GB861378A - Production of new compositions from glyoxal and alkali metal silicates - Google Patents

Production of new compositions from glyoxal and alkali metal silicates

Info

Publication number
GB861378A
GB861378A GB3944157A GB3944157A GB861378A GB 861378 A GB861378 A GB 861378A GB 3944157 A GB3944157 A GB 3944157A GB 3944157 A GB3944157 A GB 3944157A GB 861378 A GB861378 A GB 861378A
Authority
GB
United Kingdom
Prior art keywords
glyoxal
alkali metal
metal silicate
aqueous solution
silicate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3944157A
Inventor
Louis Gandon
Rene Leon Lehmann
Henri Georges Louis Marcheguet
Francis Paul Marie Tarbouriech
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nobel Bozel SA
Original Assignee
Nobel Bozel SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nobel Bozel SA filed Critical Nobel Bozel SA
Publication of GB861378A publication Critical patent/GB861378A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
    • B22C1/167—Mixtures of inorganic and organic binding agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
    • B22C1/18—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents
    • B22C1/183—Sols, colloids or hydroxide gels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C3/00—Selection of compositions for coating the surfaces of moulds, cores, or patterns
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/126—Preparation of silica of undetermined type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/141—Preparation of hydrosols or aqueous dispersions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/141—Preparation of hydrosols or aqueous dispersions
    • C01B33/142—Preparation of hydrosols or aqueous dispersions by acidic treatment of silicates
    • C01B33/143—Preparation of hydrosols or aqueous dispersions by acidic treatment of silicates of aqueous solutions of silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/145—Preparation of hydroorganosols, organosols or dispersions in an organic medium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/32—Alkali metal silicates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/008—Sludge treatment by fixation or solidification
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/008—Aldehydes, ketones
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26—Silicates of the alkali metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00—Soil-conditioning materials or soil-stabilising materials
    • C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • C09K17/42—Inorganic compounds mixed with organic active ingredients, e.g. accelerators
    • C09K17/46—Inorganic compounds mixed with organic active ingredients, e.g. accelerators the inorganic compound being a water-soluble silicate
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/14—Agglomerating; Briquetting; Binding; Granulating
    • C22B1/24—Binding; Briquetting ; Granulating
    • C22B1/242—Binding; Briquetting ; Granulating with binders
    • C22B1/244—Binding; Briquetting ; Granulating with binders organic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Structural Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Soil Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Water Supply & Treatment (AREA)
  • Textile Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Paper (AREA)
  • Paints Or Removers (AREA)

