GB887175A - New polymers - Google Patents

New polymers

Info

Publication number
GB887175A
GB887175A GB2607957A GB2607957A GB887175A GB 887175 A GB887175 A GB 887175A GB 2607957 A GB2607957 A GB 2607957A GB 2607957 A GB2607957 A GB 2607957A GB 887175 A GB887175 A GB 887175A
Authority
GB
United Kingdom
Prior art keywords
acid
sodium
hydrogen
polymers
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2607957A
Inventor
Alan Peden
Harry Smith
Edward Jervis Vickers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2607957A priority Critical patent/GB887175A/en
Publication of GB887175A publication Critical patent/GB887175A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Polymers of compounds of formul <FORM:0887175/IV (a)/1> or <FORM:0887175/IV (a)/2> where one R is hydrogen and the other hydrogen or an alkyl or aryl group, and R1 and R11 are hydrogen, alkyl, aryl or acyl groups, may be prepared by polymerizing the compounds, optionally together with other polymerizable ethylenically unsaturated compounds, in bulk, aqueous or non-aqueous solution, dispersion or suspension in the presence of free radical polymerization catalysts, ultra violet light or atomic radiation. Lists of suitable comonomers, catalysts and dispersing agents are given and examples describe the polymerization of (1) benzoylmethacrylhydroxamic acid in dioxane in the presence of benzoin and ultra violet light; (2) methacrylhydroxamic acid and methyl methacrylate in xylene in the presence of azo diisobutyronitrile; benzoylacrylhydroxamic acid and methyl methacrylate in water in the presence of ammonium persulphate, sodium metabisulphite and (3) sodium lauryl sulphate and (4) sodium oleyl sulphate; and (5) benzoylacrylhydroxamic acid and ethyl acrylate, butyl acrylate or butyl methacrylate in water in the presence of ammonium persulphate, sodium metabisulphite and sodium oleyl sulphate. The polymers may be converted by heating to polymers containing isocyanate groups which may be cross-linked by reacting with polyamines, e.g. decamethylene diamine or di-(6-aminohexyl)-amine. They may be used in thermosetting coating compositions and for binding pigments to textiles. Specifications 852,100 and 887,176 are referred to.
GB2607957A 1957-08-19 1957-08-19 New polymers Expired GB887175A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2607957A GB887175A (en) 1957-08-19 1957-08-19 New polymers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2607957A GB887175A (en) 1957-08-19 1957-08-19 New polymers

Publications (1)

Publication Number Publication Date
GB887175A true GB887175A (en) 1962-01-17

Family

ID=10238019

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2607957A Expired GB887175A (en) 1957-08-19 1957-08-19 New polymers

Country Status (1)

Country Link
GB (1) GB887175A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4868248A (en) * 1989-03-22 1989-09-19 Nalco Chemical Company Polyhydroxyamic acid polymers from polyacrylic acids
US4886872A (en) * 1989-05-22 1989-12-12 Nalco Chemical Company Novel cationic hydroxamate polymers
EP0458561A1 (en) * 1990-05-21 1991-11-27 Vinamul Ltd. Emulsion polymerisation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4868248A (en) * 1989-03-22 1989-09-19 Nalco Chemical Company Polyhydroxyamic acid polymers from polyacrylic acids
US4886872A (en) * 1989-05-22 1989-12-12 Nalco Chemical Company Novel cationic hydroxamate polymers
EP0458561A1 (en) * 1990-05-21 1991-11-27 Vinamul Ltd. Emulsion polymerisation

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