GB884656A - Process for the preparation of a detergent mixture of the type of the alkyl-aryl-sulphonates and of the secondary alkyl sulphates - Google Patents
Process for the preparation of a detergent mixture of the type of the alkyl-aryl-sulphonates and of the secondary alkyl sulphatesInfo
- Publication number
- GB884656A GB884656A GB2519/58A GB251958A GB884656A GB 884656 A GB884656 A GB 884656A GB 2519/58 A GB2519/58 A GB 2519/58A GB 251958 A GB251958 A GB 251958A GB 884656 A GB884656 A GB 884656A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphates
- alkyl
- benzene
- monoalkyl
- sulphonates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- -1 alkyl sulphates Chemical group 0.000 title abstract 3
- 239000003599 detergent Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 12
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 4
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 abstract 4
- 239000001117 sulphuric acid Substances 0.000 abstract 4
- 235000011149 sulphuric acid Nutrition 0.000 abstract 4
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 239000003208 petroleum Substances 0.000 abstract 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
- 150000004996 alkyl benzenes Chemical class 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 238000000605 extraction Methods 0.000 abstract 2
- 238000006386 neutralization reaction Methods 0.000 abstract 2
- 239000007858 starting material Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 1
- 229920000388 Polyphosphate Polymers 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 1
- 239000003518 caustics Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000001205 polyphosphate Substances 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- 235000019830 sodium polyphosphate Nutrition 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract 1
- 238000004227 thermal cracking Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
- C07C2/70—Catalytic processes with acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C309/29—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings
- C07C309/30—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings of six-membered aromatic rings substituted by alkyl groups
- C07C309/31—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings of six-membered aromatic rings substituted by alkyl groups by alkyl groups containing at least three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
- C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
- C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Detergent mixtures of alkyl aryl sulphonates and monoalkyl sulphates are produced by treating a petroleum fraction containing benzene, alkyl benzene and olefines having 8-18 carbon atoms at 5 DEG -15 DEG C. with sulphuric acid to alkylate the aromatic substances and sulphate the excess olefine, treating the resulting crude alkylate after the acid phase consisting mainly of monoalkyl sulphates has been separated out with sulphuric acid and/or sulphur trioxide to form alkyl aryl sulphonates and adding to the resulting sulphonate a quantity of the secondary alkyl sulphates prepared by neutralization and extraction of the said acid phase. Compositions are described comprising in addition to the essential ingredients sodium sulphate, polyphosphates and carboxymethyl cellulose.ALSO:In a process for the production of mixtures of alkyl aryl sulphonates and monoalkyl sulphates which are suitable as detergents (see Group III), a petroleum fraction containing benzene, alkyl benzene and olefines with 8-18 carbon atoms is treated at 5 DEG C.-15 DEG C. with sulphuric acid to alkylate the aromatic substances and sulphate the excess olefine, the resulting crude alkylate, after the acid phase consisting mainly of monoalkyl sulphates has been separated out, is treated with sulphuric acid and/or sulphur trioxide to form alkyl aryl sulphonates and to the resulting sulphonates is added a quantity of the secondary alkyl sulphates prepared by neutralisation and extraction of the said acid phase. Dialkyl sulphates also produced in the first step of the process are converted to monoalkyl sulphates by treatment with caustic alkali. Suitable starting materials specified include mixtures of benzene and gasoil obtained from thermal cracking of petroleum comprising aromatic constituents and petrol-gasoil fractions distilling between 70 DEG C. and 240 DEG C. Such fractions may be completed by addition of aromatics or olefins where necessary. Examples are furnished in which benzine-gasoil fractions and crude cracking benzene of boiling range 70 DEG C.-240 DEG C. are employed as starting materials.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO884656X | 1957-01-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB884656A true GB884656A (en) | 1961-12-13 |
