GB859737A - Phosphonic and thiophosphonic esters and compositions containing them - Google Patents
Phosphonic and thiophosphonic esters and compositions containing themInfo
- Publication number
- GB859737A GB859737A GB34662/57A GB3466257A GB859737A GB 859737 A GB859737 A GB 859737A GB 34662/57 A GB34662/57 A GB 34662/57A GB 3466257 A GB3466257 A GB 3466257A GB 859737 A GB859737 A GB 859737A
- Authority
- GB
- United Kingdom
- Prior art keywords
- general formula
- compound
- halogen atom
- esters
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002148 esters Chemical class 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 8
- 125000005843 halogen group Chemical group 0.000 abstract 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 230000000590 parasiticidal effect Effects 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 abstract 1
- 239000011149 active material Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 abstract 1
- 125000005337 azoxy group Chemical group [N+]([O-])(=N*)* 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 150000004045 organic chlorine compounds Chemical class 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 239000000454 talc Substances 0.000 abstract 1
- 229910052623 talc Inorganic materials 0.000 abstract 1
- -1 thiocyanacetates Chemical class 0.000 abstract 1
- 150000003567 thiocyanates Chemical class 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/12—Esters of phosphoric acids with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention comprises compounds of the general formula: <FORM:0859737/IV(b)/1> (wherein R is a C1-4 lower alkyl group; R1 is a hydrogen or halogen atom or -NO2, -OCH3, -OC2H5 or -CH3; X is an oxygen or sulphur atom; and Q is -N = N or <FORM:0859737/IV(b)/2> ), and the preparation thereof by reacting a compound of the general formula: <FORM:0859737/IV(b)/3> (wherein Y is a halogen atom) with a compound of the general formula: <FORM:0859737/IV(b)/4> The thiophosphoric esters can be converted into the corresponding phosphoric esters by reaction with oxidising agents; and the azo group can be converted into the azoxy group by reacting the phosphoric esters with hydrogen peroxide.ALSO:The invention comprises compounds of the general formula: <FORM:0859737/IV (c)/1> (wherein R is a C1-4 lower alkyl group; R1 is a hydrogen or halogen atom or -NO2, -OCH3, -OC2H5 or -CH3; X is an oxygen or sulphur atom; and Q is -N=N-), and the preparation thereof by reacting a compound of the general formula: <FORM:0859737/IV (c)/2> (wherein Y is a halogen atom) with a compound of the general formula: <FORM:0859737/IV (c)/3> Compounds of the invention having an orange, red or yellow colour are disclosed.ALSO:Parasiticidal compositions comprise at least one compound of the general formula: <FORM:0859737/VI/1> (wherein R is a C1-4 lower alkyl group; hydrogen or halogen atom or -NO2, -OCH3, -OC2H5 or -CH3; X is an oxygen or sulphur atom; and Q is -N=N- or <FORM:0859737/VI/2> -(and a compatible carrier therefor and/or one or more other substances having parasiticidal or fertilising properties. In particular, fly-killing compositions may contain additional fly-killing substances selected from organic chlorine compounds, phosphoric and thiophosphoric esters, thiocyanates, thiocyanacetates, pyrethrum esters and synthetic pyrethains. Adhesives, dispersing agents and wetting agents may be incorporated if desired. Suitable carriers are liquids wherein the active material may be dispersed or dissolved, e.g. in the form of self-emulsifying concentrates; semi-solids adapted to give a paste-like consistency; and particulate solids like talc.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT859737X | 1956-11-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB859737A true GB859737A (en) | 1961-01-25 |
Family
ID=11329846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB34662/57A Expired GB859737A (en) | 1956-11-07 | 1957-11-06 | Phosphonic and thiophosphonic esters and compositions containing them |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB859737A (en) |
-
1957
- 1957-11-06 GB GB34662/57A patent/GB859737A/en not_active Expired
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