GB780316A - Pigment preparations, their manufacture and use - Google Patents

Pigment preparations, their manufacture and use

Info

Publication number
GB780316A
GB780316A GB18588/53A GB1858853A GB780316A GB 780316 A GB780316 A GB 780316A GB 18588/53 A GB18588/53 A GB 18588/53A GB 1858853 A GB1858853 A GB 1858853A GB 780316 A GB780316 A GB 780316A
Authority
GB
United Kingdom
Prior art keywords
kneaded
pigment
organic
sodium chloride
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18588/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba AG filed Critical Ciba AG
Publication of GB780316A publication Critical patent/GB780316A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/006Preparation of organic pigments

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Artificial Filaments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Pigment preparations comprising a pigment in fine dispersion in an organic substance are made by subjecting a pigment to a mechanical treatment producing a shearing or kneading action in an organic medium having a viscosity of at least 10 centipoises at 20 DEG C., or in a melt of an organic medium which is solid at 20 DEG C., in presence of a grinding body (constituting at least one-fifth of the weight of pigment) which is subsequently washed out, and when the organic medium is a thermoplastic water-insoluble film-forming substance having a capacity for water-imbibition similar to cellulose acetate and a compact substantially dry solid complex containing water-soluble salts and pigment is formed and said complex is subjected to aqueous extraction using the grinding body in an amount at least equal to the amount of dyestuff present. The pigment may be inorganic, e.g. carbon black, or organic, e.g. azo dyes or phthalocyanines. The organic medium may be (1) an animal, vegetable, or mineral oil, or a plasticiser, such as dibutyl phthalate, or (2) it may be a solution of a solid substance, e.g. a natural or artificial resin, rubber or a rubber derivative, or a cellulose derivative, in a comparatively low-boiling organic solvent such as toluene, or (3) a melt of colophony. Grinding bodies comprise inorganic salts as sodium, potassium or barium chlorides, or sodium sulphate, and organic compounds such as urea. They may be removed by washing with water or an organic solvent. In the case of organic media (2) above, the extracting solvent may be miscible with the organic solvent, but if not, the latter may be removed by evaporation before or after extraction. The products colour lacquers, oily coating compositions, artificial substances, and especially spinning solutions, e.g. of cellulose acetate, nylon, superpolyurethanes, polyacrylonitriles, terephthalic acid glycol polyesters, polyvinyl compounds or polyvinyl-polyacrylic copolymers. In examples: (1) reprecipitated or crude copper phthalocyanine (which may be chlorinated) or the dyestuff 2-methyl-4-chloro-1-aminobenzene --> 1 - (21 - oxy - 31 - naphthoyl) - amino - 2 - methyl-4-chloro-benzene is kneaded with a glycerine ester of hydrogenated colophony and with toluene and sodium chloride; (2) 4,41-dimethyl - 6:61 - dichloro - thioindigo is kneaded with dibutyl phthalate and sodium chloride; (3) indigo is kneaded with a glycerine ester of hydrogenated colophony, sodium carbonate, and toluene; (4) the dye 2,5-dichloro-1-aminobenzene --> 1-(21-oxy-31-naphthoyl)-amino-2,5-dimethoxybenzene is kneaded with sodium chloride, toluene, and either ethyl cellulose or chlorinated rubber; (5) reprecipitated copper phthalocyanine is kneaded with acetyl cellulose, sodium chloride, and glycol monomethyl ether; (6) the dye 2-methyl-4-chloro-1-aminobenzene --> 1 - (21 - oxy - 31 - naphthoyl) - amino - 2 - methyl-4-chlorbenzene is kneaded with acetyl cellulose, ammonium chloride, and glycol monomethyl ether, or with sodium chloride and colophony; (7) chlorinated copper phthalocyanine is kneaded with sodium chloride and a solution of nylon in formic acid; (8) dihydroanthraquinone 1,2,21,11-azine is kneaded with sodium chloride and a solution of polyacrylonitrile in dimethyl-formamide; (9) chlorinated copper phthalocyanine is kneaded with a glycerine ester of hydrogenated colophony, sodium chloride and diacetone alcohol. Further examples describe applications of the above, viz. (10) the product of (2) is mixed with polyvinyl chloride and dioctyl phthalate to give a coloured foil; (11) the product of (1) is mixed with an alkyd resin lacquer, and the product of (5) with butyl acetate and a nitrocellulose lacquer; (12) the product of (5) is added to a cellulose acetate spinning solution consisting of acetyl cellulose and acetone; (13) the product of (8) is dispersed in a polyamide spinning melt; (14) the product of (9) is mixed with a solution of polyacrylonitrile in dimethyl-formamide and formed into a film. Specification 687,481, [Group IV (a)], is referred to.ALSO:Pigment preparations comprising a pigment in fine dispersion in an organic substance are made by subjecting a pigment to a mechanical treatment producing a shearing or kneading action in an organic medium having a viscosity of at least 10 centipoises at 20 DEG C., or in a melt of an organic medium which is solid at 20 DEG C., in presence of a grinding body constituting at least one fifth of the weight of pigment which is subsequently washed out, and when the organic medium is a thermoplastic water-insoluble film-forming substance having a capacity for water-imbibition similar to cellulose acetate and a compact substantially dry solid complex containing water-soluble salts and pigment is formed and said complex is subjected to aqueous extraction, using the grinding body in an amount at least equal to the amount of dyestuff present. The pigment may be inorganic, e.g. carbon black or phthalocyanines. The organic medium may be (1) an animal, vegetable or mineral oil, or a plasticizer, such