GB790837A - Improvements in or relating to the treatment of fibrous materials with resinous condensation products - Google Patents
Improvements in or relating to the treatment of fibrous materials with resinous condensation productsInfo
- Publication number
- GB790837A GB790837A GB1190054A GB1190054A GB790837A GB 790837 A GB790837 A GB 790837A GB 1190054 A GB1190054 A GB 1190054A GB 1190054 A GB1190054 A GB 1190054A GB 790837 A GB790837 A GB 790837A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- condensation product
- succinic
- polyethylene glycol
- aminoaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Organic textile materials are treated with an aqueous solution containing an intermediate condensation product of an aminoaldehyde resin, an acidic catalyst for further condensing the resin and a condensation product of a polyhydric alcohol and a mono- or polycarboxylic acid or of a monohydric alcohol and a polycarboxylic acid, and thereafter the fibres are dried and heated to form the aminoaldehyde resin. In a modification, the aminoaldehyde and the condensation product are applied separately. The textile materials treated may be fibres, threads, yarns, fabrics or felts of cotton, linen, regenerated cellulose or wool and the process provides a crease-resistant, stiffened or shrink-resistant finish or may be employed in the fixation of mechanical effects, e.g. glazing or embossing, for the improvement of colour fastness of direct dyes and for pigment printing. The treating composition is said to enhance the effects of daylight fluorescent dyestuffs which may be included therein. The aminoaldehyde condensate may be prepared from urea, thiourea or melamine and formaldehyde. The molecular ratio of formaldehyde to urea may be more than 1.6 to 1. The ester condensation product has hydrophilic groups and may be obtained by reacting sebacic, maleic, succinic or phthalic acid or anhydride or a fatty acid derived from a vegetable or animal oil or an amino or hydroxy acid with a glycol or polyglycol. Mixtures of acids or alcohols may be used. In examples, condensates of polyethylene glycol, M.W.400, and maleic anhydride in equimolecular amounts having an acid number of 55 to 65, of polyethylene glycol and a mixture of maleic anhydride and linseed oil fatty acid, of polyethylene glycol and a mixture of succinic and fumaric acids, having an acid value of 23, of triethylene glycol and a mixture of succinic acid and phthalic anhydride having an acid value of 90 and of polyethylene glycol and acetic acid are included in solutions with urea-formaldehyde and ammonium dihydrogen phosphate. In one example the solution is stabilized with hexamethylenetetramine. In another example the composition contains a pigmented dye and a water-soluble cellulose derivative thickener. Textile fabrics are treated with these solutions, mangled, dried on stenters, in some cases using superheated steam at 100 DEG C., and are baked, e.g. at 140 DEG C. The second Provisional Specification describes in Example (4) the treatment of cotton with a composition comprising urea-formaldehyde pre-condensate and condensation product of ethylene diamine and succinic anhydride.ALSO:Organic textile materials are treated with an aqueous solution containing an intermediate condensation product of an aminoaldehyde resin, an acidic catalyst for further condensing the resin and a condensation product of a polyhydric alcohol and a mono- or poly-carboxylic acid or of a monohydric alcohol and a polycarboxylic acid, and thereafter the fibres are dried and heated to form the aminoaldehyde resin. In a modification, the aminoaldehyde and the condensation product are applied separately. The textile materials treated may be fibres, threads, yarns, fabrics or felts of cotton, linen, regenerated cellulose or wool and the process provides a crease-resistant, stiffened or shrink-resistant finish or may be employed in the fixation of mechanical effects, e.g. glazing or embossing, for the improvement of colour fastness of direct dyes and for pigment printing. The treating composition is said to enhance the effects of daylight fluorescent dyestuffs which may be included therein. The aminoaldehyde condensate may be prepared from urea, thiourea or melamine and formaldehyde. The molecular ratio of formaldehyde to urea may be more than 1.6 to 1. The ester condensation product has hydrophilic groups and may be obtained by reacting sebacic, maleic, succinic or phthalic acid or anhydride or a fatty acid derived from a vegetable or animal oil or an amino or hydroxy acid with a glycol or polyglycol. Mixtures of acids or alcohols may be used. In examples, condensates of polyethylene glycol, M.W. 400, and maleic anhydride in equimolecular amounts having an acid number of 55 to 65, of polyethylene glycol and a mixture of maleic anhydride and linseed oil fatty acid, of polyethylene glycol and a mixture of succinic and fumaric acids, having an acid value of 23, of triethylene glycol and a mixture of succinic acid and phthalic anhydride having an acid value of 90 and of polyethylene glycol and acetic acid are included in solutions with urea formaldehyde and ammonium dihydrogen phosphate. In one example, the solution is stabilized with hexamethylenetetramine. In another example the composition contains a pigmented dye and a water-soluble cellulose derivative thickener. Textile fabrics are treated with these solutions, mangled, dried on stenters, in some cases using superheated steam at 100 DEG C., and are baked, e.g. at 140 DEG C. The second Provisional Specification describes in Example (4) the treatment of cotton with a composition comprising ureaformaldehyde pre-condensate and condensation product of ethylene diamine and succinic anhydride.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1190054A GB790837A (en) | 1954-04-24 | 1954-04-24 | Improvements in or relating to the treatment of fibrous materials with resinous condensation products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1190054A GB790837A (en) | 1954-04-24 | 1954-04-24 | Improvements in or relating to the treatment of fibrous materials with resinous condensation products |
Publications (1)
Publication Number | Publication Date |
---|---|
GB790837A true GB790837A (en) | 1958-02-19 |
Family
ID=9994712
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1190054A Expired GB790837A (en) | 1954-04-24 | 1954-04-24 | Improvements in or relating to the treatment of fibrous materials with resinous condensation products |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB790837A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1191330B (en) * | 1959-03-30 | 1965-04-22 | Owens Corning Fiberglass Corp | Process for the production of coatings on glass fibers and glass fiber fabrics |
-
1954
- 1954-04-24 GB GB1190054A patent/GB790837A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1191330B (en) * | 1959-03-30 | 1965-04-22 | Owens Corning Fiberglass Corp | Process for the production of coatings on glass fibers and glass fiber fabrics |
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