GB854613A - Improvements in and relating to rubber compositions - Google Patents
Improvements in and relating to rubber compositionsInfo
- Publication number
- GB854613A GB854613A GB13085/56A GB1308556A GB854613A GB 854613 A GB854613 A GB 854613A GB 13085/56 A GB13085/56 A GB 13085/56A GB 1308556 A GB1308556 A GB 1308556A GB 854613 A GB854613 A GB 854613A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formaldehyde
- condensation catalyst
- compound
- heating
- hexamethylene tetramine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/02—Condensation polymers of aldehydes or ketones only
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
In the preparation of a vulcanizable composition, carbon black, formaldehyde or a compound which releases formaldehyde on heating and a condensation catalyst are dispersed in natural or synthetic rubber, in the absence of extraneous formaldehyde-reactive materials, and the mixture is subjected to a heat treatment without vulcanizing it. The synthetic rubber may consist of a polymer of a conjugated diene, e.g. polybutadiene, or a copolymer such as butadiene - acrylonitrile, butadienestyrene, or isobutylene - butadiene copolymers, or a polymer of a substituted conjugated diene containing the group CH2 : C.Cl, e.g. polychloroprene. Vulcanizable reclaims of such rubbers and compositions of such rubbers containing extender oils may also be used. The heat treatment may be effected at 100 DEG to 200 DEG C. for a period of 2,5 to 40 minutes, preferably at 140 DEG to 160 DEG C. for 10 to 25 minutes. The mixture may comprise, in parts by weight, rubber 100, formaldehyde 0,1 to 10, preferably 1 to 2, carbon black 5 to 150, preferably 5 to 75, and condensation catalyst 0,1 to 0,5. The compound which liberates formaldehyde on heating may comprise formaldehyde, metaformaldehyde, or hexamethylene tetramine. A separate condensation catalyst is not required when hexamethylene tetramine is used since the ammonia liberated by that compound on heating functions as a condensation catalyst. When hexamethylene tetramine is not used the condensation catalyst may consist of aluminium chloride. Examples are described illustrating that vulcanizates having high values of hardness and resilience are obtained by the vulcanization of compositions prepared by the process according to the invention from mixtures comprising natural rubber or butadiene styrene copolymer.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB13085/56A GB854613A (en) | 1956-04-28 | 1956-04-28 | Improvements in and relating to rubber compositions |
DED25510A DE1133882B (en) | 1956-04-28 | 1957-04-29 | Process for the production of vulcanizable rubber compounds with improved properties |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB13085/56A GB854613A (en) | 1956-04-28 | 1956-04-28 | Improvements in and relating to rubber compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB854613A true GB854613A (en) | 1960-11-23 |
Family
ID=10016558
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB13085/56A Expired GB854613A (en) | 1956-04-28 | 1956-04-28 | Improvements in and relating to rubber compositions |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1133882B (en) |
GB (1) | GB854613A (en) |
-
1956
- 1956-04-28 GB GB13085/56A patent/GB854613A/en not_active Expired
-
1957
- 1957-04-29 DE DED25510A patent/DE1133882B/en active Pending
Also Published As
Publication number | Publication date |
---|---|
DE1133882B (en) | 1962-07-26 |
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