GB760554A - Lubricating compositions and additives therefor - Google Patents

Lubricating compositions and additives therefor

Info

Publication number
GB760554A
GB760554A GB31259/54A GB3125954A GB760554A GB 760554 A GB760554 A GB 760554A GB 31259/54 A GB31259/54 A GB 31259/54A GB 3125954 A GB3125954 A GB 3125954A GB 760554 A GB760554 A GB 760554A
Authority
GB
United Kingdom
Prior art keywords
vinyl
methyl
alpha
ethyl
acrylonitrile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31259/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB760554A publication Critical patent/GB760554A/en
Expired legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M149/00Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/10Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1812C12-(meth)acrylate, e.g. lauryl (meth)acrylate
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/06Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/082Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083Inorganic acids or salts thereof containing nitrogen nitrites
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    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
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    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
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    • C10M2203/106Naphthenic fractions
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    • C10M2203/108Residual fractions, e.g. bright stocks
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    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
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    • C10M2205/04Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/22Alkylation reaction products with aromatic type compounds, e.g. Friedel-crafts
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    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10M2207/34Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
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    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
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    • C10M2217/028Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
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    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
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    • C10M2223/06Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
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    • C10M2223/12Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
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    • C10M2225/00Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/046Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Lubricants (AREA)

Abstract

760,554. Synthetic resin compositions. NAAMLOOZE VENNOOTSCHAP DE BATAAFSCHE PETROLEUM MAATSCHAPPIJ. Oct. 29, 1954 [Nov. 2, 1953], No. 31259/54. Class 2 (6). [Also in Group III] A composition comprises a major proportion of a lubricating oil and a minor proportion, preferably from 0.01 to 10 per cent by weight, based on the whole composition, of a copolymer of (1) a polymerizable heterocyclic nitrogen base compound with (2) a polymerizable unsaturated material free of heterocyclic nitrogen-containing radicals, the molar ratio of (1) to (2) being between 1 : 1 and 1: 4. Compound (1) may be a vinyl pyridine, quinoline, pyrrole, pyrrolidine, pyrroline, indole, imidazole, pyrroloindole, or pyrrolidone, or a ring-substituted derivative thereof, preferred compounds being 2-vinyl-, 3-vinyl-, 4-vinyl-, 2-methyl-5-vinyl-, 4-methyl- 2-vinyl-, 2-ethyl-5-vinyl- and 2-butyl-5-vinylpyridine, and (2) may be acrylic, methacrylic, ethacrylic, or alpha-phenyl acrylic acid or a methyl, ethyl, propyl, isopropyl, butyl, isobutyl, amyl, octyl, nonyl, lauryl, cetyl, oleyl, stearyl or cyclohexyl ester thereof, acrylamide, alpha-methyl-,. alpha-ethyl- or lauryl-acrylamide, acrylonitrile, alpha-methyl-, alpha-ethyl- or alpha-propyl-acrylonitrile, 2-butyl 2-hexenenitrile, 2-propyl 2-pentene-nitrile, 2-chloroethyl- 2-butenenitrile, 2-ethyl 3-chloro 2-butenenitrile, 2-isopropyl 3-bromo 2-pentenenitrile, alphaisopropyl beta-cyclohexyl-acrylonitrile, vinyl or allyl acetate, propionate, butyrate, isobutyrate, valerate, laurate, stearate, benzoate or crotonate, vinyl or allyl methyl, isobutyl or phenyl ether or ketone, styrene, o-methyl, p-methyl, p-ethyl, 2,4-dimethyl, alpha-methyl p-methyl or alpha-methyl styrene, vinyl naphthalene or diphenyl, vinyl chloride or fluoride, vinylidene chloride or fluorochloride, maleic, fumaric, citraconic, itaconic, mesaconic, crotonic, aconitic or tricarballylic acid, or an ester, amide or nitrile thereof. Mixtures of heterocyclic nitrogen base compounds and/or the other polymerizable compounds may be used. The lubricating oil may be obtained from a paraffinic or naphthenic crude or mixtures thereof, which may be blended with fatty oils such as castor oil or lard oil, and/or with synthetic lubricating oils, such as polymerized olefins, copolymers of alkylene glycols and alkylene oxides, di-(2- ethyl hexyl) sebacate, dioctyl phthalate, trioctyl phosphate, polymeric tetrahydrofuran and polyalkyl silicone polymers. Synthetic lubricating oils may be used as the sole base lubricating oil or may be admixed with fatty oils. The compositions may contain pour-point depressants, viscosity index improvers, blooming agents, corrosion inhibitors, oiliness agents and solubilizers, such as isobutylene and alkyl styrene polymers, wax-naphthalene condensation products, sodium, lithium, diisopropylammonium or dicyclohexylammonium nitrite, trichloroethyl or tricresyl phosphate, phosphorus sulphide-terpene reaction products, calcium or zinc dicyclohexylthiophosphate or methylcyclohexylthiophosphate, wax disulphide, ethylene bistolyl sulphide, octadecylamine, stearyl alcohol, oleic acid and sorbitan mono-oleate. Examples describe the production of copolymers of lauryl methacrylate and 2-methyl-5-vinyl- or 4-vinyl-pyridine in the presence of benzoyl peroxide or alpha, alphaazodiisobutyronitrile as catalyst. Specification 726,785 is referred to.
GB31259/54A 1953-05-18 1954-10-29 Lubricating compositions and additives therefor Expired GB760554A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US770771XA 1953-05-18 1953-05-18
US760554XA 1953-11-02 1953-11-02