as dibutyl phthalate; or (2) it may be a solution of a solid substance, e.g. a natural or artificial resin, rubber or a rubber derivative, or a cellulose derivative, in a comparatively low-boiling organic solvent such as toluene; or (3) a melt of colophony. Grinding bodies comprise inorganic salts such as sodium, potassium, or barium chlorides, or sodium sulphate, and organic compounds such as urea. They may be removed by washing with water or an organic solvent. In the case of organic media (2) above, the extracting solvent may be miscible with the organic solvent, but if not, the latter may be removed by evaporation before or after extraction. The products colour lacquers, oily coating compositions, artificial substances, and especially spinning solutions, e.g. of cellulose acetate, nylon, superpolyurethanes, polyacrylonitriles, terephthalic acid glycol poly-esters, polyvinyl compounds or polyvinyl-polyacrylic copolymers. In examples: (1) reprecipitated or crude copper phthalocyamine (which may be chlorinated) or the dyestuff 2-methyl-4-chloro-1-aminobenzene --> 1 - (21 - oxy - 31 - naphthoyl) amino - 2-methyl-4-chloro-benzene is kneaded with a glycerine ester of hydrogenated colophony and with toluene and sodium chloride; (2) 4,41-dimethyl-6.61-dichloro-thioindigo is kneaded with dibutyl phthalate and sodium chloride; (3) indigo is kneaded with a glycerine ester of hydrogenated colophony, sodium carbonate, and toluene; (4) the dye 2.5-dichloro-1-aminobenzene --> 1 - (21 - oxy - 31 - naphthoyl) - amino-2.5-dimethoxybenzene is kneaded with sodium chloride, toluene, and either ethyl cellulose or chlorinated rubber; (5) reprecipitated copper phthalocyanine is kneaded with acetyl cellulose, sodium chloride, and glycol monomethyl ether; (6) the dye 2-methyl-4-chloro-1-aminobenzene 1 - (21 - oxy - 31 - napthoyl) - amino - 2 - methyl-4 - chlorbenzene is kneaded with acetyl cellulose, ammonium chloride, and glycol monomethyl ether, or with sodium chloride and colophony; (7) gas black is kneaded with acetyl cellulose, urea and acetone; (8) chlorinated copper phthalocyanine is kneaded with sodium chloride and a solution of nylon in formic acid; (9) dihydro-anthraquinone 1.2.21.11-azine is kneaded with sodium chloride and a solution of polyacrylonitrile in dimethyl-formamide; (10) chlorinated copper, phthalocyanine is kneaded with a glycerine ester of hydrogenated colophony, sodium chloride and diacetone alcohol. Further examples describe applications of the above, viz. (11) the product of (2) is mixed with polyvinyl chloride and dioctyl phthalate to give a coloured foil; (12) the product of (1) is mixed with an alkyd resin lacquer, and the product of (5) with butyl acetate and a nitrocellulose lacquer; (13) the product of (5) is added to a cellulose acetate spinning solution consisting of acetyl cellulose and acetone; (14) the product of (8) is dispersed in a polyamide spinning melt; (15) the product of (9) is mixed with a solution of polyacrylonitrile in dimethyl-formamide and formed into a film. Specification 687,481, [Group IV (a)], is referred to.ALSO:Pigment preparations comprising a pigment in fine dispersion in an organic substance are made by subjecting a pigment to a mechanical treatment producing a shearing or kneading action in an organic medium having a viscosity of at least 10 centiposes at 20 DEG C., or in a melt of an organic medium which is solid at 20 DEG C., in presence of a grinding body (constituting at least one fifth of the weight of pigment) which is subsequently washed out, and when the organic medium is a thermoplastic water-insoluble film-forming substance having a capacity for water-imbibition similar to cellulose acetate and a compact substantially dry solid complex containing water-soluble salts and pigment is formed and said complex is subjected to aqueous extraction, using the grinding body in an amount at least equal to the amount of dyestuff present. The pigment may be inorganic, e.g. carbon black, or organic, e.g. azo dyes or phthalocyanines. The organic medium may be (1) an animal, vegetable or mineral oil, or a plasticizer, such as dibutyl phthalate; or (2) it may be a solution of a solid substance, e.g. a natural or artificial resin, rubber or a rubber derivative, or a cellulose derivative, in a comparatively low-boiling organic solvent such as toluene; or (3) a melt of colophony. Grinding bodies comprise inorganic salts such as sodium, potassium or barium chlorides, or sodium sulphate, and organic compounds such as urea. They may be removed by washing with water or an organic solvent. In the case of organic media (2) above, the extracting solvent may be miscible with the organic solvent, but if not, the latter may be removed by evaporation before or after extraction. The products colour lacquers, oily coating compositions,
GB18588/53A 1952-07-04 1953-07-03 Pigment preparations, their manufacture and use Expired GB780316A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH780316X 1952-07-04

Publications (1)

Publication Number Publication Date
GB780316A true GB780316A (en) 1957-07-31

Family

ID=4536153

Family Applications (1)

Application Number Title Priority Date Filing Date
GB18588/53A Expired GB780316A (en) 1952-07-04 1953-07-03 Pigment preparations, their manufacture and use

Country Status (1)

Country Link
GB (1) GB780316A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108250819A (en) * 2018-02-09 2018-07-06 上海马利画材销售有限公司 A kind of Chinese painting color and preparation method thereof and purposes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108250819A (en) * 2018-02-09 2018-07-06 上海马利画材销售有限公司 A kind of Chinese painting color and preparation method thereof and purposes
CN108250819B (en) * 2018-02-09 2020-05-01 上海马利画材销售有限公司 Traditional Chinese painting pigment and preparation method and application thereof

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