GB814572A - Improvements in and relating to lubricating compositions - Google Patents
Improvements in and relating to lubricating compositionsInfo
- Publication number
- GB814572A GB814572A GB12431/57A GB1243157A GB814572A GB 814572 A GB814572 A GB 814572A GB 12431/57 A GB12431/57 A GB 12431/57A GB 1243157 A GB1243157 A GB 1243157A GB 814572 A GB814572 A GB 814572A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- copolymers
- fluorine
- lauryl
- methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
- C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M149/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of a saturated carboxylic or carbonic acid
- C10M145/08—Vinyl esters of a saturated carboxylic or carbonic acid
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
- C10M145/14—Acrylate; Methacrylate
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- C10M147/00—Lubricating compositions characterised by the additive being a macromolecular compound containing halogen
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/082—Inorganic acids or salts thereof containing nitrogen
- C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10M2207/027—Neutral salts thereof
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- C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
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- C10M2209/062—Vinyl esters of saturated carboxylic or carbonic acids, e.g. vinyl acetate
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- C10M2209/084—Acrylate; Methacrylate
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- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/101—Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof
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- C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
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- C10M2211/022—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
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- C10M2211/024—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aromatic
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- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
- C10M2211/042—Alcohols; Ethers; Aldehydes; Ketones
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- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
- C10M2211/044—Acids; Salts or esters thereof
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- C10M2215/065—Phenyl-Naphthyl amines
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
- C10M2223/065—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/044—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
Abstract
Lubricating oil compositions with good viscosity-temperature characteristics comprise a major proportion of a mineral lubricating oil, a minor proportion of a polymer or copolymer of one or more esters of the general formula <FORM:0814572/III/1> where Y is <FORM:0814572/III/2> or <FORM:0814572/III/3> X is H or a hydrocarbon group and R is a monovalent hydrocarbon radical, preferably a C8-20 radical, or a copolymer of such an ester with a polymerizable heterocyclic nitrogen base compound and a minor proportion of an organic fluorine-containing compound either in addition to or as part of the polymer. The base oils may be derived from paraffinic, naphthenic, asphaltic or mixed base crude petroleum stocks. Examples of copolymers include those of octyl and lauryl methacrylates; vinyl stearate and laurate; 2-methyl-5-vinyl pyridine and lauryl or octadecyl methacrylate; N-vinyl pyrrolidone and lauryl or octadecyl methacrylate; and terpolymers such as 2-methyl-5-vinyl pyridine with lauryl and octadecyl methacrylates. Many examples of organic fluorine-containing compounds are given including fluorinated C5.50 aliphatic, cycloaliphatic and aromatic hydrocarbons, amines, ethers, acids, alcohols, esters and amides. The fluorinated compound or mixture thereof may comprise 0.01 to 10 per cent wt. of the whole composition. The fluorine compound may be a monomeric unit of the copolymer, in which case it may account for between 1 and 5 per cent of the molecular weight of the polymer. Suitable fluorine-containing monomers are trifluorovinyl chloride, trifluoromethyl acrylonitrile, vinyl trifluoro acetate and perfluorobutyl acrylate which may be copolymerized with vinyl pyridines or pyrrolidones and methacrylates. The molecular weights of the polymers may be: for ester