GB792827A - Improvements in or relating to process for catalytic treatment of hydrocarbons - Google Patents

Improvements in or relating to process for catalytic treatment of hydrocarbons

Info

Publication number
GB792827A
GB792827A GB421855A GB421855A GB792827A GB 792827 A GB792827 A GB 792827A GB 421855 A GB421855 A GB 421855A GB 421855 A GB421855 A GB 421855A GB 792827 A GB792827 A GB 792827A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbons
reaction
catalytic
tube
heated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB421855A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hercules Powder Co
Original Assignee
Hercules Powder Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hercules Powder Co filed Critical Hercules Powder Co
Publication of GB792827A publication Critical patent/GB792827A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0407—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds
    • B01J8/0415—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds the beds being superimposed one above the other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/321—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Fluid Mechanics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Catalysts (AREA)

Abstract

<PICT:0792827/III/1> In a process for catalytically treating fluid hydrocarbons, a heated reaction vessel contains a catalytic basket spaced from the walls so as to give a reaction space between the heating wall and the catalyst basket, which is continuously heated by radiation from the vessel. A refractory wall furnace 10 is employed to heat a thin walled metallic reaction tube 11, which passes completely through the furnace and is provided with inlets 12 and 13 and outlet 14. Concentrically disposed within the tube is a catalyst container 17 disposed in spaced relationship with the inner wall of the reaction tube to provide a narrow passageway 18 for reaction. A thin layer of particulate catalyst 19 is confined between the outer foraminous screen 20 and the fluid-impervious tubular member 21. Alternatively, as in Figures not shown, the reactor may be heated by an internal heating tube or the catalytic baskets may be placed on top of one another or may be coaxially disposed. Fluidized solids and heating gases may be also introduced into the reaction space. Reactions specified are the catalytic production of hydrogen from hydrocarbons the catalytic hydroforming of naphthenic hydrocarbons, polymerization of olefines and the hydrogenation of naphthenes and olefines, dehydrogenation of butylene and the oxiation of hydrocarbons. Catalysts specified are chromium or molybdenum oxides supported on zinc aluminate, chromium oxide on silica or alumina Fe203 supported on magnesium oxide together with promoters or accelerators such as copper or potassium oxide and catalysts described in Specification 640,368 and U.S.A. Specifications 2,571,953 and 2,575,324.
GB421855A 1954-02-19 1955-02-11 Improvements in or relating to process for catalytic treatment of hydrocarbons Expired GB792827A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US1133808XA 1954-02-19 1954-02-19

Publications (1)

Publication Number Publication Date
GB792827A true GB792827A (en) 1958-04-02

Family

ID=22349067

Family Applications (1)

Application Number Title Priority Date Filing Date
GB421855A Expired GB792827A (en) 1954-02-19 1955-02-11 Improvements in or relating to process for catalytic treatment of hydrocarbons

Country Status (4)

Country Link
DE (1) DE1080981B (en)
FR (1) FR1133808A (en)
GB (1) GB792827A (en)
NL (1) NL103240C (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2077347A1 (en) * 1970-01-27 1971-10-22 Selas Corp Of America
US3751232A (en) * 1971-01-14 1973-08-07 Universal Oil Prod Co Means for effecting a multiple stage contact of a reactant stream
EP0021736A2 (en) * 1979-06-27 1981-01-07 Imperial Chemical Industries Plc Catalytic process involving carbon monoxide and hydrogen
EP0036268A1 (en) * 1980-03-18 1981-09-23 British Gas Corporation Vaporisation and gasification of hydrocarbon feedstocks
ITMI20131564A1 (en) * 2013-09-23 2015-03-24 Rivoira S P A ENDOGAS GENERATION SYSTEM
CN113264502A (en) * 2020-08-29 2021-08-17 江苏集萃分子工程研究院有限公司 Hydrogen production device by hydrolysis of sodium borohydride of kilowatt-level fuel cell
CN113277468A (en) * 2020-08-29 2021-08-20 江苏集萃分子工程研究院有限公司 Integrated kilowatt-level fuel cell sodium borohydride hydrolysis hydrogen production device
CN113477027A (en) * 2021-08-04 2021-10-08 中冶赛迪技术研究中心有限公司 Integrated device and method for desulfurization, adsorption, regeneration, cooling and recovery of blast furnace gas
CN113845404A (en) * 2021-09-30 2021-12-28 中国石油化工股份有限公司 Method for preparing hydrogenated bisphenol A by catalytic hydrogenation of bisphenol A
US11438976B2 (en) 2020-02-04 2022-09-06 Qwave Solutions, Inc. Apparatuses, systems, and methods for heating with electromagnetic waves

