GB804070A - Dimerization of polypropylenes - Google Patents
Dimerization of polypropylenesInfo
- Publication number
- GB804070A GB804070A GB1572957A GB1572957A GB804070A GB 804070 A GB804070 A GB 804070A GB 1572957 A GB1572957 A GB 1572957A GB 1572957 A GB1572957 A GB 1572957A GB 804070 A GB804070 A GB 804070A
- Authority
- GB
- United Kingdom
- Prior art keywords
- boron trifluoride
- complex
- propylene
- carbon atoms
- reaction mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001155 polypropylene Polymers 0.000 title abstract 6
- -1 polypropylenes Polymers 0.000 title abstract 4
- 239000004743 Polypropylene Substances 0.000 title abstract 3
- 238000006471 dimerization reaction Methods 0.000 title abstract 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 abstract 10
- 229910015900 BF3 Inorganic materials 0.000 abstract 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 abstract 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical class COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000000539 dimer Substances 0.000 abstract 1
- 230000000447 dimerizing effect Effects 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
- C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/08—Halides
- C07C2527/12—Fluorides
- C07C2527/1213—Boron fluoride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Propylene polymers of 12 to 24 carbon atoms are prepared by dimerizing propylene polymers of 6 to 12 carbon atoms at 0-100 DEG C. in the presence of a preformed boron trifluoride-ether complex and excess boron trifluoride. The starting polypropylene may be a narrow fraction of a simple propylene polymerization product. Specified ethers which may be used in the complex are dimethyl, diethyl, diisopropyl, methyl ethyl and methyl tertiary butyl ethers. The amount of complex used may be 1 to 10 weight per cent of the polypropylene to be dimerized. Excess boron trifluoride is maintained by passing the gas through the reaction mixture. Pressures of 1 to 10 atmospheres may be used to maintain liquid phase conditions. Batch or continuous operation can be used. The catalyst can be decomposed with water and the oily product separated from the aqueous layer and fractionated to obtain the desired dimer from unconverted material and any other products formed. Examples illustrate the dimerization of a C9 and a C12 propylene polymer cut using a complex of ethyl ether and boron trifluoride containing 45 weight per cent of boron trifluoride at 60-70 DEG C. for four hours, boron trifluoride gas being slowly passed through the reaction mixture throughout the reaction period.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1572957A GB804070A (en) | 1957-05-17 | 1957-05-17 | Dimerization of polypropylenes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1572957A GB804070A (en) | 1957-05-17 | 1957-05-17 | Dimerization of polypropylenes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB804070A true GB804070A (en) | 1958-11-05 |
Family
ID=10064451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1572957A Expired GB804070A (en) | 1957-05-17 | 1957-05-17 | Dimerization of polypropylenes |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB804070A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4956513A (en) * | 1988-10-17 | 1990-09-11 | Ethyl Corporation | Recovery of BF3 from olefin oligomer process |
| US5068490A (en) * | 1989-08-18 | 1991-11-26 | Amoco Corporation | BF3-tertiary etherate complexes for isobutylene polymerization |
| WO1993010063A1 (en) * | 1991-11-18 | 1993-05-27 | Amoco Corporation | Bf3-tertiary etherate complexes for isobutylene polymerization |
-
1957
- 1957-05-17 GB GB1572957A patent/GB804070A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4956513A (en) * | 1988-10-17 | 1990-09-11 | Ethyl Corporation | Recovery of BF3 from olefin oligomer process |
| US5068490A (en) * | 1989-08-18 | 1991-11-26 | Amoco Corporation | BF3-tertiary etherate complexes for isobutylene polymerization |
| WO1993010063A1 (en) * | 1991-11-18 | 1993-05-27 | Amoco Corporation | Bf3-tertiary etherate complexes for isobutylene polymerization |
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