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GB760554A true GB760554A (en) 1956-10-31

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GB10885/54A Expired GB770771A (en) 1953-05-18 1954-04-13 Copolymeric dispersants and lubricant compositions containing them
GB31259/54A Expired GB760554A (en) 1953-05-18 1954-10-29 Lubricating compositions and additives therefor

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GB10885/54A Expired GB770771A (en) 1953-05-18 1954-04-13 Copolymeric dispersants and lubricant compositions containing them

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BE (1) BE532975A (en)
DE (1) DE1003896B (en)
FR (1) FR1111338A (en)
GB (2) GB770771A (en)
NL (1) NL89506C (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1090362B (en) * 1958-05-19 1960-10-06 Iashellia Res Ltd Lubricating oil
DE1102327B (en) * 1958-09-22 1961-03-16 Iashellia Res Ltd Lubricating oil
US3015546A (en) * 1958-10-28 1962-01-02 Exxon Research Engineering Co Gasolines inhibited against the formation of deposits, sludge and varnish
DE1135604B (en) * 1958-11-18 1962-08-30 Shell Int Research lubricant
US3053766A (en) * 1958-07-25 1962-09-11 Exxon Research Engineering Co High detergency automotive engine lubricant
US3058818A (en) * 1959-04-22 1962-10-16 Exxon Research Engineering Co Gasolines containing polymeric additive agents
US3108967A (en) * 1960-12-16 1963-10-29 Union Carbide Corp Lubricating oil composition of improved viscosity index and dispersancy
US3130161A (en) * 1958-11-18 1964-04-21 Shell Oil Co Lubricating oil and anti-wear additives therefor
US3143513A (en) * 1960-02-26 1964-08-04 Exxon Research Engineering Co Lubricant composition
US3153632A (en) * 1960-06-15 1964-10-20 Shell Oil Co Power transmission fluids
US3175976A (en) * 1965-03-30 Automatic transmission fluids
US3208938A (en) * 1963-02-08 1965-09-28 Shell Oil Co Lubricating compositions
US3282841A (en) * 1962-11-30 1966-11-01 Shell Oil Co Lubricating oil composition
US3285854A (en) * 1963-07-15 1966-11-15 Shell Oil Co Lubricating oil composition
US3309317A (en) * 1964-06-08 1967-03-14 Shell Oil Co Lubricating composition
US5349019A (en) * 1988-12-24 1994-09-20 Hoechst New copolymers, mixtures thereof with poly(meth)acrylate esters and the use thereof for improving the cold fluidity of crude oils

