GB791851A - Elastomeric latices derived from diisocyanates and substances containing active hydrogen atoms - Google Patents
Elastomeric latices derived from diisocyanates and substances containing active hydrogen atomsInfo
- Publication number
- GB791851A GB791851A GB17981/54A GB1798154A GB791851A GB 791851 A GB791851 A GB 791851A GB 17981/54 A GB17981/54 A GB 17981/54A GB 1798154 A GB1798154 A GB 1798154A GB 791851 A GB791851 A GB 791851A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diisocyanate
- added
- latex
- organic
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/80—Compositions for aqueous adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2350/00—Acoustic or vibration damping material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2380/00—Tyres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2410/00—Soles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
An elastomeric latex is made by reacting an organic compound having a molecular weight of at least 750 and containing at least two groups bearing active hydrogen atoms with a stoichiometric excess of an organic diisocyanate and thereafter effecting chain extension of the reaction product by emulsifying it in aqueous medium and in the presence of an emulsifying agent. The aqueous medium may contain a diamine (e.g. phenylene-, tolylene-, cyclohexylene-, propylene- or ethylene-diamine) which reacts, with the isocyanate terminated polymer preferentially to the water. The organic compound with a molecular weight of at least 750 may be a linear or branched polyester, a polyesteramide, a polyalkylene glycol, a polyalkylene ether-thioether glycol having terminal hydroxyl groups or an ester of a hydroxy fatty acid with a polyhydric alcohol (e.g. castor oil or glyceryl ricinoleate). A mixture of castor oil and polyethylene glycol may be used. In addition to these organic compounds smaller amounts of low molecular weight diols (e.g.2-butene-1,4-diol) may be used. The Specification lists suitable starting materials of the type referred to above. Suitable emulsifying agents are the polyethylene glycol ethers of long-chain alcohols, quaternary ammonium salts, the tertiary amine or alkylol amine salts of long-chain alkyl acid sulphate esters, alkyl sulphonic acids or alkyl aryl sulphonic acids, the sodium salt of long-chain sulphated alcohols, casein, and alkali metal salts of high molecular weight organic acids (e.g. rosin or tall oil). The last named may be formed in situ by adding the acid to the isocyanate terminated polymer and adding alkali to the aqueous bath. The isocyanate terminated polymer may be added to the aqueous medium while dissolved in an organic solvent (e.g. heptanes, octanes, nonanes, kerosenes, synthetic hydrocarbons, methylcyclohexane, benzene or toluene). Coagulation of the latex may be effected by adding an acid (e.g. acetic) and/or an inorganic salt (e.g. sodium or calcium chloride) or by freezing. In an example, a film of elastomer is formed by dipping a cylindrical glass mould first into a coagulating solution and then into a latex, the coagulating solution comprising methanol, acetone, calcium nitrate and calcium chloride. The coagulated polymer may then be dried and cured by milling it with a diisocyanate. Films of the dried polymer may be cured either by dipping into a liquid diisocyanate or a solution thereof or by exposure to the vapours of a diisocyanate. In Example 21, toluene is added to the reaction product of castor oil, polyethylene glycol and 2,4-tolylenediisocyanate and the mixture added to a solution containing water, the sodium salt of sulphated long-chain alcohols, casein and an anti-foaming agent comprising pine oil and tributyl phosphate. An emulsion suitable for gluing wood results. In Example 25, tall oil is added to the reaction product of polytetramethylene ether glycol and 2,4-tolylene diisocyanate and the mixture added to sodium hydroxide solution to produce a latex. A curing agent is then dispersed in the latex comprising the dimer of 2,4-tolylene diisocyanate, the sodium salt of polymerized formaldehyde napthalene sulphonic acids, water and casein. A dip film is then made, coagulated and dried. The elastomers may be made fireproof by adding antimony or zinc oxide and electrically conductive by adding carbon black or powdered metals. Compounding agents such as carbon black, clay, silica, talc, zinc and magnesium oxides, calcium and magnesium carbonate, titanium dioxide, plasticizers and inorganic or organic colouring agents may be added. The Specification lists a large number of uses for the elastomers. Specifications 731,071, 753,712, [Group IV (b)], 791,852 and 791,854 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US791851XA | 1953-06-30 | 1953-06-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB791851A true GB791851A (en) | 1958-03-12 |