polymers and copolymers over 104 and preferably below 106; for ester/nitrogen compound copolymers 7.5 X 103 to 2.5 X 106; and for ester/nitrogen compound/fluoro compound copolymers 1.5 X 103 to 2 X 106. They may constitute between 0.1 and 10 wt. per cent of the total composition. Optional ingredients mentioned are corrosion inhibitors, e.g. sodium, lithium and diisopropyl ammonium nitrites, and polyvalent metal thiophosphates, e.g. calcium or zinc dicyclohexyl thiophosphate or methylcyclohexyl thiophosphate; E.P. agents such as organic phosphites, phosphates and phosphonates, e.g. trichloroethyl phosphite and tricresyl phosphate; P2S5-terpene reaction products; organic sulphides, e.g. wax disulphide or ethylene bistolyl sulphide; anti-oxidants such as amines and phenols, e.g. octadecyl amine, phenyl a -naphthylamine or 2,6-di-t-butyl-4-methyl phenol; and other additives such as metal phenates and sulphonates, e.g. Ca or Ba salt of octyl phenol-formaldehyde condensation product or neutral or basic Ca or Ba petroleum sulphonate. Examples comprise (i) a mineral lubricating oil; (ii) one of the following copolymers: lauryl methacrylate/N-vinyl pyrrolidone, lauryl methacrylate/octyl methacrylate, or octadecyl methacrylate/2-methyl-5-vinyl pyridine; and (iii) one of the following: fluorobenzene, perfluoromethyl cyclohexane, 4-fluorobiphenyl; a fluorinated cyclic ether (C8F16O), heptacosofluorotributylamine, diiodopentane, diiodobenzene, 1,4-dichlorobutane, chlorowax, or glycerol monooleate, the last five being included for purposes of comparison. Specifications 583,874, [Group IV], 634,673, [Group IV (a)], and 752,383 are referred to.ALSO:Fluorine-containing copolymers are added to lubricating oils (see Group III). The copolymers are those obtained by copolymerising an ester of the general formula <FORM:0814572/IV (a)/1> where X represents an hydrogen atom or hydrocarbon group and Y represents <FORM:0814572/IV (a)/2> or <FORM:0814572/IV (a)/3> with another such ester and/or a polymerisable heterocyclic nitrogen compound at least one of which contains at least one substituent fluorine atom. Examples of fluorine-containing monomers are trifluorovinyl chloride, trifluoromethylacrylonitrile, vinyl trifluoroacetate and perfluorobutyl acrylate. They may be copolymerized with vinyl pyridines or alkyl methacrylates, vinyl pyrrolidones, vinyl esters, or mixtures. The preferred terpolymers have molecular weights of 1.5 X 103 to 2 X 106 with the fluorine-containing monomer unit accounting for less than 10 per cent of the total molecular weight. Specific examples of such copolymers are vinyl pyridine/lauryl methacrylate/vinyl trifluoro acetate; 2-methyl-5-vinyl pyridine/octadecyl methacrylate/trifluorovinyl chloride; N-vinyl pyrrolidone/octadecyl methacrylate/trifluorovinyl chloride; and trifluoromethyl acrylonitrile/vinyl stearate. Specifications 583,874, [Group IV], 634,673 and 752,383, [Group III], are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US814572XA | 1956-04-16 | 1956-04-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB814572A true GB814572A (en) | 1959-06-10 |
Family
ID=22164285
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12431/57A Expired GB814572A (en) | 1956-04-16 | 1957-04-16 | Improvements in and relating to lubricating compositions |
Country Status (4)
Country | Link |
---|---|
DE (1) | DE1057271B (en) |
FR (1) | FR1174242A (en) |
GB (1) | GB814572A (en) |
NL (1) | NL109302C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017216332A1 (en) * | 2016-06-17 | 2017-12-21 | Akzo Nobel Chemicals International B.V. | Lubricant spray polymers |
US11142720B2 (en) | 2016-06-17 | 2021-10-12 | Nouryon Chemicals International B.V. | Lubricant spray polymers |
-
0
- NL NL109302D patent/NL109302C/xx active
-
1957
- 1957-04-15 DE DEN13538A patent/DE1057271B/en active Pending
- 1957-04-16 GB GB12431/57A patent/GB814572A/en not_active Expired
- 1957-04-16 FR FR1174242D patent/FR1174242A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017216332A1 (en) * | 2016-06-17 | 2017-12-21 | Akzo Nobel Chemicals International B.V. | Lubricant spray polymers |
US11142720B2 (en) | 2016-06-17 | 2021-10-12 | Nouryon Chemicals International B.V. | Lubricant spray polymers |
Also Published As
Publication number | Publication date |
---|---|
NL109302C (en) | |
DE1057271B (en) | 1959-05-14 |
FR1174242A (en) | 1959-03-09 |
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