GB784611A - Curing of polymerisable materials - Google Patents

Curing of polymerisable materials

Info

Publication number
GB784611A
GB784611A GB2737254A GB2737254A GB784611A GB 784611 A GB784611 A GB 784611A GB 2737254 A GB2737254 A GB 2737254A GB 2737254 A GB2737254 A GB 2737254A GB 784611 A GB784611 A GB 784611A
Authority
GB
United Kingdom
Prior art keywords
allyloxyalkanol
phthalate
methacrylate
curing
esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2737254A
Inventor
Geoffrey Lambsin Foster
Peter Francis Nicks
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2737254A priority Critical patent/GB784611A/en
Publication of GB784611A publication Critical patent/GB784611A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/46—Polyesters chemically modified by esterification
    • C08G63/47—Polyesters chemically modified by esterification by unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

Acrylate and methacrylate esters are cured or polymerized in the presence of a drier, e.g. cobalt, manganese and lead naphthenates, a hydroperoxide curing catalyst, e.g. cyclohexyl, methyl ethyl ketone, tertiary butyl, paramenthane, di-isopropyl benzene and cumene hydroperoxides, and an ester derived from an allyloxyalkanol, e.g. alpha-allyl glyceryl phthalate and succinate and allyloxymethyl and allyloxyisopropyl methacrylates. Suitable acrylic and methacrylic esters are the polyesters described in Specification 607,888, e.g. ethylene glycol methacrylate/phthalate. The process may be used in making laminates with glass-cloth reinforcement, the allyloxyalkanol component being either mixed with part or the whole of the laminating resin or else a solution, e.g. in glycol dimethacrylate, may be brushed or sprayed on to the outer layer of the laminated body.
GB2737254A 1954-09-22 1954-09-22 Curing of polymerisable materials Expired GB784611A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2737254A GB784611A (en) 1954-09-22 1954-09-22 Curing of polymerisable materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2737254A GB784611A (en) 1954-09-22 1954-09-22 Curing of polymerisable materials

Publications (1)

Publication Number Publication Date
GB784611A true GB784611A (en) 1957-10-09

Family

ID=10258543

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2737254A Expired GB784611A (en) 1954-09-22 1954-09-22 Curing of polymerisable materials

Country Status (1)

Country Link
GB (1) GB784611A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140279A (en) * 1961-08-03 1964-07-07 Grace W R & Co Post extrusion crosslinking of polyethylene
US4322490A (en) 1980-11-17 1982-03-30 Eastman Kodak Company Photopolymerizable compositions featuring improved monomers
EP0364169A2 (en) * 1988-10-13 1990-04-18 Nippon Oil And Fats Company, Limited Polymeric peroxy ester and its use

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140279A (en) * 1961-08-03 1964-07-07 Grace W R & Co Post extrusion crosslinking of polyethylene
US4322490A (en) 1980-11-17 1982-03-30 Eastman Kodak Company Photopolymerizable compositions featuring improved monomers
EP0364169A2 (en) * 1988-10-13 1990-04-18 Nippon Oil And Fats Company, Limited Polymeric peroxy ester and its use
EP0364169A3 (en) * 1988-10-13 1991-06-12 Nippon Oil And Fats Company, Limited Polymeric peroxy ester and its use

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