Family
ID=22148955
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB17981/54A Expired GB791851A (en) | 1953-06-30 | 1954-06-18 | Elastomeric latices derived from diisocyanates and substances containing active hydrogen atoms |
Country Status (5)
Country | Link |
---|---|
CA (1) | CA583572A (en) |
DE (1) | DE1097678B (en) |
FR (1) | FR1108785A (en) |
GB (1) | GB791851A (en) |
IT (1) | IT517966A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015048441A1 (en) * | 2013-09-30 | 2015-04-02 | Basf Se | Lignocellulosic composite articles |
CN115141597A (en) * | 2022-08-04 | 2022-10-04 | 河南工程学院 | Castor oil-based degradable pressure-sensitive adhesive and preparation method thereof |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1007502B (en) * | 1955-06-10 | 1957-05-02 | Bayer Ag | Process for the production of rubber-elastic plastics from polythioethers containing hydroxyl groups, diisocyanates and crosslinking agents |
NL104700C (en) * | 1955-08-12 | |||
US2901467A (en) * | 1956-04-20 | 1959-08-25 | Du Pont | Polyurethane coating compositions |
US2899411A (en) * | 1956-07-30 | 1959-08-11 | Polyurethane elastomers from hy- | |
DE1027395B (en) * | 1956-10-01 | 1958-04-03 | Phoenix Gummiwerke Ag | Process for the production of light-resistant, elastic plastics |
US2948611A (en) * | 1957-10-30 | 1960-08-09 | Du Pont | Photopolymerizable compositions, elements, and processes |
BE570635A (en) * | 1957-11-06 | 1900-01-01 | ||
US2995531A (en) * | 1958-09-08 | 1961-08-08 | Mobay Chemical Corp | Stable coating compositions containing a polyisocyanate and a polyamide |
US3148173A (en) * | 1959-01-26 | 1964-09-08 | Wyandotte Chemicals Corp | Polyurethane-ureas containing urealinked nu-(2-hydroxypropyl) alkylene diamines |
GB880665A (en) * | 1959-01-26 | 1961-10-25 | Wyandotte Chemicals Corp | Polyurethane-ureas containing urea-linked piperazine compounds |
US3178310A (en) * | 1962-03-01 | 1965-04-13 | Du Pont | Aqueous polyurethane coating emulsions |
BE636685A (en) * | 1962-08-28 | |||
BE637982A (en) * | 1962-10-01 | |||
US3350332A (en) * | 1962-10-05 | 1967-10-31 | Monsanto Co | Rigid polyvinyl chloride blends having improved impact strength |
DE1248287B (en) * | 1965-12-18 | 1967-08-24 | Bayer Ag | Process for the production of molded articles from aqueous polyurethane dispersions |
DE1282962B (en) * | 1966-04-28 | 1968-11-14 | Bayer Ag | Process for the production of aqueous sedimenting, redispersible dispersions of crosslinked polyadducts containing urea groups |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE957564C (en) * | 1957-01-17 | Farbenfabriken Bayer Aktiengesellschaft, Leverkusen-Bayerwerk | Process for coating or preparing carrier materials such as fabrics, textiles, foils with plastics | |
DE896716C (en) * | 1943-12-28 | 1953-11-16 | Bayer Ag | Process for the manufacture of rubber-like articles |
DE819086C (en) * | 1949-09-23 | 1951-10-29 | Bayer Ag | Process for coating textiles |
DE831772C (en) * | 1952-11-18 | 1952-02-18 | Bayer Ag | Process for the production of high molecular weight crosslinked plastics |
-
0
- IT IT517966D patent/IT517966A/it unknown
- CA CA583572A patent/CA583572A/en not_active Expired
-
1954
- 1954-06-18 GB GB17981/54A patent/GB791851A/en not_active Expired
- 1954-06-28 DE DEP12223A patent/DE1097678B/en active Pending
- 1954-06-30 FR FR1108785D patent/FR1108785A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015048441A1 (en) * | 2013-09-30 | 2015-04-02 | Basf Se | Lignocellulosic composite articles |
US9920202B2 (en) | 2013-09-30 | 2018-03-20 | Basf Se | Lignocellulosic composite articles |
US10669424B2 (en) | 2013-09-30 | 2020-06-02 | Basf Se | Lignocellulosic composite articles |
CN115141597A (en) * | 2022-08-04 | 2022-10-04 | 河南工程学院 | Castor oil-based degradable pressure-sensitive adhesive and preparation method thereof |
CN115141597B (en) * | 2022-08-04 | 2023-04-28 | 河南工程学院 | Castor oil-based degradable pressure-sensitive adhesive and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
IT517966A (en) | |
DE1097678B (en) | 1961-01-19 |
FR1108785A (en) | 1956-01-17 |
CA583572A (en) | 1959-09-22 |
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