Abstract

Glyoxal in aqueous medium is reacted with an alkali metal silicate to give a sol which will set to a hardenable gel. The glyoxal/silica mixture is suitable for incorporation as a filler in rubber latex; data given indicate that the vulcanizates produced have enhanced modulus at 300% and resistance to tearing (Example 6).ALSO:Glyoxal in aqueous medium is reacted with an alkali metal silicate to give a sol which will set to a hardenable gel. The glyoxal/silica mixture is suitable for the tanning of gelatine.ALSO:Glyoxal in aqueous medium is reacted with an alkali metal silicate to give a sol which will set to a hardenable gel. The glyoxal/silica mixture is suitable for the impregnation of viscose rayon crepe de chine to give improved weight, swelling and warp shrinkage effects as well as a permanent matting of the fabric.ALSO:Glyoxal in aqueous medium is reacted with an alkali metal silicate to give a sol which will set to a hardenable gel. The alkali metal silicate may be employed in the form of a commercial aqueous solution of sodium or potassium silicate, e.g. in which the ratio between the number of molecules of SiO2 and the number of molecules of Na2O ranges from 3 to 4 and the aqueous solution of sodium silicate may have a strength of from 35 DEG to 50 DEG Be; or the commercial aqueous solution of the alkali metal silicate may be diluted. The glyoxal is employed in the form of a neutral aqueous solution, for example 30%, preferably in a proportion corresponding to about 5 to 20 parts by weight of this latter solution for 100 parts by weight of 36 DEG Be commercial sodium silicate solution. In a modification of the process stable siliceous hydrosols are produced by mixing glyoxal and an aqueous solution of an acid and introducing into this acid glyoxal solution an aqueous solution of alkali metal silicate, the proportions so adjusted as to form a hydrosol which is weakly acid, if necessary in a pH region approaching neutrality.ALSO:Glyoxal in aqueous medium is reacted with an alkali metal silicate to give a sol which will set to a hardenable gel. Exemplified use is the conversion of waste water into hard removable masses by adding the mixture to nitric acid, sugar and molasses waste.ALSO:Glyexal in aqueous sodium is reacted with an alkali metal silicate to give a sol which will set to a hardenable gel. The alkali metal silicate may be employed in the form of a commercial aqueous solution of sodium or potassium silicate, e.g. in which the ratio between the number of molecules of SiO2 and the number of molecules of Na2O ranges from 3 to 4 and the aqueous solution of sodium silicate may have a strength of from 35 DEG to 50 DEG Be; or the commercial aqueous solution of the alkali metal silicate may be diluted. The glyoxal is employed in the form of a neutral aqueous solution, for example 30%, preferably in a proportion corresponding to about 5 to 20 parts by weight of this latter solution for 100 parts by weight of 36 DEG Be commercial sodium silicate solution. Kaolin or potatoe starch may be added to the reactants to accelerate the hardening.
GB3944157A 1956-12-28 1957-12-19 Production of new compositions from glyoxal and alkali metal silicates Expired GB861378A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR728624 1956-12-28
FR739662 1957-05-28
FR741523 1957-06-21

Publications (1)

Publication Number Publication Date
GB861378A true GB861378A (en) 1961-02-22

Family

ID=27245092

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3944157A Expired GB861378A (en) 1956-12-28 1957-12-19 Production of new compositions from glyoxal and alkali metal silicates

Country Status (5)

Country Link
BE (1) BE563574A (en)
CH (1) CH382722A (en)
DE (1) DE1112940B (en)
GB (1) GB861378A (en)
NL (2) NL223562A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2170839A (en) * 1985-02-11 1986-08-13 Labofina Sa Process for consolidating soils
EP2091888A2 (en) * 2006-11-10 2009-08-26 Buntrock Industries, Inc. Mold system for the casting of reactive alloys

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3782982A (en) * 1970-06-12 1974-01-01 Corning Glass Works Products prepared from soluble silicate solutions
DE3538791A1 (en) * 1985-10-31 1987-05-07 Webac Chemie Gmbh Process for hardening of waterglass solutions and hardening system for this purpose
DE102004006612A1 (en) 2004-02-10 2005-08-25 Degussa Ag Compound ceramic wall coating comprises a carrier layer and at least one ceramic layer containing ceramic particles which are chosen from a group of oxides, nitrides, borides or carbides of metal or semi-metals
US9096041B2 (en) 2004-02-10 2015-08-04 Evonik Degussa Gmbh Method for coating substrates and carrier substrates

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2170839A (en) * 1985-02-11 1986-08-13 Labofina Sa Process for consolidating soils
GB2170845A (en) * 1985-02-11 1986-08-13 Labofina Sa Process for consolidating soils
EP2091888A2 (en) * 2006-11-10 2009-08-26 Buntrock Industries, Inc. Mold system for the casting of reactive alloys
EP2091888A4 (en) * 2006-11-10 2011-06-29 Buntrock Ind Inc Mold system for the casting of reactive alloys
US8980778B2 (en) 2006-11-10 2015-03-17 Buntrock Industries, Inc. Mold system for casting of reactive alloys

Also Published As

Publication number Publication date
BE563574A (en)
DE1112940B (en) 1961-08-17
NL113111C (en)
CH382722A (en) 1964-10-15
NL223562A (en)

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