GB847414A - Silicone compositions for imparting water-repellency - Google Patents

Silicone compositions for imparting water-repellency

Info

Publication number
GB847414A
GB847414A GB1548/58A GB154858A GB847414A GB 847414 A GB847414 A GB 847414A GB 1548/58 A GB1548/58 A GB 1548/58A GB 154858 A GB154858 A GB 154858A GB 847414 A GB847414 A GB 847414A
Authority
GB
United Kingdom
Prior art keywords
diol
amine
propane
reacted
amino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1548/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Chemicals Ltd
Original Assignee
Monsanto Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Chemicals Ltd filed Critical Monsanto Chemicals Ltd
Publication of GB847414A publication Critical patent/GB847414A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups

Abstract

Compositions suitable for imparting waterrepellency to a material comprise an aqueous silicone emulsion incorporating a catalyst obtained by reacting an inorganic metal salt with an amine and, if desired, with a polyhydric alcohol (see Group IV(b)). The silicone may be a resin or an oil and contains alkyl groups, alkenyl groups or aryl groups ; good results are given by silicones of the formula Rx Hg Si O2- 1/2 (x + g ) where x + y is 1,2-2,1 and y can be zero, and R is methyl, ethyl, amyl, vinyl or phenyl ; mixtures of these groups may be present. The compositions may contain emulsifying agents. Specifications 723,989, 804,989, 804,990, 812,505 and 823,760 are referred to.ALSO:Catalysts suitable for use in compositions for imparting water-repellency to a material (see Group IV(a) are the products obtained by reacting an inorganic metal salt with an amine; if desired, a polyhydric alcohol may also be reacted, either before or during the reaction with the amine, and in this case the products are claimed as novel. The preferred metal salts are the halides, specified metals being Ti, Zr, Al, Sr, Zn, Ca, K, Na and Li. Specified amines are isobutylamine, octylamine, cyclo hexylamine, morpholine, and amino-alcohols such as 2-aminobutanol, 2-amino-2-methyl-1, 3-propanediol, 2-amino-2-ethyl-1, 3-propane-diol, and mono-,di-, and triethanolamines and -iso propanolamines. Specified polyhydric alcohols are ethylene glycol, diethyleneglycol, polyethylene glycols, 1, 2-propane-diol,1, 3-propane-diol, 1, 3-butane-diol, 2, 3-butane-diol, and butanetriols. The catalysts may be prepared by treating 1 mole of the inorganic salt with 2-6 moles of the amine, e.g. at 170-205 DEG C., until the product is substantially soluble in water; if used, 1-6 moles of polyhydric alcohol may be employed per 1 mole of metal salt; e.g. the salt and alcohol are reacted at 100-130 DEG C., and then reacted at 170-200 DEG C. with the amine. However, heating is not essential, and preferably the temperature is kept below 70 DEG C. Specifications 723,989, 804,989, 804,990, 812,505 and 823,760 are referred to.
GB1548/58A 1957-02-15 1958-01-16 Silicone compositions for imparting water-repellency Expired GB847414A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BE847414X 1957-02-15

Publications (1)

Publication Number Publication Date
GB847414A true GB847414A (en) 1960-09-07

Family

ID=3882041

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1548/58A Expired GB847414A (en) 1957-02-15 1958-01-16 Silicone compositions for imparting water-repellency

Country Status (3)

Country Link
BE (2) BE558782A (en)
FR (1) FR1212044A (en)
GB (1) GB847414A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1205279B (en) * 1963-10-31 1965-11-18 Wacker Chemie Gmbh Process for the preparation of organopolysiloxane elastomers
FR2013410A1 (en) * 1968-07-20 1970-04-03 Kanegafuchi Spinning Co Ltd

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1205279B (en) * 1963-10-31 1965-11-18 Wacker Chemie Gmbh Process for the preparation of organopolysiloxane elastomers
FR2013410A1 (en) * 1968-07-20 1970-04-03 Kanegafuchi Spinning Co Ltd

Also Published As

Publication number Publication date
FR1212044A (en) 1960-03-21
BE558782A (en)
BE555021A (en)

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