GB792553A - Improved additives suitable for lubricating oil compositions - Google Patents

Improved additives suitable for lubricating oil compositions

Info

Publication number
GB792553A
GB792553A GB21001/56A GB2100156A GB792553A GB 792553 A GB792553 A GB 792553A GB 21001/56 A GB21001/56 A GB 21001/56A GB 2100156 A GB2100156 A GB 2100156A GB 792553 A GB792553 A GB 792553A
Authority
GB
United Kingdom
Prior art keywords
product
lubricating oil
phosphorus
alkylene oxide
phosphosulphurizing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21001/56A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Esso SA
Original Assignee
Esso Standard SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Esso Standard SA filed Critical Esso Standard SA
Publication of GB792553A publication Critical patent/GB792553A/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/04—Reaction products of phosphorus sulfur compounds with hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • C10M2225/041—Hydrocarbon polymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/02—Bearings
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/12—Gas-turbines
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    • C10N2040/13—Aircraft turbines
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/135—Steam engines or turbines
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C—CHEMISTRY; METALLURGY
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/16—Dielectric; Insulating oil or insulators
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/17—Electric or magnetic purposes for electric contacts
    • C—CHEMISTRY; METALLURGY
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/175—Pantographs, i.e. printing devices
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/18—Electric or magnetic purposes in connection with recordings on magnetic tape or disc
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2040/185—Magnetic fluids
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
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    • C10N2040/241—Manufacturing joint-less pipes
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
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    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
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    • C10N2040/246—Iron or steel
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2040/253—Small diesel engines
    • C—CHEMISTRY; METALLURGY
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/30—Refrigerators lubricants or compressors lubricants
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/32—Wires, ropes or cables lubricants
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    • C10N2040/34—Lubricating-sealants
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    • C10N2040/36—Release agents or mold release agents
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    • C10N2040/38—Conveyors or chain belts
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    • C10N2040/40—Generators or electric motors in oil or gas winning field
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/42—Flashing oils or marking oils
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    • C10N2040/44—Super vacuum or supercritical use
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    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy
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    • C10N2070/02—Concentrating of additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Lubricants (AREA)

Abstract

The invention comprises additive compounds for lubricating oils (see Group III), prepared by phosphosulphurizing a hydrocarbon and reacting the product thus obtained with a C2 to C6 alkylene oxide. In the first stage of the reaction a hydrocarbon is reacted with a mixture of phosphorus and sulphur or a phosphorus sulphide, preferably phosphorus pentasulphide. Specified hydrocarbons are paraffins, olefins, acetylenic hydrocarbons, alkyl-aromatic or cyclo-aliphatic hydrocarbons, petroleum fractions, bright stocks, lubricating oil distillates and waxes. In the second stage the product is condensed with the alkylene oxide at about 285 DEG F. Specified alkylene oxides are ethylene and propylene oxides. In an example a bright stock solvent is treated with phosphorus pentasulphide in a nitrogen atmosphere and the product is either reacted directly with ethylene oxide or treated with an activated earth in a carbon dioxide atmosphere before reaction with ethylene oxide.ALSO:Additives for lubricating oil compositions comprise the products obtained by phosphosulphurizing a hydrocarbon and reacting the product thus obtained with a C2 to C6 alkylene oxide (see Groups IV (a) and IV (b)). They may be incorporated in synthetic, animal, vegetable or mineral lubricating oils, distillates derived from crude paraffin, naphthenic, asphaltic or mixed oils, together with the usual additives. Various tests carried out on lubricating oil compositions containing the additives are described.ALSO:Additive compounds for lubricating oils (see Group III) are prepared by phosphosulphurizing a polyolefin in known manner and reacting the product with a C2 to C6 alkylene oxide. In an example a polyisobutylene having a molecular weight of about 1200 is reacted with phosphorus pentasulphide in an atmosphere of nitrogen and the product is treated with ethylene oxide.
GB21001/56A 1955-09-08 1956-07-06 Improved additives suitable for lubricating oil compositions Expired GB792553A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1131205T 1955-09-08

Publications (1)

Publication Number Publication Date
GB792553A true GB792553A (en) 1958-03-26

Family

ID=9637745

Family Applications (2)

Application Number Title Priority Date Filing Date
GB21001/56A Expired GB792553A (en) 1955-09-08 1956-07-06 Improved additives suitable for lubricating oil compositions
GB34092/58A Expired GB838928A (en) 1955-09-08 1958-10-24 Oxyalkylated phosphosulphurised hydrocarbons and lubricating compositions therefrom

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB34092/58A Expired GB838928A (en) 1955-09-08 1958-10-24 Oxyalkylated phosphosulphurised hydrocarbons and lubricating compositions therefrom

Country Status (2)

