GB835896A - New aryloxazolyl-ethylene derivatives and process for their manufacture - Google Patents

New aryloxazolyl-ethylene derivatives and process for their manufacture

Info

Publication number
GB835896A
GB835896A GB1868556A GB1868556A GB835896A GB 835896 A GB835896 A GB 835896A GB 1868556 A GB1868556 A GB 1868556A GB 1868556 A GB1868556 A GB 1868556A GB 835896 A GB835896 A GB 835896A
Authority
GB
United Kingdom
Prior art keywords
aryloxazolyl
ethylenes
give
ethylene derivatives
new
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1868556A
Inventor
Adolf-Emil Siegrist
Franz Ackermann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba AG filed Critical Ciba AG
Priority to GB1868556A priority Critical patent/GB835896A/en
Publication of GB835896A publication Critical patent/GB835896A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D263/00Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • C07D263/62Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

The invention comprises new aryloxazolyl-ethylene derivatives of formula <FORM:0835896/IV (b)/1> in which R1 and R2 each represent an alkyl residue. They may be produced by heating two molecular proportions of an ortho-hydroxy-aminoaryl compound with one molecular proportion of thiomalic acid or an alkyl mono- or di-ester thereof. The reaction is advantageously carried out in the temperature range 100-200 DEG C. in an inert organic solvent such as monochlorbenzene, dichlorbenzenes, trichlorbenzenes, nitrobenzenes, toluene, xylenes or cumene. The compounds formed may be treated with agents capable of splitting off water to give di(aryloxazolyl)-ethylenes in accordance with the process described and claimed in Specification 835,897. In the examples details are given of the preparation of <FORM:0835896/IV (b)/2> <FORM:0835896/IV (b)/3> and <FORM:0835896/IV (b)/4> These compounds when heated with zinc chloride lose water to give the corresponding a ,b -di-[benzoxazolyl-(2)]-ethylenes.
GB1868556A 1956-06-15 1956-06-15 New aryloxazolyl-ethylene derivatives and process for their manufacture Expired GB835896A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1868556A GB835896A (en) 1956-06-15 1956-06-15 New aryloxazolyl-ethylene derivatives and process for their manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1868556A GB835896A (en) 1956-06-15 1956-06-15 New aryloxazolyl-ethylene derivatives and process for their manufacture

Publications (1)

Publication Number Publication Date
GB835896A true GB835896A (en) 1960-05-25

Family

ID=10116658

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1868556A Expired GB835896A (en) 1956-06-15 1956-06-15 New aryloxazolyl-ethylene derivatives and process for their manufacture

Country Status (1)

Country Link
GB (1) GB835896A (en)

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