GB888547A - Dyeing and printing process - Google Patents

Dyeing and printing process

Info

Publication number
GB888547A
GB888547A GB4178659A GB4178659A GB888547A GB 888547 A GB888547 A GB 888547A GB 4178659 A GB4178659 A GB 4178659A GB 4178659 A GB4178659 A GB 4178659A GB 888547 A GB888547 A GB 888547A
Authority
GB
United Kingdom
Prior art keywords
unsubstituted
hydrogen
carboxylic
aralkyl
substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4178659A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB888547A publication Critical patent/GB888547A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/08Sensitivity-increasing substances
    • G03C1/10Organic substances
    • G03C1/12Methine and polymethine dyes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18One oxygen or sulfur atom
    • C07D231/20One oxygen atom attached in position 3 or 5
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18One oxygen or sulfur atom
    • C07D231/20One oxygen atom attached in position 3 or 5
    • C07D231/22One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18One oxygen or sulfur atom
    • C07D231/20One oxygen atom attached in position 3 or 5
    • C07D231/22One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
    • C07D231/261-Phenyl-3-methyl-5- pyrazolones, unsubstituted or substituted on the phenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3445Five-membered rings
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/0091Methine or polymethine dyes, e.g. cyanine dyes having only one heterocyclic ring at one end of the methine chain, e.g. hemicyamines, hemioxonol
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/02Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
    • C09B23/04Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups one >CH- group, e.g. cyanines, isocyanines, pseudocyanines
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/825Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
    • G03C1/83Organic dyestuffs therefor
    • G03C1/832Methine or polymethine dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Coloring (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Dyestuffs of the formula:- <FORM:0888547/IV (a)/1> wherein R1 is hydrogen, an unsubstituted or substituted alkyl radical or a functional derivative of a carboxylic group (e.g. a carboxylic acid ester group), R2 is hydrogen, an unsubstituted or substituted alkyl, aralkyl or aryl radical or a functional derivative of a carboxylic group and R3 and R4 are hydrogen, alkyl, aralkyl or unsubstituted or substituted aryl radicals or carboxylic groups or functional derivatives thereof, are added to cellulose ester, e.g. cellulose acetate, or polyamide, polyurethane or aromatic polyester (including polyethylene terephthalate and polycarbonates of 4,41-dihydroxy-diphenylpropane) spinning masses, whereby the fibres or films produced therefrom are dyed. Specification 886,091 is referred to.ALSO:Fibrous materials, films or other shaped articles of aromatic polyesters (including polycarbonates of 41,41-dihydroxy-diphenyl-propane), polyamides, polyurethanes or cellulose esters are dyed or printed with an aqueous bath or paste containing a dyestuff free from sulphonic acid groups of the formula <FORM:0888547/IV (c)/1> wherein R1 is hydrogen, an unsubstituted or substituted alkyl radical or a functional derivative of a carboxylic group, R2 is hydrogen, an unsubstituted or substituted alkyl, aralkyl or aryl radical or a functional derivative of a carboxylic group and R3 and R4 are hydrogen or alkyl, aralkyl or unsubstituted or substituted aryl radicals or carboxylic groups or functional derivatives thereof. Dyeing may be effected at 60 DEG C.-130 DEG C., preferably in the presence of an acid. Prints are subsequently heated or steamed at 180 DEG C.-210 DEG C. Leveling and dispersing agents and carriers, several of which are specified, may be added to the dyebath. Examples of dyeing and printing are given. The dyestuffs are made by the action of appropriately substituted 4-formyl-pyrazolones-5 or N,N-disubstituted 4-amino-methylene-pyrazolones-5 on appropriately substituted pyrazolones with unsubstituted 4-positions. Numerous dyestuffs are specified in which R2=phenyl, p-tolyl, mono- and di-chloro-phenyl, nitrophenyl, methoxyphenyl and cyanoethyl, R1=cyanoethyl, R4=methyl, carbethoxy or carboxy and R3=methyl or methoxy-phenyl groups. Specification 886,091 is referred to.
GB4178659A 1958-12-09 1959-12-08 Dyeing and printing process Expired GB888547A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF29767A DE1157582B (en) 1958-12-09 1958-12-09 Process for dyeing and printing structures made of aromatic polyesters, polyamides and polyurethanes

Publications (1)

Publication Number Publication Date
GB888547A true GB888547A (en) 1962-01-31

Family

ID=7093453

Family Applications (2)

Application Number Title Priority Date Filing Date
GB4157659A Expired GB886091A (en) 1958-12-09 1959-12-07 Process for the production of methine dyestuffs
GB4178659A Expired GB888547A (en) 1958-12-09 1959-12-08 Dyeing and printing process

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB4157659A Expired GB886091A (en) 1958-12-09 1959-12-07 Process for the production of methine dyestuffs

Country Status (6)

Country Link
BE (1) BE584028A (en)
CH (2) CH8094059D (en)
DE (1) DE1157582B (en)
FR (3) FR1244583A (en)
GB (2) GB886091A (en)
NL (1) NL246136A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3441563A (en) * 1958-08-22 1969-04-29 Bayer Ag Process for the production of substituted pyrazolones and of monomethine dyestuffs thereof
US4234677A (en) * 1978-01-26 1980-11-18 Ciba-Geigy Ag Pyrazolone dyestuffs and their use in photographic materials
CA1130130A (en) * 1979-03-02 1982-08-24 Raymond G. Lemahieu Photographic silver halide materials comprising a 2-pyrazolin-5-one pentamethine oxonol dye

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2840443A (en) * 1954-08-05 1958-06-24 Gen Aniline & Film Corp Use of methylidyne bis pyrazolones for dyeing

Also Published As

Publication number Publication date
FR1242601A (en) 1960-09-30
FR1244583A (en) 1960-10-28
CH8094059D (en)
DE1157582B (en) 1963-11-21
CH8093959D (en)
BE584028A (en)
NL246136A (en)
GB886091A (en) 1962-01-03
FR1240930A (en) 1960-09-09

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