GB763986A - New ethylene derivatives and compositions containing the same - Google Patents

New ethylene derivatives and compositions containing the same

Info

Publication number
GB763986A
GB763986A GB936054A GB936054A GB763986A GB 763986 A GB763986 A GB 763986A GB 936054 A GB936054 A GB 936054A GB 936054 A GB936054 A GB 936054A GB 763986 A GB763986 A GB 763986A
Authority
GB
United Kingdom
Prior art keywords
dichloro
substituted
ethylenes
benzyl
carboxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB936054A
Inventor
Jean Metivier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc SA
Original Assignee
Rhone Poulenc SA
Societe des Usines Chimiques Rhone Poulenc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc SA, Societe des Usines Chimiques Rhone Poulenc SA filed Critical Rhone Poulenc SA
Priority to GB936054A priority Critical patent/GB763986A/en
Priority to ES0220952A priority patent/ES220952A1/en
Publication of GB763986A publication Critical patent/GB763986A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00Sulfones; Sulfoxides
    • C07C317/14Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00Sulfones; Sulfoxides
    • C07C317/16Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C317/22Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises compounds of the formula Ar-CnH2n-X-CCl = CHCl, where Ar is an aryl radical, which may be substituted by halogen, alkyl, alkoxy, carboxy, nitro or other groups, n = 0-3, and X is SO or SO2, and insecticidal or fungicidal compositions containing the compounds. The products are obtainable by oxidation of the corresponding sulphides. In examples, 1 : 2 - dichloro - 1 - phenylthioethylene and the corresponding p-chlorophenyl- and p-bromophenyl derivatives, the corresponding p-methyl-, p-isopropyl-, p-methoxy-, and p-ethoxy-phenylthioethylenes are each oxidized in two stages, with hydrogen peroxide in acetic acid solution to give the 1 : 2-dichloro-1-phenyl- or substituted phenylsulphinyl- or sulphonyl-ethylenes; the phenyl groups may also be substituted by two chlorines, and by one carboxy group; 1 : 2-dichloro-1-(b -naphthyl sulphinyl)-ethylene, and 1 : 2-dichloro-1 - benzyl - and - 1 - p - chlorobenzyl - sulphonyl-ethylenes and the corresponding sulphinyl products, are also described. Starting materials. 1 : 2 - Dichloro - 1 - (41 - alkoxyphenylthio) ethylenes are obtained by condensation of trichloroethylene and p-alkoxythiophenols. Methyl, carboxy and chloro- and bromo-substituted phenyl and benzyl-thioethylene derivatives of similar type are obtained by the reaction between the corresponding thiophenols or benzyl mercaptans with trichloroethylene, and a corresponding b -naphthyl derivative from b -thionaphthol.
GB936054A 1954-03-30 1954-03-30 New ethylene derivatives and compositions containing the same Expired GB763986A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB936054A GB763986A (en) 1954-03-30 1954-03-30 New ethylene derivatives and compositions containing the same
ES0220952A ES220952A1 (en) 1954-03-30 1955-03-29 New ethylene derivatives and compositions containing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB936054A GB763986A (en) 1954-03-30 1954-03-30 New ethylene derivatives and compositions containing the same

Publications (1)

Publication Number Publication Date
GB763986A true GB763986A (en) 1956-12-19

Family

ID=9870437

Family Applications (1)

Application Number Title Priority Date Filing Date
GB936054A Expired GB763986A (en) 1954-03-30 1954-03-30 New ethylene derivatives and compositions containing the same

Country Status (2)

Country Link
ES (1) ES220952A1 (en)
GB (1) GB763986A (en)

Also Published As

Publication number Publication date
ES220952A1 (en) 1955-09-16

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