GB876956A - Process for the manufacture of highly polymeric copolymers of acetaldehyde - Google Patents

Process for the manufacture of highly polymeric copolymers of acetaldehyde

Info

Publication number
GB876956A
GB876956A GB2299860A GB2299860A GB876956A GB 876956 A GB876956 A GB 876956A GB 2299860 A GB2299860 A GB 2299860A GB 2299860 A GB2299860 A GB 2299860A GB 876956 A GB876956 A GB 876956A
Authority
GB
United Kingdom
Prior art keywords
acetaldehyde
copolymers
specified
manufacture
highly polymeric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2299860A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consortium fuer Elektrochemische Industrie GmbH
Original Assignee
Consortium fuer Elektrochemische Industrie GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consortium fuer Elektrochemische Industrie GmbH filed Critical Consortium fuer Elektrochemische Industrie GmbH
Publication of GB876956A publication Critical patent/GB876956A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/06Catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/18Copolymerisation of aldehydes or ketones
    • C08G2/20Copolymerisation of aldehydes or ketones with other aldehydes or ketones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

Copolymers of acetaldehyde are prepared by copolymerizing a mixture of acetaldehyde with up to 15% of another aldehyde, that contains no multiple bonds or aromatic ring systems in alpha-position to the carbonyl group, at below -30 DEG C. in the presence of an initiator for acetaldehyde polymerization. Specified other aldehydes include formaldehyde, propionaldehyde, butyraldehyde, benzaldehyde, and terpene aldehydes. Acetic acid, boron trifluoride and ammonium persulphate are specified initiators, while unsaturated hydrocarbons, e.g. ethylene, propylene, butylene, isobutylene and cyclohexene, are specified solvents. The copolymers may be cross-linked.
GB2299860A 1959-06-30 1960-06-30 Process for the manufacture of highly polymeric copolymers of acetaldehyde Expired GB876956A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1959C0019318 DE1292394B (en) 1959-06-30 1959-06-30 Process for the preparation of copolymers of acetaldehyde

Publications (1)

Publication Number Publication Date
GB876956A true GB876956A (en) 1961-09-06

Family

ID=7016604

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2299860A Expired GB876956A (en) 1959-06-30 1960-06-30 Process for the manufacture of highly polymeric copolymers of acetaldehyde

Country Status (3)

Country Link
BE (1) BE592462A (en)
DE (1) DE1292394B (en)
GB (1) GB876956A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3215673A (en) * 1961-10-30 1965-11-02 Shell Oil Co Process for polymerizing aldehydes
US3215675A (en) * 1962-07-10 1965-11-02 American Cyanamid Co Carbonyl polymers of dialdehydes and processes for preparing the same
US3272780A (en) * 1960-10-17 1966-09-13 British Industrial Plastics Copolymers of trioxane, another aldehyde having at least two carbon atoms and optionally a third comonomer
US3272778A (en) * 1960-04-26 1966-09-13 Asahi Chemical Ind Process for polymerizing aldehydes
US3278635A (en) * 1961-10-30 1966-10-11 Shell Oil Co Process for polymerizing aldehydes with a coordination complex of (1) a lewis acid and (2) an organic tertiary amine or organic phosphine
US3278490A (en) * 1963-08-05 1966-10-11 Diamond Alkali Co Polychloroaldehydes and process of preparing same
US3278491A (en) * 1962-04-23 1966-10-11 Diamond Alkali Co Stabilized polychloroaldehydes and process of preparing same
US3332913A (en) * 1964-11-02 1967-07-25 Union Carbide Corp Thermally stable copolymers of aldehydes and epoxides
US3350359A (en) * 1962-06-04 1967-10-31 Nippon Synthetic Chem Ind Polymerization of aldehydes
US3499871A (en) * 1960-04-23 1970-03-10 Charbonnages De France Copolymer of formaldehyde and acetaldehyde
EP0001004A1 (en) * 1977-08-22 1979-03-07 Monsanto Company Polymeric acetal carboxylates, a method for their preparation and their use in a detergent composition

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE539475C (en) * 1929-06-12 1931-11-26 Hans Kappeler Dr Process for the production of infusible synthetic masses
CH338306A (en) * 1954-07-13 1959-05-15 Kurth Herbert Process for the production of a water-soluble, liquid precondensate

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3499871A (en) * 1960-04-23 1970-03-10 Charbonnages De France Copolymer of formaldehyde and acetaldehyde
US3272778A (en) * 1960-04-26 1966-09-13 Asahi Chemical Ind Process for polymerizing aldehydes
US3272780A (en) * 1960-10-17 1966-09-13 British Industrial Plastics Copolymers of trioxane, another aldehyde having at least two carbon atoms and optionally a third comonomer
US3215673A (en) * 1961-10-30 1965-11-02 Shell Oil Co Process for polymerizing aldehydes
US3278635A (en) * 1961-10-30 1966-10-11 Shell Oil Co Process for polymerizing aldehydes with a coordination complex of (1) a lewis acid and (2) an organic tertiary amine or organic phosphine
US3278491A (en) * 1962-04-23 1966-10-11 Diamond Alkali Co Stabilized polychloroaldehydes and process of preparing same
US3350359A (en) * 1962-06-04 1967-10-31 Nippon Synthetic Chem Ind Polymerization of aldehydes
US3215675A (en) * 1962-07-10 1965-11-02 American Cyanamid Co Carbonyl polymers of dialdehydes and processes for preparing the same
US3278490A (en) * 1963-08-05 1966-10-11 Diamond Alkali Co Polychloroaldehydes and process of preparing same
US3332913A (en) * 1964-11-02 1967-07-25 Union Carbide Corp Thermally stable copolymers of aldehydes and epoxides
EP0001004A1 (en) * 1977-08-22 1979-03-07 Monsanto Company Polymeric acetal carboxylates, a method for their preparation and their use in a detergent composition

Also Published As

Publication number Publication date
DE1292394B (en) 1969-04-10
BE592462A (en)

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