GB859295A - A process for stabilising siloxane polymers - Google Patents

A process for stabilising siloxane polymers

Info

Publication number
GB859295A
GB859295A GB9045/59A GB904559A GB859295A GB 859295 A GB859295 A GB 859295A GB 9045/59 A GB9045/59 A GB 9045/59A GB 904559 A GB904559 A GB 904559A GB 859295 A GB859295 A GB 859295A
Authority
GB
United Kingdom
Prior art keywords
siloxane
resin
ion exchange
quarternary ammonium
exchange resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9045/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Midland Silicones Ltd
Original Assignee
Midland Silicones Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Midland Silicones Ltd filed Critical Midland Silicones Ltd
Publication of GB859295A publication Critical patent/GB859295A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/06Preparatory processes
    • C08G77/08Preparatory processes characterised by the catalysts used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/32Post-polymerisation treatment
    • C08G77/34Purification
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

A polysiloxane containing an alkaline catalyst is stabilised by contacting it with an ion exchange resin containing sulphonic acid groups, the resin being used in amount sufficient to remove the alkali from the siloxane. The siloxanes may contain alkyl, alkenyl, cycloaliphatic, aromatic or halogenated hydrocarbon radicals. The process is preferably effected by adding the siloxane to a suspension of the ion exchange resin, e.g. a sulphonated polystyrene or phenolaldehyde resin, in a solvent for the siloxane, e.g. acetone or toluene. Catalysts, e.g. alkali metal hydroxides; Li Na, K and Cs silanolates; quarternary ammonium hydroxides and quarternary ammonium salts of silanols, can be removed in the above manner. Examples are given.
GB9045/59A 1958-04-09 1959-03-16 A process for stabilising siloxane polymers Expired GB859295A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US859295XA 1958-04-09 1958-04-09

Publications (1)

Publication Number Publication Date
GB859295A true GB859295A (en) 1961-01-18

Family

ID=22194915

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9045/59A Expired GB859295A (en) 1958-04-09 1959-03-16 A process for stabilising siloxane polymers

Country Status (1)

Country Link
GB (1) GB859295A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0129318A1 (en) * 1983-06-15 1984-12-27 Dow Corning Corporation Neutralization of alkali metal catalysts in organopolysiloxanes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0129318A1 (en) * 1983-06-15 1984-12-27 Dow Corning Corporation Neutralization of alkali metal catalysts in organopolysiloxanes

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