethylene oxide per mol; (10) and (11) t-butyl-hydroperoxide reacts with styrene oxide; (12) t-butylhydroperoxide reacts with propylene oxide; (13) t-butyl-b -ethoxy-peroxide obtained by distillation of the product of (2) is reacted with a further 11 mols of ethylene oxide. The products may be used in liquid washing agents.ALSO:A liquid washing agent incorporates the product obtainable by addition of an alkylene oxide and a hydroperoxide of the formula R-O-O-H, wherein R is an organic residue which is linked to the peroxide residue by a non-aromatic carbon atom (for preparation see Group IV (b)). Preferred hydroperoxides contain 1-30 carbon atoms and preferred alkylene oxides contain 2-10 carbon atoms. The term alkylene oxide includes styrene oxide. In an example, a washing agent consisting of alkyl-benzene sulphonate, oleyl sulphate, coconut fatty acid ethanolamide, coconut alcohol, Na2CO3, Na4P2O7, Na5P3O10, MgSiO3, Na2O.3.3SiO2, Na2SO4, an optical brightene and water is dissolved in water so that the solution contains 6 gms per litre of the washing agent and to this is added an addition product of ethylene oxide and tert-butylhydroperoxide and the solution is used for washing, with boiling, of linen or cotton. The bleaching action may be intensified by addition of benzoic anhydride.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE889652X | 1957-03-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB889652A true GB889652A (en) | 1962-02-21 |
Family
ID=6834648
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB6327/58A Expired GB889652A (en) | 1957-03-07 | 1958-02-27 | Liquid washing agent incorporating glycol derivatives containing peroxide groups |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB889652A (en) |
NL (1) | NL225517A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0005098A1 (en) * | 1978-04-14 | 1979-10-31 | Société Chimique des Charbonnages | Compositions containing alkali metal mono- or polyalkylarylsulfonate and the corresponding hydroperoxide; process for their preparation and detergent compositions containing them |
FR2438682A2 (en) * | 1978-10-10 | 1980-05-09 | Charbonnages Ste Chimique | Dry mixt. of alkylbenzene sulphonate and corresp. hydroperoxide - useful as detergent and bleaching components |
EP0028186A1 (en) * | 1979-10-26 | 1981-05-06 | Société Chimique des Charbonnages | Process for the production of compositions comprising hydroperoxides of mono- or polyalkylarylsulfonates of an alkali metal and use of these compositions in the preparation of detergents |
US4283553A (en) * | 1979-09-24 | 1981-08-11 | Ivanchev Sergei S | Hydroperoxide derivatives of hydroxyethylated compounds and method of producing same |
-
0
- NL NL225517D patent/NL225517A/xx unknown
-
1958
- 1958-02-27 GB GB6327/58A patent/GB889652A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0005098A1 (en) * | 1978-04-14 | 1979-10-31 | Société Chimique des Charbonnages | Compositions containing alkali metal mono- or polyalkylarylsulfonate and the corresponding hydroperoxide; process for their preparation and detergent compositions containing them |
FR2438682A2 (en) * | 1978-10-10 | 1980-05-09 | Charbonnages Ste Chimique | Dry mixt. of alkylbenzene sulphonate and corresp. hydroperoxide - useful as detergent and bleaching components |
US4283553A (en) * | 1979-09-24 | 1981-08-11 | Ivanchev Sergei S | Hydroperoxide derivatives of hydroxyethylated compounds and method of producing same |
EP0028186A1 (en) * | 1979-10-26 | 1981-05-06 | Société Chimique des Charbonnages | Process for the production of compositions comprising hydroperoxides of mono- or polyalkylarylsulfonates of an alkali metal and use of these compositions in the preparation of detergents |
Also Published As
Publication number | Publication date |
---|---|
NL225517A (en) |
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