GB795688A - Improvements in the thermal cracking of combustible organic liquids - Google Patents
Improvements in the thermal cracking of combustible organic liquidsInfo
- Publication number
- GB795688A GB795688A GB27834/55A GB2783455A GB795688A GB 795688 A GB795688 A GB 795688A GB 27834/55 A GB27834/55 A GB 27834/55A GB 2783455 A GB2783455 A GB 2783455A GB 795688 A GB795688 A GB 795688A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxygen
- liquid
- ignition
- hydrogen
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/40—Thermal non-catalytic treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B47/00—Methods of operating engines involving adding non-fuel substances or anti-knock agents to combustion air, fuel, or fuel-air mixtures of engines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Fire-Extinguishing Compositions (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Combustible organic liquids are thermally cracked by burning oxygen or an oxygen-containing gas, in an amount insufficient for complete combustion, below the surface of the liquid. The liquids to which the process may be applied include hydrocarbons, ethers, alcohols and ketones and is particularly suitable for converting mineral oils into acetylene, olefines, lower alkanes, carbon monoxide and hydrogen. Reduced or increased pressures may be used. Ignition may be accomplished by heating the liquid and/or the oxygen so that spontaneous ignition occurs; if the ignition point is above the boiling point of the liquid, pressure may be applied. Heating of the oxygen may be effected by burning a combustible gas such as hydrogen in the oxygen. Alternatively a flame may be introduced in a protective bell, for example a flame of hydrogen burning in an excess of oxygen, the excess oxygen then being used as the oxygen-containing gas. In the case of substances difficult to ignite, a heat-storage material may be arranged in the gas chamber of the combustion zone to store heat and thus ensure ignition. Substances which reduce the ignition point may also be added to the liquid, such as ethers, ethyl nitrite, amyl nitrite and methyl ethyl ketone peroxide in the case of mineral oils. Electrical ignition can be used, either discharge or resistance heaters being used. Strong oxidizing agents may be added to the oxygen such as ozone, nitric acid vapour, nitrogen oxides, chloric acid, perchloric acid, chlorine dioxide, manganese heptoxide, nitrates, chlorates and perchlorates, solids and liquids being added as dust or aerosol respectively. Oxidizing catalysts such as platinized asbestos or other platinum catalyst, magnesium silicates or aluminium silicates such as pumice stone can also be suspended in the liquid. The oxygen may be introduced as bubbles by introduction through a sieve or frit material or slots or a layer of granular material over a grate in the bottom of the vessel, or through a nozzle or bell submerged in the liquid. Alternatively the liquid may be allowed to flow through a tube and oxygen introduced through one or more nozzles so that the oxygen flows as a separate phase or as bubbles; liquid may be recycled after purification and cooling. Where the liquid is stationary in a vessl the depth through which the oxygen passes should be sufficient to ensure that all the oxygen is "burned." Steam or nitrogen may be added to the oxygen to moderate the combustion. In the examples the process is applied to the cracking of diesel oil, octane, crude oil and methyl alcohol to give hydrocarbon mixtures with oxides of carbon and hydrogen.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB27834/55A GB795688A (en) | 1955-09-30 | 1955-09-30 | Improvements in the thermal cracking of combustible organic liquids |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB27834/55A GB795688A (en) | 1955-09-30 | 1955-09-30 | Improvements in the thermal cracking of combustible organic liquids |
Publications (1)
Publication Number | Publication Date |
---|---|
GB795688A true GB795688A (en) | 1958-05-28 |
Family
ID=10266058
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB27834/55A Expired GB795688A (en) | 1955-09-30 | 1955-09-30 | Improvements in the thermal cracking of combustible organic liquids |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB795688A (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1144260B (en) * | 1960-12-10 | 1963-02-28 | Basf Ag | Process for the production of acetylene by thermal cracking of liquid hydrocarbons |
FR2006491A1 (en) * | 1968-04-18 | 1969-12-26 | Ruhrchemie Ag | |
WO2012099674A3 (en) * | 2011-01-19 | 2013-03-21 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion process |
CN104534512A (en) * | 2014-12-26 | 2015-04-22 | 北京神雾环境能源科技集团股份有限公司 | Ignition method of water wall natural gas partial oxidation reforming furnace |
US9346728B2 (en) | 2011-01-19 | 2016-05-24 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion process |
US9505680B2 (en) | 2011-01-19 | 2016-11-29 | Exxonmobil Chemical Patents Inc. | Method and apparatus for managing the conversion of hydrocarbons into olefins |
