GB820185A - Improvements in and relating to the production of alkyl aluminium sesquichlorides - Google Patents
Improvements in and relating to the production of alkyl aluminium sesquichloridesInfo
- Publication number
- GB820185A GB820185A GB655157A GB655157A GB820185A GB 820185 A GB820185 A GB 820185A GB 655157 A GB655157 A GB 655157A GB 655157 A GB655157 A GB 655157A GB 820185 A GB820185 A GB 820185A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- alkyl
- sesquichloride
- reaction
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000005234 alkyl aluminium group Chemical group 0.000 title abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- 229910052782 aluminium Inorganic materials 0.000 abstract 3
- 239000004411 aluminium Substances 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- 150000001348 alkyl chlorides Chemical class 0.000 abstract 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 150000001347 alkyl bromides Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 abstract 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 abstract 1
- 229960003750 ethyl chloride Drugs 0.000 abstract 1
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- -1 saturated alicyclic hydrocarbons Chemical class 0.000 abstract 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/064—Aluminium compounds with C-aluminium linkage compounds with an Al-Halogen linkage
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B7/00—Roofs; Roof construction with regard to insulation
- E04B7/08—Vaulted roofs
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Alkyl aluminium sesquichlorides are prepared by reacting aluminium with a primary alkyl chloride in the presence of an inert solvent, the reaction being initiated by a primary alkyl bromide or iodide, suitably in amount from 1 to 30 molar per cent of the total halide used. It is desirable that the alkyl groups of the alkyl chloride and of the initiator should be the same. The reaction may take place between 0 DEG and 250 DEG C., preferably between 50 DEG and 180 DEG C. Suitable solvents are paraffinic and saturated alicyclic hydrocarbons. The sesquichloride so produced may be dehalogenated by the process of Specification 762,200 to give an aluminium trialkyl without separating the sesquichloride from the solvent. The example describes the production of ethyl aluminium sesquichloride from aluminium and ethyl chloride using decalin as a solvent and ethyl bromide as reaction initiator.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE565083D BE565083A (en) | 1957-02-27 | ||
| NL96430D NL96430C (en) | 1957-02-27 | ||
| GB655157A GB820185A (en) | 1957-02-27 | 1957-02-27 | Improvements in and relating to the production of alkyl aluminium sesquichlorides |
| FR1199347D FR1199347A (en) | 1957-02-27 | 1958-02-14 | Manufacture of organic aluminum compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB655157A GB820185A (en) | 1957-02-27 | 1957-02-27 | Improvements in and relating to the production of alkyl aluminium sesquichlorides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB820185A true GB820185A (en) | 1959-09-16 |
Family
ID=9816569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB655157A Expired GB820185A (en) | 1957-02-27 | 1957-02-27 | Improvements in and relating to the production of alkyl aluminium sesquichlorides |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE565083A (en) |
| FR (1) | FR1199347A (en) |
| GB (1) | GB820185A (en) |
| NL (1) | NL96430C (en) |
-
0
- BE BE565083D patent/BE565083A/xx unknown
- NL NL96430D patent/NL96430C/xx active
-
1957
- 1957-02-27 GB GB655157A patent/GB820185A/en not_active Expired
-
1958
- 1958-02-14 FR FR1199347D patent/FR1199347A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR1199347A (en) | 1959-12-14 |
| NL96430C (en) | |
| BE565083A (en) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB820185A (en) | Improvements in and relating to the production of alkyl aluminium sesquichlorides | |
| GB802796A (en) | Method of preparing hydrocarbon-tin compounds | |
| GB718198A (en) | Improvements in the manufacture of alkyl aluminium halides | |
| GB873212A (en) | Process for the manufacture of 1:1:1-trifluoro-2-chloro-2-bromethane | |
| GB824428A (en) | Improvements in and relating to the production of aluminium alkyls | |
| GB568569A (en) | Improvements in or relating to the production of vinyl halides | |
| GB766429A (en) | Improvements in polyvinyl chloride resins | |
| GB887974A (en) | Polymerisation of olefins | |
| GB1270618A (en) | Process for the preparation of organosilicon compounds having hydrogen directly bonded to silicon | |
| SE7605459L (en) | WAY TO POLYMERIZE UNSATURATED ORGANIC ASSOCIATIONS OR MIXTURES OF SUCH ASSOCIATIONS | |
| ES434999A1 (en) | Process for the manufacture of a catalyst for the polymerization of alpha-olefins | |
| ES284442A1 (en) | Procedure for the polymerization of alpha-olefins (Machine-translation by Google Translate, not legally binding) | |
| FR1202061A (en) | Process for preparing vinyl chloride by pyrolysis of ethylene chloride | |
| FR1186716A (en) | Process for preparing vinyl chloride | |
| AU156513B2 (en) | Suspension polymerisation process for the polymerisation of unsaturated organic compounds which contain a CH2: C < group in the molecule | |
| AU690151A (en) | Suspension polymerisation process for the polymerisation of unsaturated organic compounds which contain a CH2: C < group in the molecule | |
| GB909212A (en) | Process for the manufacture of polyethylene | |
| GB861459A (en) | Process of preparing tetraaryl tin compounds | |
| CA511650A (en) | Suspension polymerization of unsaturated organic compounds | |
| GB1262539A (en) | Fluoroalkyl ethers and process for their manufacture | |
| GB927985A (en) | Process for preparing alkyl aluminium halides | |
| CA542441A (en) | Production of vinyl chloride from cracking hydrocarbon gases containing acetylene | |
| AU279525B2 (en) | Process for the preparation of fluorinated organic compounds by fluorination of aliphatic hydrocarbons | |
| CA547607A (en) | Production of organic chlorides by reaction of organic compound with ammonium chloride | |
| GB967573A (en) | Organoaluminium compounds and process for preparing them |