GB861404A - Improvements in quick-drying vehicles, particularly printing inks - Google Patents
Improvements in quick-drying vehicles, particularly printing inksInfo
- Publication number
- GB861404A GB861404A GB360259A GB360259A GB861404A GB 861404 A GB861404 A GB 861404A GB 360259 A GB360259 A GB 360259A GB 360259 A GB360259 A GB 360259A GB 861404 A GB861404 A GB 861404A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- acrylamide
- monomers
- methyl methacrylate
- drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000001035 drying Methods 0.000 title abstract 8
- 239000000976 ink Substances 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 10
- 239000003921 oil Substances 0.000 abstract 10
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 8
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 6
- 239000003638 chemical reducing agent Substances 0.000 abstract 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 4
- 239000002383 tung oil Substances 0.000 abstract 4
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 abstract 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 abstract 3
- 229910021626 Tin(II) chloride Inorganic materials 0.000 abstract 3
- 239000000975 dye Substances 0.000 abstract 3
- 150000002978 peroxides Chemical class 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- 235000011150 stannous chloride Nutrition 0.000 abstract 3
- 239000001119 stannous chloride Substances 0.000 abstract 3
- 239000003981 vehicle Substances 0.000 abstract 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 abstract 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 abstract 2
- 235000010323 ascorbic acid Nutrition 0.000 abstract 2
- 229960005070 ascorbic acid Drugs 0.000 abstract 2
- 239000011668 ascorbic acid Substances 0.000 abstract 2
- 239000008199 coating composition Substances 0.000 abstract 2
- 238000004132 cross linking Methods 0.000 abstract 2
- ZGCHATBSUIJLRL-UHFFFAOYSA-N hydrazine sulfate Chemical compound NN.OS(O)(=O)=O ZGCHATBSUIJLRL-UHFFFAOYSA-N 0.000 abstract 2
- 230000000977 initiatory effect Effects 0.000 abstract 2
- HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 abstract 2
- 229940067157 phenylhydrazine Drugs 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 229940013123 stannous chloride Drugs 0.000 abstract 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 abstract 2
- KKAJSJJFBSOMGS-UHFFFAOYSA-N 3,6-diamino-10-methylacridinium chloride Chemical compound [Cl-].C1=C(N)C=C2[N+](C)=C(C=C(N)C=C3)C3=CC2=C1 KKAJSJJFBSOMGS-UHFFFAOYSA-N 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 229940023020 acriflavine Drugs 0.000 abstract 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 1
- 239000000298 carbocyanine Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000002687 nonaqueous vehicle Substances 0.000 abstract 1
- 150000004893 oxazines Chemical class 0.000 abstract 1
- QWYZFXLSWMXLDM-UHFFFAOYSA-M pinacyanol iodide Chemical compound [I-].C1=CC2=CC=CC=C2N(CC)C1=CC=CC1=CC=C(C=CC=C2)C2=[N+]1CC QWYZFXLSWMXLDM-UHFFFAOYSA-M 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F7/00—Chemical modification of drying oils
- C09F7/06—Chemical modification of drying oils by polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Polymerization Catalysts (AREA)
Abstract
Non-aqueous quick-drying vehicles for coating compositions, e.g. printing inks, comprise a drying oil with conjugated double bonds, an oil-soluble dye capable of initiating polymerization of the oil when activated by cold energy irradiation (e.g. ultra-violet light or alpha rays), and preferably a monomer, a reducing agent and a peroxide. Suitable monomers are methyl methacrylate, acrylonitrile, styrene, vinyl acetate, vinyl chloride and methyl acrylate. Certain monomers, e.g. acrylamide and N-vinyl pyrrolidone are themselves reducing agents and can be used without another reducing agent. A crosslinking monomer, e.g. divinyl benzene may also be included. Suitable reducing agents are stannous chloride, ascorbic acid, phenylhydrazine, ferrous salts, chromous salts, hydroxylamine, thiourea and hydrazine sulphate. Suitable peroxides are benzoyl, lauroyl, tert.-butyl hydro-, methyl ethyl ketone, or tert.-butyl perbenzoate. The preferred oil is bodied tung oil. It may be used together with other drying oils, or styrenated drying oils. Solvents may be included, or excess of a monomer may act as a solvent (Example 1). In examples, vehicles based on bodied tungoil with or without other drying oils also include monomers as follows: (1), (2), (3), (4), (6), (7) and (8) methyl methacrylate and acrylamide, (5) acrylamide, (9) methyl methacrylate, divinyl benzene and acrylamide, (10)-(13) styrene, (14), (15) N-vinyl pyrrolidone, p (16), (17) methyl methacrylate, (18), (19) acrylonitrile, (20)-(22) acrylamide. U.S.A. Specifications 2,453,769 and 2,453,770 are referred to.ALSO:A non-aqueous vehicle for coating compositions comprises a drying oil with conjugated unsaturation and an oil-soluble dye capable of initiating rapid polymerization of the oil when activated by irradiation with cold energy such as ultraviolet light or alpha rays. The preferred oil is tung oil, alone or together with other drying oils. Suitable dyes are of the phthalein, acridine, triphenyl-methane, carbocyanine or oxazine class. Many examples are given. Polymerizable monomers such as acrylamide, methyl methacrylate, acrylonitrile, styrene, vinyl acetate, vinyl chloride or methyl acrylate and reducing agents, e.g. stannous chloride, ascorbic acid, phenylhydrazine, ferrous salts, chromous salts, hydroxylamine, thiourea or hydrazine sulphate may be included in the compositions. Solvents for the monomers, e.g. methyl alcohol, ethylene glycol or polyethylene glycol may also be added. Certain monomers, e.g. N-vinyl pyrrolidone or acrylamide may also act as reducing agents. Cross-linking monomers, e.g. divinyl benzene may also be used. Desirably a peroxide catalyst may also be present. A typical example of a vehicle, selected from a large number in the Specification, contains bodied tung oil, tert.-butyl perbenzoate, methyl methacrylate, acrylamide, methanol, acriflavine and stannous chloride. U.S.A. Specifications 2,453,769 and 2,453,770 are referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB360259A GB861404A (en) | 1959-02-02 | 1959-02-02 | Improvements in quick-drying vehicles, particularly printing inks |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB360259A GB861404A (en) | 1959-02-02 | 1959-02-02 | Improvements in quick-drying vehicles, particularly printing inks |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB861404A true GB861404A (en) | 1961-02-22 |
Family
ID=9761427
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB360259A Expired GB861404A (en) | 1959-02-02 | 1959-02-02 | Improvements in quick-drying vehicles, particularly printing inks |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB861404A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4395301A (en) | 1979-10-18 | 1983-07-26 | Usm Corporation | Adhesive compositions and method |
-
1959
- 1959-02-02 GB GB360259A patent/GB861404A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4395301A (en) | 1979-10-18 | 1983-07-26 | Usm Corporation | Adhesive compositions and method |
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