GB776102A - Improvements in or relating to the manufacture of catalysts containing molybdenum - Google Patents

Improvements in or relating to the manufacture of catalysts containing molybdenum

Info

Publication number
GB776102A
GB776102A GB16703/55A GB1670355A GB776102A GB 776102 A GB776102 A GB 776102A GB 16703/55 A GB16703/55 A GB 16703/55A GB 1670355 A GB1670355 A GB 1670355A GB 776102 A GB776102 A GB 776102A
Authority
GB
United Kingdom
Prior art keywords
alumina
silica
zirconia
hydrogen
magnesia
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16703/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Publication of GB776102A publication Critical patent/GB776102A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16Clays or other mineral silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20Sulfiding

Abstract

Reforming treatments of hydrocarbons in the presence of hydrogen such as paraffin hydrocracking and cyclization and naphthene dehydrogenation at temperatures from 427-593 DEG C. and pressures of 6.8-136 atmospheres in the presence of hydrogen of molar ratio to hydrocarbon of 0.5-10:1 are carried out using a molybdenum catalyst supported on an inorganic oxide. The catalyst is made by calcining the support; hydrating to a moisture content of 1-10 per cent by weight; impregnating with an acidic solution containing molybdenum and finally drying and calcining.ALSO:An inorganic oxide support, preferably alumina, is calcined; hydrated to a moisture content of 1 to 10, preferably 3-8, per cent by weight, e.g. by exposing to an atmosphere containing water vapour; impregnated with an acidic solution containing molybdenum and finally dried and calcined. A wetting agent may be used in the hydration of the support. Regeneration may be achieved with oxygen or hydrogen. Other elements which may be incorporated into the catalyst are:-iron, cobalt, nickel, sulphur, fluorine, chlorine or other halogens. Catalytic supports exemplified are:-silica magnesia, zirconia titania hafnia thoria and zinc oxide; composites such as silica-alumina, silica-zirconia, silica-alumina-zirconia, silica-magnesia, silica-alumina-magnesia, alumina-zinc oxide, alumina-zirconia, alumina-titania and zinc oxide-zirconia, naturally occurring oxides such as felspar, bauxite, kaolin, fuller's earth, kieselguhr, montmorrillonite, bentonite and attapulgus clay. The catalysts are used for the purification of hydrogen fractions, e.g. cracked naphthas.
GB16703/55A 1954-06-16 1955-06-10 Improvements in or relating to the manufacture of catalysts containing molybdenum Expired GB776102A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US776102XA 1954-06-16 1954-06-16

Publications (1)

Publication Number Publication Date
GB776102A true GB776102A (en) 1957-06-05

Family

ID=22139069

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16703/55A Expired GB776102A (en) 1954-06-16 1955-06-10 Improvements in or relating to the manufacture of catalysts containing molybdenum

Country Status (2)

Country Link
FR (1) FR1148436A (en)
GB (1) GB776102A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3213040A (en) * 1962-04-18 1965-10-19 Chemetron Corp Method of preparing an extended catalyst composition consisting of cobalt oxide, molybdenum oxide and alumina
US3280041A (en) * 1961-03-03 1966-10-18 American Cyanamid Co Method of preparing a platinum on alumina reforming catalyst composition
FR2473542A1 (en) * 1980-01-12 1981-07-17 Jgc Corp PROCESS FOR DESULFURING AND REFINING HYDROCARBON FRACTIONS CONTAINING IMPORTANT QUANTITIES OF AROMATIC CONSTITUENTS

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3280041A (en) * 1961-03-03 1966-10-18 American Cyanamid Co Method of preparing a platinum on alumina reforming catalyst composition
US3213040A (en) * 1962-04-18 1965-10-19 Chemetron Corp Method of preparing an extended catalyst composition consisting of cobalt oxide, molybdenum oxide and alumina
FR2473542A1 (en) * 1980-01-12 1981-07-17 Jgc Corp PROCESS FOR DESULFURING AND REFINING HYDROCARBON FRACTIONS CONTAINING IMPORTANT QUANTITIES OF AROMATIC CONSTITUENTS

Also Published As

Publication number Publication date
FR1148436A (en) 1957-12-09

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