GB864768A - Improvements in or relating to the production of deuteriumenriched compounds - Google Patents

Improvements in or relating to the production of deuteriumenriched compounds

Info

Publication number
GB864768A
GB864768A GB23936/56A GB2393656A GB864768A GB 864768 A GB864768 A GB 864768A GB 23936/56 A GB23936/56 A GB 23936/56A GB 2393656 A GB2393656 A GB 2393656A GB 864768 A GB864768 A GB 864768A
Authority
GB
United Kingdom
Prior art keywords
enriched
withdrawn
passed
deuterium
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23936/56A
Inventor
Peter Thomas Walker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UK Atomic Energy Authority
Original Assignee
UK Atomic Energy Authority
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UK Atomic Energy Authority filed Critical UK Atomic Energy Authority
Priority to GB23936/56A priority Critical patent/GB864768A/en
Priority to DEU4685A priority patent/DE1129135B/en
Priority to ES0236899A priority patent/ES236899A1/en
Publication of GB864768A publication Critical patent/GB864768A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B4/00—Hydrogen isotopes; Inorganic compounds thereof prepared by isotope exchange, e.g. NH3 + D2 → NH2D + HD
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

<PICT:0864768/III/1> In the production of deuterium-enriched hydrogen or ammonia by contacting hydrogen with a counter-current of liquid ammonia containing a homogeneous catalyst in a dual temperature isotopic exchange process, the deuterium-depleted H2 leaving the cold tower is regenerated by contacting with steam of natural deuterium content in the presence of a catalyst. As shown liquid NH3 containing potassamide and a counter-current of H2 are passed continuously in series through cold and hot towers working at 50 atms. and-60 DEG C. and 30 DEG C., respectively. Heat is added at X and withdrawn at O in the circuits possibly by interlinking. Enriched hydrogen is withdrawn at B and passed to distillation at-225 DEG C., whence a highly-enriched fraction is recovered and combined with O2 to form heavy water, and a depleted fraction is passed into the H2 cycle. The H2 is regenerated by contact with steam at 550 DEG C. before return to the hot tower. Alternatively, enriched NH3 may be withdrawn at A and distilled to isolate an enriched fraction.
GB23936/56A 1956-08-02 1956-08-02 Improvements in or relating to the production of deuteriumenriched compounds Expired GB864768A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB23936/56A GB864768A (en) 1956-08-02 1956-08-02 Improvements in or relating to the production of deuteriumenriched compounds
DEU4685A DE1129135B (en) 1956-08-02 1957-07-29 Process for the production of hydrogen or ammonia enriched in deuterium
ES0236899A ES236899A1 (en) 1956-08-02 1957-07-31 Improvements in or relating to the production of deuteriumenriched compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB23936/56A GB864768A (en) 1956-08-02 1956-08-02 Improvements in or relating to the production of deuteriumenriched compounds

Publications (1)

Publication Number Publication Date
GB864768A true GB864768A (en) 1961-04-06

Family

ID=10203718

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23936/56A Expired GB864768A (en) 1956-08-02 1956-08-02 Improvements in or relating to the production of deuteriumenriched compounds

Country Status (3)

Country Link
DE (1) DE1129135B (en)
ES (1) ES236899A1 (en)
GB (1) GB864768A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115215498B (en) * 2022-08-02 2023-09-12 苏州思萃同位素技术研究所有限公司 Device, method and application for hydrogen isotope wastewater treatment and resource utilization

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2690379A (en) * 1942-11-21 1954-09-28 Harold C Urey Process for production of deuterium oxide as a source of deuterium

Also Published As

Publication number Publication date
DE1129135B (en) 1962-05-10
ES236899A1 (en) 1958-03-16

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