GB876496A - New monoazo dyestuffs derived from urea or thiourea and the production of the same - Google Patents
New monoazo dyestuffs derived from urea or thiourea and the production of the sameInfo
- Publication number
- GB876496A GB876496A GB1183/59A GB118359A GB876496A GB 876496 A GB876496 A GB 876496A GB 1183/59 A GB1183/59 A GB 1183/59A GB 118359 A GB118359 A GB 118359A GB 876496 A GB876496 A GB 876496A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- dyes
- sulphonic acid
- naphthylamine
- sulphonic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/12—Preparation of azo dyes from other azo compounds by acylation of amino groups
- C09B43/136—Preparation of azo dyes from other azo compounds by acylation of amino groups with polyfunctional acylating agents
- C09B43/155—Preparation of azo dyes from other azo compounds by acylation of amino groups with polyfunctional acylating agents with di- or poly-isocyanates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/12—Preparation of azo dyes from other azo compounds by acylation of amino groups
- C09B43/136—Preparation of azo dyes from other azo compounds by acylation of amino groups with polyfunctional acylating agents
- C09B43/14—Preparation of azo dyes from other azo compounds by acylation of amino groups with polyfunctional acylating agents with phosgene or thiophosgene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/523—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl amido or hydroxyalkyl amino sulfonyl group, a quaternised or non-quaternised amino alkyl sulfonyl amido group, or a substituted alkyl amino sulfonyl group, or a halogen alkyl sulfonyl amido or halogen alkyl amino sulfonyl group or a vinyl sulfonylamido or a substituted vinyl sulfonamido group
- C09B62/527—Azo dyes
- C09B62/53—Monoazo dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention comprises dyes of formula:- <FORM:0876496/IV(c)/1> where X is the residue of a water-soluble monoazo dye, A is O or S, D is an arylene residue which may be substituted, E is an alkylene radical of 2-4 C atoms and Z is Hlg. The dyes are made by treating an aminoarylsulphonic acid halogen-alkylamide and an appropriate amino azo dye with phosgene, thiophosgene or a chloroformic acid ester. Alternatively the dyes may be made by conventional diazotization and coupling processes. Indicated aminoaryl sulphonic acid halogen alkylamides are aniline, aminodiphenyl and naphthylamine sulphonic acid chlor- or brom-alkylamides which may be substituted in the aryl nucleus with such substituents as alkyl, aryl, aralkyl, hydroxy, alkoxy, aroxy, sulphonic acid, sulphonamide, sulphohalogenalkylamide, nitro and halogen groups. Specified reactants from which the diazo residue is derived include 1, 4-diaminobenzene- 3-sulphonic acid and 1, 4-diamino-3-nitro-benzene. Coupling component residues are derived from amino-phenol and -naphthols and aminophenyl-methylpyrazolones and their sulphonic acids, sulphones and sulphonamides. The new dyes may be used on wool or linear polyamides but are particularly effective on natural or regenerated cellulose, especially when used in conjunction with an acid-binding agent. Numerous examples are provided of the preparation of the dyes and their use in dyeing cotton in red and yellow shades the diazo components used including 1-naphthylamine, 2-naphthylamine- 5-sulphonic acid, 1-acetamino-3-aniline- 4-sulphonic acid and 4-aminobenzoic acid. Specification 868,745 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE876496X | 1958-01-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB876496A true GB876496A (en) | 1961-09-06 |
Family
ID=6817709
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1183/59A Expired GB876496A (en) | 1958-01-14 | 1959-01-13 | New monoazo dyestuffs derived from urea or thiourea and the production of the same |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB876496A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4841028A (en) * | 1984-08-30 | 1989-06-20 | Peter Aeschlimann | Reactive dyes comprising a reactive radical bonded to the chromophor by a urea bridge member |
-
1959
- 1959-01-13 GB GB1183/59A patent/GB876496A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4841028A (en) * | 1984-08-30 | 1989-06-20 | Peter Aeschlimann | Reactive dyes comprising a reactive radical bonded to the chromophor by a urea bridge member |
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