Country Link
FR (1) FR1131205A (en)
GB (2) GB792553A (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3087956A (en) * 1960-09-30 1963-04-30 Texaco Inc Alkylene oxide reaction products
US3223495A (en) * 1961-09-11 1965-12-14 Exxon Research Engineering Co Motor fuel composition
US3227532A (en) * 1961-08-14 1966-01-04 Exxon Research Engineering Co Polymer-containing motor fuel composition
US3256191A (en) * 1962-10-18 1966-06-14 Texaco Inc Alkenoate derivatives
US3256194A (en) * 1962-10-18 1966-06-14 Texaco Inc Haloalkylene reaction products
US3256189A (en) * 1962-10-18 1966-06-14 Texaco Inc Hydrocarbyl ether reaction products
US3256192A (en) * 1962-10-18 1966-06-14 Texaco Inc Reaction products of glycidols
US3256193A (en) * 1962-10-18 1966-06-14 Texaco Inc Polyhydroxyoxaalkyl esters
US3257318A (en) * 1960-09-15 1966-06-21 Exxon Research Engineering Co Lubricating compositions containing a synergistic mixture of additives
US3307928A (en) * 1963-01-30 1967-03-07 Exxon Research Engineering Co Gasoline additives for enhancing engine cleanliness
WO2010023621A2 (en) * 2008-08-26 2010-03-04 Dorf Ketal Chemicals (I) Pvt. Ltd. A new additive for inhibiting acid corrosion and method of using the new additive
US9090837B2 (en) 2007-03-30 2015-07-28 Dorf Ketal Chemicals (I) Private Limited High temperature naphthenic acid corrosion inhibition using organophosphorous sulphur compounds and combinations thereof
US9115319B2 (en) 2007-09-14 2015-08-25 Dorf Ketal Chemicals (I) Private Limited Additive for naphthenic acid corrosion inhibition and method of using the same
US9228142B2 (en) 2007-04-04 2016-01-05 Dorf Ketal Chemicals (I) Private Limited Naphthenic acid corrosion inhibition using new synergetic combination of phosphorus compounds
US10787619B2 (en) 2008-08-26 2020-09-29 Dorf Ketal Chemicals (India) Private Limited Effective novel polymeric additive for inhibiting napthenic acid corrosion and method of using the same

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US3001980A (en) * 1956-08-04 1961-09-26 Exxon Standard Sa Lubricating oils
US3201438A (en) * 1962-08-09 1965-08-17 Texaco Inc Method of producing a monoester of a hydrocarbyl thiophosphonic acid and a polyalkylene glycol
US3256190A (en) * 1962-10-18 1966-06-14 Texaco Inc Thiophosphonoxyalkanes
US3285853A (en) * 1963-10-09 1966-11-15 Texaco Inc Hydrocarbonthiophosphonates and lubricant compositions thereof
US3281359A (en) * 1964-08-27 1966-10-25 Texaco Inc Neopentyl polyol derivatives and lubricating compositions
US3272744A (en) * 1964-10-27 1966-09-13 Texaco Inc Lubricants containing alkylene oxide reaction products

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3257318A (en) * 1960-09-15 1966-06-21 Exxon Research Engineering Co Lubricating compositions containing a synergistic mixture of additives
US3087956A (en) * 1960-09-30 1963-04-30 Texaco Inc Alkylene oxide reaction products
US3227532A (en) * 1961-08-14 1966-01-04 Exxon Research Engineering Co Polymer-containing motor fuel composition
US3223495A (en) * 1961-09-11 1965-12-14 Exxon Research Engineering Co Motor fuel composition
US3256194A (en) * 1962-10-18 1966-06-14 Texaco Inc Haloalkylene reaction products
US3256189A (en) * 1962-10-18 1966-06-14 Texaco Inc Hydrocarbyl ether reaction products
US3256192A (en) * 1962-10-18 1966-06-14 Texaco Inc Reaction products of glycidols
US3256193A (en) * 1962-10-18 1966-06-14 Texaco Inc Polyhydroxyoxaalkyl esters
US3256191A (en) * 1962-10-18 1966-06-14 Texaco Inc Alkenoate derivatives
US3307928A (en) * 1963-01-30 1967-03-07 Exxon Research Engineering Co Gasoline additives for enhancing engine cleanliness
US9090837B2 (en) 2007-03-30 2015-07-28 Dorf Ketal Chemicals (I) Private Limited High temperature naphthenic acid corrosion inhibition using organophosphorous sulphur compounds and combinations thereof
US9228142B2 (en) 2007-04-04 2016-01-05 Dorf Ketal Chemicals (I) Private Limited Naphthenic acid corrosion inhibition using new synergetic combination of phosphorus compounds
US9115319B2 (en) 2007-09-14 2015-08-25 Dorf Ketal Chemicals (I) Private Limited Additive for naphthenic acid corrosion inhibition and method of using the same
WO2010023621A2 (en) * 2008-08-26 2010-03-04 Dorf Ketal Chemicals (I) Pvt. Ltd. A new additive for inhibiting acid corrosion and method of using the new additive
WO2010023621A3 (en) * 2008-08-26 2010-08-19 Dorf Ketal Chemicals (I) Pvt. Ltd. A new additive for inhibiting acid corrosion and method of using the new additive
US9890339B2 (en) 2008-08-26 2018-02-13 Dorf Ketal Chemicals (I) Private Limited Additive for inhibiting acid corrosion and method of using the new additive
US10787619B2 (en) 2008-08-26 2020-09-29 Dorf Ketal Chemicals (India) Private Limited Effective novel polymeric additive for inhibiting napthenic acid corrosion and method of using the same

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GB838928A (en) 1960-06-22
FR1131205A (en) 1957-02-19

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