Family
ID=20096958
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2519/58A Expired GB884656A (en) | 1957-01-25 | 1958-01-24 | Process for the preparation of a detergent mixture of the type of the alkyl-aryl-sulphonates and of the secondary alkyl sulphates |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1150382B (en) |
| FR (1) | FR1200160A (en) |
| GB (1) | GB884656A (en) |
| NL (2) | NL113406C (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0466243A1 (en) * | 1990-06-28 | 1992-01-15 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of secondary alkyl sulfate-containing surfactant compositions |
| US5250718A (en) * | 1992-09-28 | 1993-10-05 | Shell Oil Company | Process for the preparation of secondary alkyl sulfate-containing surfactant compositions |
| US5281366A (en) * | 1992-09-17 | 1994-01-25 | Shell Oil Company | Process for the preparation of secondary alkyl sulfate-containing surfactant compositions |
| US5290484A (en) * | 1992-11-12 | 1994-03-01 | Shell Oil Company | Process for the preparation of secondary alkyl sulfate-containing surfactant compositions |
| US5349101A (en) * | 1992-05-28 | 1994-09-20 | Shell Oil Company | Process for the preparation of secondary alkyl sulfate-containing surfactant compositions |
| US5389277A (en) * | 1993-09-30 | 1995-02-14 | Shell Oil Company | Secondary alkyl sulfate-containing powdered laundry detergent compositions |
| US5427717A (en) * | 1992-12-15 | 1995-06-27 | Shell Oil Company | Secondary alkyl sulfate/zeolite-containing surfactant compositions |
| USH1467H (en) * | 1993-11-16 | 1995-08-01 | Shell Oil Company | Detergent formulations containing a surface active composition containing a nonionic surfactant component and a secondary alkyl sulfate anionic surfactant component |
| USH1478H (en) * | 1993-09-30 | 1995-09-05 | Shell Oil Company | Secondary alkyl sulfate-containing liquid laundry detergent compositions |
| USH1680H (en) * | 1993-10-27 | 1997-09-02 | Shell Oil Company | Secondary alkyl sulfate-containing hard surface cleaning compositions |
-
0
- NL NL223297D patent/NL223297A/xx unknown
-
1957
- 1957-12-12 DE DEM36151A patent/DE1150382B/en active Pending
- 1957-12-17 NL NL223297A patent/NL113406C/xx active
-
1958
- 1958-01-22 FR FR1200160D patent/FR1200160A/en not_active Expired
- 1958-01-24 GB GB2519/58A patent/GB884656A/en not_active Expired
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0466243A1 (en) * | 1990-06-28 | 1992-01-15 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of secondary alkyl sulfate-containing surfactant compositions |
| US5349101A (en) * | 1992-05-28 | 1994-09-20 | Shell Oil Company | Process for the preparation of secondary alkyl sulfate-containing surfactant compositions |
| US5281366A (en) * | 1992-09-17 | 1994-01-25 | Shell Oil Company | Process for the preparation of secondary alkyl sulfate-containing surfactant compositions |
| US5250718A (en) * | 1992-09-28 | 1993-10-05 | Shell Oil Company | Process for the preparation of secondary alkyl sulfate-containing surfactant compositions |
| US5290484A (en) * | 1992-11-12 | 1994-03-01 | Shell Oil Company | Process for the preparation of secondary alkyl sulfate-containing surfactant compositions |
| US5427717A (en) * | 1992-12-15 | 1995-06-27 | Shell Oil Company | Secondary alkyl sulfate/zeolite-containing surfactant compositions |
| US5389277A (en) * | 1993-09-30 | 1995-02-14 | Shell Oil Company | Secondary alkyl sulfate-containing powdered laundry detergent compositions |
| USH1478H (en) * | 1993-09-30 | 1995-09-05 | Shell Oil Company | Secondary alkyl sulfate-containing liquid laundry detergent compositions |
| USH1680H (en) * | 1993-10-27 | 1997-09-02 | Shell Oil Company | Secondary alkyl sulfate-containing hard surface cleaning compositions |
| USH1467H (en) * | 1993-11-16 | 1995-08-01 | Shell Oil Company | Detergent formulations containing a surface active composition containing a nonionic surfactant component and a secondary alkyl sulfate anionic surfactant component |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1200160A (en) | 1959-12-18 |
| NL223297A (en) | |
| NL113406C (en) | 1966-07-15 |
| DE1150382B (en) | 1963-06-20 |
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