GB792553A - Improved additives suitable for lubricating oil compositions - Google Patents
Improved additives suitable for lubricating oil compositionsInfo
- Publication number
- GB792553A GB792553A GB21001/56A GB2100156A GB792553A GB 792553 A GB792553 A GB 792553A GB 21001/56 A GB21001/56 A GB 21001/56A GB 2100156 A GB2100156 A GB 2100156A GB 792553 A GB792553 A GB 792553A
- Authority
- GB
- United Kingdom
- Prior art keywords
- product
- lubricating oil
- phosphorus
- alkylene oxide
- phosphosulphurizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000654 additive Substances 0.000 title abstract 6
- 239000010687 lubricating oil Substances 0.000 title abstract 6
- 239000000203 mixture Substances 0.000 title abstract 4
- 125000002947 alkylene group Chemical group 0.000 abstract 5
- 229930195733 hydrocarbon Natural products 0.000 abstract 5
- 150000002430 hydrocarbons Chemical class 0.000 abstract 5
- 239000004215 Carbon black (E152) Substances 0.000 abstract 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 3
- CYQAYERJWZKYML-UHFFFAOYSA-N phosphorus pentasulfide Chemical compound S1P(S2)(=S)SP3(=S)SP1(=S)SP2(=S)S3 CYQAYERJWZKYML-UHFFFAOYSA-N 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 2
- 239000012298 atmosphere Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229920002367 Polyisobutene Polymers 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical class CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- VKCLPVFDVVKEKU-UHFFFAOYSA-N S=[P] Chemical compound S=[P] VKCLPVFDVVKEKU-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000010694 animal lubricating oil Substances 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000010688 mineral lubricating oil Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000012299 nitrogen atmosphere Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000010689 synthetic lubricating oil Substances 0.000 abstract 1
- 239000010693 vegetable lubricating oil Substances 0.000 abstract 1
- 235000013311 vegetables Nutrition 0.000 abstract 1
- 239000001993 wax Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/04—Reaction products of phosphorus sulfur compounds with hydrocarbons
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
- C10M2225/041—Hydrocarbon polymers
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
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- C10N2040/135—Steam engines or turbines
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- C10N2040/16—Dielectric; Insulating oil or insulators
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- C10N2040/17—Electric or magnetic purposes for electric contacts
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/14—Electric or magnetic purposes
- C10N2040/175—Pantographs, i.e. printing devices
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
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- C10N2040/18—Electric or magnetic purposes in connection with recordings on magnetic tape or disc
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- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Lubricants (AREA)
Abstract
The invention comprises additive compounds for lubricating oils (see Group III), prepared by phosphosulphurizing a hydrocarbon and reacting the product thus obtained with a C2 to C6 alkylene oxide. In the first stage of the reaction a hydrocarbon is reacted with a mixture of phosphorus and sulphur or a phosphorus sulphide, preferably phosphorus pentasulphide. Specified hydrocarbons are paraffins, olefins, acetylenic hydrocarbons, alkyl-aromatic or cyclo-aliphatic hydrocarbons, petroleum fractions, bright stocks, lubricating oil distillates and waxes. In the second stage the product is condensed with the alkylene oxide at about 285 DEG F. Specified alkylene oxides are ethylene and propylene oxides. In an example a bright stock solvent is treated with phosphorus pentasulphide in a nitrogen atmosphere and the product is either reacted directly with ethylene oxide or treated with an activated earth in a carbon dioxide atmosphere before reaction with ethylene oxide.ALSO:Additives for lubricating oil compositions comprise the products obtained by phosphosulphurizing a hydrocarbon and reacting the product thus obtained with a C2 to C6 alkylene oxide (see Groups IV (a) and IV (b)). They may be incorporated in synthetic, animal, vegetable or mineral lubricating oils, distillates derived from crude paraffin, naphthenic, asphaltic or mixed oils, together with the usual additives. Various tests carried out on lubricating oil compositions containing the additives are described.ALSO:Additive compounds for lubricating oils (see Group III) are prepared by phosphosulphurizing a polyolefin in known manner and reacting the product with a C2 to C6 alkylene oxide. In an example a polyisobutylene having a molecular weight of about 1200 is reacted with phosphorus pentasulphide in an atmosphere of nitrogen and the product is treated with ethylene oxide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1131205T | 1955-09-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB792553A true GB792553A (en) | 1958-03-26 |
Family
ID=9637745
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21001/56A Expired GB792553A (en) | 1955-09-08 | 1956-07-06 | Improved additives suitable for lubricating oil compositions |
GB34092/58A Expired GB838928A (en) | 1955-09-08 | 1958-10-24 | Oxyalkylated phosphosulphurised hydrocarbons and lubricating compositions therefrom |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB34092/58A Expired GB838928A (en) | 1955-09-08 | 1958-10-24 | Oxyalkylated phosphosulphurised hydrocarbons and lubricating compositions therefrom |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1131205A (en) |