US9663419B2 (en) | 2011-01-19 | 2017-05-30 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion process |
US9677014B2 (en) | 2011-01-19 | 2017-06-13 | Exxonmobil Chemical Patents Inc. | Process and apparatus for converting hydrocarbons |
US9676681B2 (en) | 2011-01-19 | 2017-06-13 | Exxonmobil Chemical Patents Inc. | Method and apparatus for managing hydrogen content through the conversion of hydrocarbons into olefins |
US9708232B2 (en) | 2011-01-19 | 2017-07-18 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins |
US9708231B2 (en) | 2011-01-19 | 2017-07-18 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins using hydroprocessing and thermal pyrolysis |
US9809508B2 (en) | 2011-01-19 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins |
US9815751B2 (en) | 2011-01-19 | 2017-11-14 | Exxonmobil Chemical Patents Inc. | Hydrocarbon and oxygenate conversion by high severity pyrolysis to make acetylene and ethylene |
US9868680B2 (en) | 2011-01-19 | 2018-01-16 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins |
-
1955
- 1955-09-30 GB GB27834/55A patent/GB795688A/en not_active Expired
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1144260B (en) * | 1960-12-10 | 1963-02-28 | Basf Ag | Process for the production of acetylene by thermal cracking of liquid hydrocarbons |
FR2006491A1 (en) * | 1968-04-18 | 1969-12-26 | Ruhrchemie Ag | |
US9708232B2 (en) | 2011-01-19 | 2017-07-18 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins |
US9346728B2 (en) | 2011-01-19 | 2016-05-24 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion process |
US9505680B2 (en) | 2011-01-19 | 2016-11-29 | Exxonmobil Chemical Patents Inc. | Method and apparatus for managing the conversion of hydrocarbons into olefins |
US9663419B2 (en) | 2011-01-19 | 2017-05-30 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion process |
US9677014B2 (en) | 2011-01-19 | 2017-06-13 | Exxonmobil Chemical Patents Inc. | Process and apparatus for converting hydrocarbons |
US9676681B2 (en) | 2011-01-19 | 2017-06-13 | Exxonmobil Chemical Patents Inc. | Method and apparatus for managing hydrogen content through the conversion of hydrocarbons into olefins |
WO2012099674A3 (en) * | 2011-01-19 | 2013-03-21 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion process |
US9708231B2 (en) | 2011-01-19 | 2017-07-18 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins using hydroprocessing and thermal pyrolysis |
US9809508B2 (en) | 2011-01-19 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins |
US9815919B2 (en) | 2011-01-19 | 2017-11-14 | Exxonmobil Chemical Patents Inc. | Hydrocarbon conversion process |
US9815751B2 (en) | 2011-01-19 | 2017-11-14 | Exxonmobil Chemical Patents Inc. | Hydrocarbon and oxygenate conversion by high severity pyrolysis to make acetylene and ethylene |
US9868680B2 (en) | 2011-01-19 | 2018-01-16 | Exxonmobil Chemical Patents Inc. | Method and apparatus for converting hydrocarbons into olefins |
CN104534512A (en) * | 2014-12-26 | 2015-04-22 | 北京神雾环境能源科技集团股份有限公司 | Ignition method of water wall natural gas partial oxidation reforming furnace |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB795688A (en) | Improvements in the thermal cracking of combustible organic liquids | |
GB1082260A (en) | Improvements in or relating to the manufacture of hydrogen | |
US3639261A (en) | Process for the generation of synthesis gas from oil | |
US3223081A (en) | Bottom-hole catalytic heater using heat transfer liquid | |
NO120573B (en) | ||
US1965770A (en) | Production of acetylene | |
NZ211695A (en) | Process for the production of synthesis gas | |
US3242223A (en) | Production of acetylene by thermal cracking of liquid hydrocarbons | |
GB709035A (en) | Improvements relating to the production of pyrogenic chemical reactions | |
US3219108A (en) | Use of propynol in chemical ignition | |
US3090684A (en) | Conversion of oils with amounts of oxygen insufficient for complete combustion for the formation of carbon monoxide and hydrogen | |
US3363024A (en) | Hydrogenation of hydrocarbon oils | |
US1864196A (en) | Process for the preparation of acetylene and ethylene | |
GB1005935A (en) | Process for forming a combustion gas | |
US1896552A (en) | Production of acetylene | |
GB680159A (en) | Process for the utilisation of heavy oils and residues for the production of oxygen-containing organic compounds | |
US2954416A (en) | Process for the thermal decomposition of combustible organic liquids | |
US3177150A (en) | Treatment gas and system for its generation | |
US2768223A (en) | Manufacture of acetylene | |
Slovetskii | Plasma-chemical processes for the preparation of pure hydrogen | |
RU2675561C1 (en) | Synthetic gas production method | |
RU2172731C1 (en) | Chemical processing of methane | |
Polianczyk et al. | CONVERSION OF 2-PROPANOL TO SYNGAS VIA PARTIAL OXIDATION IN FILTRATION COMBUSTION | |
US1198542A (en) | Structure for producing flameless catalytic combustion. | |
SU1318783A1 (en) | Method for producing reducing gas |