GB821941A - A method of lubricating relatively moving parts - Google Patents

A method of lubricating relatively moving parts

Info

Publication number
GB821941A
GB821941A GB34453/55A GB3445355A GB821941A GB 821941 A GB821941 A GB 821941A GB 34453/55 A GB34453/55 A GB 34453/55A GB 3445355 A GB3445355 A GB 3445355A GB 821941 A GB821941 A GB 821941A
Authority
GB
United Kingdom
Prior art keywords
ester
esters
alcohol
integer
acetylenic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB34453/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Airco Inc
Original Assignee
Air Reduction Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Reduction Co Inc filed Critical Air Reduction Co Inc
Publication of GB821941A publication Critical patent/GB821941A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M3/00Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/34Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Lubricants (AREA)

Abstract

A method of lubricating relatively moving parts comprises using as lubricant either a substantially neutral ester corresponding to the general formula <FORM:0821941/III/1> where x is an integer from 2 to 8, R1 and R2 are hydrogen or alkyl radicals, n is an integer including O and the radical of the acetylenic alcohol from which the ester is derived contains from 3 to 10 carbon atoms in its longest carbon chain which chain includes the terminal ethinyl group and is linked to the hydroxyl group of the alcohol, or a mixture comprising the substantially neutral ester and a saturated ester having lubricating properties, examples of which include di-octyl azelate, di-isoamyl adipate, di-2 - ethylhexyl glutanate and di - 2 - ethylhexyl phthalate. The expression "substantially neutral ester" denotes the pure diester or the diester containing a very small amount of the mono-ester. The acetylenic di-esters are preferably those in which x is an integer from 4-8, n is 0, 1 or 2 and the alcohol radical, preferably tertiary, contains 3-5 carbon atoms in its longest chain. The esters are high pressure lubricants and in the lubricant mixtures are preferably used in amounts ranging from 5-50% by weight of the whole. Numerous acetylenic esters are named and their preparation is given (see Group IV (b)).ALSO:Esters having the general formula <FORM:0821941/IV (a)/1> wherein x is an integer from 2 to 8, R1 and R2 are hydrogen or alkyl radicals, n is an integer including O and the radical of the acetylenic alcohol from which the ester is derived contains from 3 to 10 carbon atoms in its longest chain which chain includes the terminal ethinyl group and is linked to the hydroxyl group, are prepared by reacting an appropriate acetylenic alcohol, preferably a tertiary alcohol, with the dichloride of the appropriate dibasic acid in the presence of an acid acceptor, e.g. pyridine, and an inert organic liquid medium. The esters, examples of which are given, may be used in lubricating (see Group III).
GB34453/55A 1954-12-09 1955-12-01 A method of lubricating relatively moving parts Expired GB821941A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US821941XA 1954-12-09 1954-12-09

Publications (1)

Publication Number Publication Date
GB821941A true GB821941A (en) 1959-10-14

Family

ID=22169634

Family Applications (1)

Application Number Title Priority Date Filing Date
GB34453/55A Expired GB821941A (en) 1954-12-09 1955-12-01 A method of lubricating relatively moving parts

Country Status (1)

Country Link
GB (1) GB821941A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1230511B (en) * 1963-04-29 1966-12-15 Rheinpreussen Ag Lubricating oil for aircraft gas turbines
DE1246921B (en) * 1964-05-05 1967-08-10 Rheinpreussen Ag Lubricating oils for high-speed aircraft with jet or gas turbine propulsion

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1230511B (en) * 1963-04-29 1966-12-15 Rheinpreussen Ag Lubricating oil for aircraft gas turbines
DE1246921B (en) * 1964-05-05 1967-08-10 Rheinpreussen Ag Lubricating oils for high-speed aircraft with jet or gas turbine propulsion

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