GB (2) | GB792553A (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3087956A (en) * | 1960-09-30 | 1963-04-30 | Texaco Inc | Alkylene oxide reaction products |
US3223495A (en) * | 1961-09-11 | 1965-12-14 | Exxon Research Engineering Co | Motor fuel composition |
US3227532A (en) * | 1961-08-14 | 1966-01-04 | Exxon Research Engineering Co | Polymer-containing motor fuel composition |
US3256191A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Alkenoate derivatives |
US3256193A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Polyhydroxyoxaalkyl esters |
US3256192A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Reaction products of glycidols |
US3256189A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Hydrocarbyl ether reaction products |
US3256194A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Haloalkylene reaction products |
US3257318A (en) * | 1960-09-15 | 1966-06-21 | Exxon Research Engineering Co | Lubricating compositions containing a synergistic mixture of additives |
US3307928A (en) * | 1963-01-30 | 1967-03-07 | Exxon Research Engineering Co | Gasoline additives for enhancing engine cleanliness |
WO2010023621A2 (en) * | 2008-08-26 | 2010-03-04 | Dorf Ketal Chemicals (I) Pvt. Ltd. | A new additive for inhibiting acid corrosion and method of using the new additive |
US9090837B2 (en) | 2007-03-30 | 2015-07-28 | Dorf Ketal Chemicals (I) Private Limited | High temperature naphthenic acid corrosion inhibition using organophosphorous sulphur compounds and combinations thereof |
US9115319B2 (en) | 2007-09-14 | 2015-08-25 | Dorf Ketal Chemicals (I) Private Limited | Additive for naphthenic acid corrosion inhibition and method of using the same |
US9228142B2 (en) | 2007-04-04 | 2016-01-05 | Dorf Ketal Chemicals (I) Private Limited | Naphthenic acid corrosion inhibition using new synergetic combination of phosphorus compounds |
US10787619B2 (en) | 2008-08-26 | 2020-09-29 | Dorf Ketal Chemicals (India) Private Limited | Effective novel polymeric additive for inhibiting napthenic acid corrosion and method of using the same |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3001980A (en) * | 1956-08-04 | 1961-09-26 | Exxon Standard Sa | Lubricating oils |
US3201438A (en) * | 1962-08-09 | 1965-08-17 | Texaco Inc | Method of producing a monoester of a hydrocarbyl thiophosphonic acid and a polyalkylene glycol |
US3256190A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Thiophosphonoxyalkanes |
US3285853A (en) * | 1963-10-09 | 1966-11-15 | Texaco Inc | Hydrocarbonthiophosphonates and lubricant compositions thereof |
US3281359A (en) * | 1964-08-27 | 1966-10-25 | Texaco Inc | Neopentyl polyol derivatives and lubricating compositions |
US3272744A (en) * | 1964-10-27 | 1966-09-13 | Texaco Inc | Lubricants containing alkylene oxide reaction products |
-
1955
- 1955-09-08 FR FR1131205D patent/FR1131205A/en not_active Expired
-
1956
- 1956-07-06 GB GB21001/56A patent/GB792553A/en not_active Expired
-
1958
- 1958-10-24 GB GB34092/58A patent/GB838928A/en not_active Expired
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3257318A (en) * | 1960-09-15 | 1966-06-21 | Exxon Research Engineering Co | Lubricating compositions containing a synergistic mixture of additives |
US3087956A (en) * | 1960-09-30 | 1963-04-30 | Texaco Inc | Alkylene oxide reaction products |
US3227532A (en) * | 1961-08-14 | 1966-01-04 | Exxon Research Engineering Co | Polymer-containing motor fuel composition |
US3223495A (en) * | 1961-09-11 | 1965-12-14 | Exxon Research Engineering Co | Motor fuel composition |
US3256193A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Polyhydroxyoxaalkyl esters |
US3256192A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Reaction products of glycidols |
US3256189A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Hydrocarbyl ether reaction products |
US3256194A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Haloalkylene reaction products |
US3256191A (en) * | 1962-10-18 | 1966-06-14 | Texaco Inc | Alkenoate derivatives |
US3307928A (en) * | 1963-01-30 | 1967-03-07 | Exxon Research Engineering Co | Gasoline additives for enhancing engine cleanliness |
US9090837B2 (en) | 2007-03-30 | 2015-07-28 | Dorf Ketal Chemicals (I) Private Limited | High temperature naphthenic acid corrosion inhibition using organophosphorous sulphur compounds and combinations thereof |
US9228142B2 (en) | 2007-04-04 | 2016-01-05 | Dorf Ketal Chemicals (I) Private Limited | Naphthenic acid corrosion inhibition using new synergetic combination of phosphorus compounds |
US9115319B2 (en) | 2007-09-14 | 2015-08-25 | Dorf Ketal Chemicals (I) Private Limited | Additive for naphthenic acid corrosion inhibition and method of using the same |
WO2010023621A2 (en) * | 2008-08-26 | 2010-03-04 | Dorf Ketal Chemicals (I) Pvt. Ltd. | A new additive for inhibiting acid corrosion and method of using the new additive |
WO2010023621A3 (en) * | 2008-08-26 | 2010-08-19 | Dorf Ketal Chemicals (I) Pvt. Ltd. | A new additive for inhibiting acid corrosion and method of using the new additive |
US9890339B2 (en) | 2008-08-26 | 2018-02-13 | Dorf Ketal Chemicals (I) Private Limited | Additive for inhibiting acid corrosion and method of using the new additive |
US10787619B2 (en) | 2008-08-26 | 2020-09-29 | Dorf Ketal Chemicals (India) Private Limited | Effective novel polymeric additive for inhibiting napthenic acid corrosion and method of using the same |
Also Published As
Publication number | Publication date |
---|---|
GB838928A (en) | 1960-06-22 |
FR1131205A (en) | 1957-02-19 |
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