GB857501A - New dipyridyl derivatives - Google Patents

New dipyridyl derivatives

Info

Publication number
GB857501A
GB857501A GB1287058A GB1287058A GB857501A GB 857501 A GB857501 A GB 857501A GB 1287058 A GB1287058 A GB 1287058A GB 1287058 A GB1287058 A GB 1287058A GB 857501 A GB857501 A GB 857501A
Authority
GB
United Kingdom
Prior art keywords
compositions
stands
formula
dipyridyl
radical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1287058A
Inventor
Ronald Frederick Homer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB1287058A priority Critical patent/GB857501A/en
Publication of GB857501A publication Critical patent/GB857501A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D471/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/12Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains three hetero rings
    • C07D471/14Ortho-condensed systems

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention comprises dipyridyl derivatives of the formula: <FORM:0857501/IV(b)/1> wherein R represents a branched or unbranched, saturated or unsaturated alkyl radical located at positions 4 or 5, and 41 or 51 and X stands for an anionic radical, such as chloride, bromide, iodide and p-toluenesulphonate radicals. The novel compounds may be prepared by interaction of the corresponding di-substituted a , a 1-dipyridyl with an ethylene glycol di-ester. The reaction may be effected by heating the reagents together alone or in the presence of an inert solvent or diluent, for example nitrobenzene or b -ethoxyethanol. Certain of the new dipyridyl derivatives may be obtained by reacting a salt of the formula: <FORM:0857501/IV(b)/2> in which Y is an anionic radical with a salt derived from an anionic radical X, e.g., silver iodide, or silver chloride. The new compounds may be used in herbicidal compositions.ALSO:Herbicidal compositions contain, as the active herbicidal ingredient, one or more dipyridyl derivatives of the formula: <FORM:0857501/VI/1> wherein R stands for a branched or unbranched saturated or unsaturated alkyl radical located at positions 4 or 5 and 41 or 51, and X stands for an anionic radical such as chlorine, bromine, iodine or p-toluensulphonate radicals. (For preparation see Group IV(b)). The compositions may be liquid compositions, for example aqueous solutions of the active ingredients. Wetting agents such as alkali metal salts of dinaphthylmethane disulphonic acids, alkali metal salts of long chain aliphatic sulphates, and condensation products of ethylene oxide with an alkyl phenol, and/or humectants, for example, calcium chloride, glycerol, ethylene glycol and water-soluble polyethylene glycols, may be present. Agents which improve the adhering properties of the composition to the plant, such as sodium carboxymethylcellulose and ammonium polymethacrylate may also be present. The compositions may also be solids containing inert pulverulent diluents such as talc, china clay, gypsum, basic slag, kieselguhr, bentonite or other colloidal clays.
GB1287058A 1958-04-23 1958-04-23 New dipyridyl derivatives Expired GB857501A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1287058A GB857501A (en) 1958-04-23 1958-04-23 New dipyridyl derivatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1287058A GB857501A (en) 1958-04-23 1958-04-23 New dipyridyl derivatives

Publications (1)

Publication Number Publication Date
GB857501A true GB857501A (en) 1960-12-29

Family

ID=10012651

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1287058A Expired GB857501A (en) 1958-04-23 1958-04-23 New dipyridyl derivatives

Country Status (1)

Country Link
GB (1) GB857501A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1213665B (en) * 1955-06-15 1966-03-31 Ici Ltd Selective herbicides

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1213665B (en) * 1955-06-15 1966-03-31 Ici Ltd Selective herbicides

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