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3142664A (en) * 1955-08-19 1964-07-28 Rohm & Haas Oil soluble copolymer of a nu-vinyl pyrrolidinone and an alkyl ester of an unsaturated monocarboxylic acid
BE563612A (en) * 1956-12-31
US3153640A (en) * 1957-03-11 1964-10-20 Shell Oil Co Nitrogen-containing copolymers and their preparation
NL226646A (en) * 1957-04-09
DE1128585B (en) * 1957-06-24 1962-04-26 Bataafsche Petroleum lubricant
DE1075254B (en) * 1957-11-26 1960-02-11 N. V. De Bataafsche Petroleum Maatschappij, Den Haag Mineral oil-based lubricating oil mixture
US3147222A (en) * 1958-03-05 1964-09-01 Rohm & Haas Compositions comprising a petroleum liquid and an nu-vinyl pyrrolidinaone polymer
DE1107869B (en) * 1958-04-12 1961-05-31 Roehm & Haas Gmbh Additives to hydraulic fluids based on mineral oil-free glycol ethers or triaryl phosphates
DE1126057B (en) * 1958-11-13 1962-03-22 Roehm & Haas Gmbh Additive to mineral and synthetic lubricating oils
BE591232A (en) * 1959-05-28
NL246087A (en) * 1959-12-04
US3198739A (en) * 1960-11-25 1965-08-03 Shell Oil Co Lubricants and polymeric additives therefor
NL272801A (en) * 1960-12-23
US3116248A (en) * 1960-12-23 1963-12-31 Shell Oil Co Lubricating oil composition
LU58617A1 (en) * 1969-05-09 1971-03-09
DE2905954C2 (en) * 1979-02-16 1982-10-28 Röhm GmbH, 6100 Darmstadt Concentrated polymer emulsions as viscosity index improvers for mineral oils
DE3318136A1 (en) * 1983-05-18 1984-11-22 Oskar Dr.-Ing. 8035 Gauting Schatz CHARGING DEVICE FOR CHARGING COMBUSTION ENGINES
DE3843922A1 (en) * 1988-12-24 1990-06-28 Hoechst Ag NEW COPOLYMERS, THEIR MIXTURES WITH POLY (METH) ACRYLIC ACID ESTERS AND THEIR USE FOR IMPROVING THE FLOWABILITY OF RAW OILS IN THE COLD

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE747186C (en) * 1942-01-01 1945-01-08 Removable paneling for landing gear struts or the like that can be retracted into the airframe of an aircraft

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3175976A (en) * 1965-03-30 Automatic transmission fluids
DE1090362B (en) * 1958-05-19 1960-10-06 Iashellia Res Ltd Lubricating oil
US3053766A (en) * 1958-07-25 1962-09-11 Exxon Research Engineering Co High detergency automotive engine lubricant
DE1102327B (en) * 1958-09-22 1961-03-16 Iashellia Res Ltd Lubricating oil
US3015546A (en) * 1958-10-28 1962-01-02 Exxon Research Engineering Co Gasolines inhibited against the formation of deposits, sludge and varnish
US3130161A (en) * 1958-11-18 1964-04-21 Shell Oil Co Lubricating oil and anti-wear additives therefor
US3116250A (en) * 1958-11-18 1963-12-31 Shell Oil Co Nitro-aromatic telomers and oils containing them
DE1135604B (en) * 1958-11-18 1962-08-30 Shell Int Research lubricant
US3058818A (en) * 1959-04-22 1962-10-16 Exxon Research Engineering Co Gasolines containing polymeric additive agents
US3143513A (en) * 1960-02-26 1964-08-04 Exxon Research Engineering Co Lubricant composition
US3153632A (en) * 1960-06-15 1964-10-20 Shell Oil Co Power transmission fluids
US3108967A (en) * 1960-12-16 1963-10-29 Union Carbide Corp Lubricating oil composition of improved viscosity index and dispersancy
US3282841A (en) * 1962-11-30 1966-11-01 Shell Oil Co Lubricating oil composition
US3208938A (en) * 1963-02-08 1965-09-28 Shell Oil Co Lubricating compositions
US3285854A (en) * 1963-07-15 1966-11-15 Shell Oil Co Lubricating oil composition
US3309317A (en) * 1964-06-08 1967-03-14 Shell Oil Co Lubricating composition
US5349019A (en) * 1988-12-24 1994-09-20 Hoechst New copolymers, mixtures thereof with poly(meth)acrylate esters and the use thereof for improving the cold fluidity of crude oils

Also Published As

Publication number Publication date
FR1111338A (en) 1956-02-24
BE532975A (en) 1955-04-30
NL89506C (en) 1958-06-16
GB770771A (en) 1957-03-27
DE1003896B (en) 1957-03-07

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