GB785474A - Process for the production of polyalkylene oxide-polybasic carboxylic acid condensation products - Google Patents

Process for the production of polyalkylene oxide-polybasic carboxylic acid condensation products

Info

Publication number
GB785474A
GB785474A GB8090/55A GB809055A GB785474A GB 785474 A GB785474 A GB 785474A GB 8090/55 A GB8090/55 A GB 8090/55A GB 809055 A GB809055 A GB 809055A GB 785474 A GB785474 A GB 785474A
Authority
GB
United Kingdom
Prior art keywords
acid
molecular weight
products
oxides
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8090/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boehme Fettchemie GmbH
Original Assignee
Boehme Fettchemie GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boehme Fettchemie GmbH filed Critical Boehme Fettchemie GmbH
Publication of GB785474A publication Critical patent/GB785474A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/53—Polyethers; Polyesters

Abstract

A polyalkylene oxide or derivative thereof, of molecular weight greater than 1000, and which has a lipophilic group and at least one free hydroxyl group condensed with a polybasic carboxylic acid or ester containing at least three carboxyl groups and at least one lipophilic group (see Group IV (a)) is used as a dispersing agent alone or in combination with known emulsifiers. Specified polyalkylene oxides are the reaction products of alkylene oxides, e.g. propylene oxide, and epichlorhydrin with polyhydric alcohols, e.g. glycerine and pentaerythritol; whilst the derivatives thereof comprise the reaction products of higher molecular weight alcohols, amines or mercaptans with ethylene oxide, or the esterification or etherification products of higher molecular weight carboxylic acids or alcohols with polyethylene oxides. Specified acids are the reaction products of unsaturated fatty acids, e.g. oleic acid, linoleic acid, ricinoleic acid, erucic acid, mixtures of unsaturated fatty acids from marine animal oils or brassidic acid with maleic anhydride. Emulsified are mineral, animal, vegetable or synthetic fats or waxes (which may be sulphonated), natural or synthetic resins or oils, natural or synthetic rubber or albumens. Other dispersing agents which may be coemployed are alkyl sulphates and sulphonates, alkyl-benzene sulphonates, alkyl phosphates, ethylene oxide addition products of fatty acids or cation active compounds.ALSO:Polyalkylene oxides or derivatives thereof, said oxides or derivatives possessing in addition to a lipophilic group at least one free hydroxyl group and having a molecular weight of at least 1000 are condensed with a polycarboxylic acid containing at least three carboxyl groups and at least one lipophilic group. Specified lipophilic groups are aliphatic, cycloaliphatic or aliphaticaromatic groups containing at least six carbon atoms. Specified polyalkylene oxides contain a plurality of alkylene oxide groups, e.g. polyethylene glycols with a molecular weight not greater than 10,000, or reaction products of alkylene oxides or epichlorhydrin with polyhydric alcohols, e.g. glucose or pentaerythritol. The polyalkylene oxide derivatives are defined as the condensation products of alkylene oxides with high molecular weight compounds which contain linked through oxygen, sulphur or nitrogen, a lipophilic group and at least one free hydroxyl group, e.g. the reaction products of higher molecular weight alcohols, amines or mercaptans with ethylene oxide, or the esterification or etherification products of higher molecular weight alcohols or carboxylic acids with polyethylene oxides. The polybasic acids may be prepared by reacting unsaturated hydrocarbons or fatty acids, e.g. oleic acid, linoleic acid, ricinoleic acid, erucic acid or brassidic acid with maleic anhydride. In the examples: (1) a polyethylene glycol of average molecular weight 9000 is condensed with a reaction product of soya oil fatty acid and maleic anhydride, in examples (2) to (4), a polyethylene oxide of average molecular weight 9000 is condensed with a reaction product of maleic anhydride and (2) linoleic acid, (3) oleic acid, and (4) soya oil fatty acid. Examples (5) to (9) describe the treatment of products similar to those in examples (1) to (4) by (5) heating with sulphonated sperm oil and sodium alkyl sulphate, an aqueous emulsion formed with the resultant mixture being mixed with chrome tanning salts, (6) dissolving in water, mixing with neat's-foot oil and emulsifying, (7) dissolving in water and mixing with chloroparaffin, decalin and powdered chromium oxide, (8) dissolving in water and mixing with a reaction product of oleyl alcohol and ethylene oxide, sperm oil then being added to form an emulsion, (9) dissolving in water and mixing with carnauba wax to form an emulsion. The products may be used as auxiliary agents for leather and textiles, thickening agents, dispersing and emulsifying agents, surface protection agents and as solid vehicles for colouring matter.
GB8090/55A 1954-03-22 1955-03-21 Process for the production of polyalkylene oxide-polybasic carboxylic acid condensation products Expired GB785474A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE785474X 1954-03-22

Publications (1)

Publication Number Publication Date
GB785474A true GB785474A (en) 1957-10-30

Family

ID=6698779

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8090/55A Expired GB785474A (en) 1954-03-22 1955-03-21 Process for the production of polyalkylene oxide-polybasic carboxylic acid condensation products

Country Status (1)

Country Link
GB (1) GB785474A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1115027B (en) * 1958-03-26 1961-10-12 Bayer Ag Process for the preparation of diesters from polyethers having a free hydroxyl group
FR2538810A1 (en) * 1982-12-31 1984-07-06 Nippon Paint Co Ltd DISPERSING RESIN FOR PIGMENTS, PIGMENT PULP CONTAINING THE RESIN, AND COATING COMPOSITIONS BASED ON THE PIGMENTARY PULP
US5011630A (en) * 1985-06-07 1991-04-30 National Starch And Chemical Investment Holding Corporation Emulsifiable triglyceride compositions
US5030388A (en) * 1985-06-07 1991-07-09 National Starch And Chemical Investment Holding Corporation Emulsifiable triglyceride compositions
US5292480A (en) * 1992-06-11 1994-03-08 Westvaco Corporation Acid-anhydride esters as oil field corrosion inhibitors
US5759485A (en) * 1997-05-12 1998-06-02 Westvaco Corporation Water soluble corrosion inhibitors
US9023929B2 (en) 2004-02-13 2015-05-05 Lawter, Inc. Tackifier dispersion

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1115027B (en) * 1958-03-26 1961-10-12 Bayer Ag Process for the preparation of diesters from polyethers having a free hydroxyl group
FR2538810A1 (en) * 1982-12-31 1984-07-06 Nippon Paint Co Ltd DISPERSING RESIN FOR PIGMENTS, PIGMENT PULP CONTAINING THE RESIN, AND COATING COMPOSITIONS BASED ON THE PIGMENTARY PULP
GB2133025A (en) * 1982-12-31 1984-07-18 Nippon Paint Co Ltd Polymers and pigment-in-polymer dispersions
US5011630A (en) * 1985-06-07 1991-04-30 National Starch And Chemical Investment Holding Corporation Emulsifiable triglyceride compositions
US5030388A (en) * 1985-06-07 1991-07-09 National Starch And Chemical Investment Holding Corporation Emulsifiable triglyceride compositions
US5292480A (en) * 1992-06-11 1994-03-08 Westvaco Corporation Acid-anhydride esters as oil field corrosion inhibitors
US5759485A (en) * 1997-05-12 1998-06-02 Westvaco Corporation Water soluble corrosion inhibitors
US9023929B2 (en) 2004-02-13 2015-05-05 Lawter, Inc. Tackifier dispersion

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