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1180719B (en) * 1961-04-18 1964-11-05 Georg Schwaneck Device for treating granules with gas

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE270062C (en) *
DE386395C (en) * 1922-10-27 1923-12-15 Merck Chem Fab E Device for carrying out contact reactions of gaseous substances
DE578824C (en) * 1926-11-27 1933-06-17 I G Farbenindustrie Akt Ges Conversion of hydrocarbons or gas mixtures containing them
DE570026C (en) * 1927-06-28 1933-02-10 I G Farbenindustrie Akt Ges Process for the catalytic conversion of hydrocarbons
DE542494C (en) * 1928-12-16 1932-01-25 I G Farbenindustrie Akt Ges Device for carrying out endothermic catalytic gas reactions
BE429915A (en) * 1937-08-30
US2524840A (en) * 1945-02-06 1950-10-10 Hercules Powder Co Ltd Hydrogen production
US2628890A (en) * 1946-06-20 1953-02-17 Hercules Powder Co Ltd Process for the decomposition of hydrocarbons
DE807802C (en) * 1949-09-03 1951-07-05 Georg Vogelsang Clamping device, especially for clamping items of clothing to be separated
US2665979A (en) * 1949-10-31 1954-01-12 United Gas Improvement Co Method of reforming gaseous hydrocarbons
DE933087C (en) * 1952-03-11 1955-09-15 J F Mahler Tube furnace with bent tubes for the catalytic mass to convert gaseous or vaporous substances

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2077347A1 (en) * 1970-01-27 1971-10-22 Selas Corp Of America
US3751232A (en) * 1971-01-14 1973-08-07 Universal Oil Prod Co Means for effecting a multiple stage contact of a reactant stream
EP0021736A2 (en) * 1979-06-27 1981-01-07 Imperial Chemical Industries Plc Catalytic process involving carbon monoxide and hydrogen
EP0021736A3 (en) * 1979-06-27 1981-06-10 Imperial Chemical Industries Plc Catalytic process involving carbon monoxide and hydrogen
EP0036268A1 (en) * 1980-03-18 1981-09-23 British Gas Corporation Vaporisation and gasification of hydrocarbon feedstocks
ITMI20131564A1 (en) * 2013-09-23 2015-03-24 Rivoira S P A ENDOGAS GENERATION SYSTEM
EP2851339A1 (en) * 2013-09-23 2015-03-25 Rivoira S.p.A. Modulable system for the generation of endogas
US11438976B2 (en) 2020-02-04 2022-09-06 Qwave Solutions, Inc. Apparatuses, systems, and methods for heating with electromagnetic waves
CN113264502A (en) * 2020-08-29 2021-08-17 江苏集萃分子工程研究院有限公司 Hydrogen production device by hydrolysis of sodium borohydride of kilowatt-level fuel cell
CN113277468A (en) * 2020-08-29 2021-08-20 江苏集萃分子工程研究院有限公司 Integrated kilowatt-level fuel cell sodium borohydride hydrolysis hydrogen production device
CN113477027A (en) * 2021-08-04 2021-10-08 中冶赛迪技术研究中心有限公司 Integrated device and method for desulfurization, adsorption, regeneration, cooling and recovery of blast furnace gas
CN113845404A (en) * 2021-09-30 2021-12-28 中国石油化工股份有限公司 Method for preparing hydrogenated bisphenol A by catalytic hydrogenation of bisphenol A

Also Published As

Publication number Publication date
NL103240C (en) 1962-12-17
DE1080981B (en) 1960-05-05
FR1133808A (en) 1957-04-02

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