GB763986A - New ethylene derivatives and compositions containing the same - Google Patents
New ethylene derivatives and compositions containing the sameInfo
- Publication number
- GB763986A GB763986A GB936054A GB936054A GB763986A GB 763986 A GB763986 A GB 763986A GB 936054 A GB936054 A GB 936054A GB 936054 A GB936054 A GB 936054A GB 763986 A GB763986 A GB 763986A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dichloro
- substituted
- ethylenes
- benzyl
- carboxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/14—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
- C07C317/22—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises compounds of the formula Ar-CnH2n-X-CCl = CHCl, where Ar is an aryl radical, which may be substituted by halogen, alkyl, alkoxy, carboxy, nitro or other groups, n = 0-3, and X is SO or SO2, and insecticidal or fungicidal compositions containing the compounds. The products are obtainable by oxidation of the corresponding sulphides. In examples, 1 : 2 - dichloro - 1 - phenylthioethylene and the corresponding p-chlorophenyl- and p-bromophenyl derivatives, the corresponding p-methyl-, p-isopropyl-, p-methoxy-, and p-ethoxy-phenylthioethylenes are each oxidized in two stages, with hydrogen peroxide in acetic acid solution to give the 1 : 2-dichloro-1-phenyl- or substituted phenylsulphinyl- or sulphonyl-ethylenes; the phenyl groups may also be substituted by two chlorines, and by one carboxy group; 1 : 2-dichloro-1-(b -naphthyl sulphinyl)-ethylene, and 1 : 2-dichloro-1 - benzyl - and - 1 - p - chlorobenzyl - sulphonyl-ethylenes and the corresponding sulphinyl products, are also described. Starting materials. 1 : 2 - Dichloro - 1 - (41 - alkoxyphenylthio) ethylenes are obtained by condensation of trichloroethylene and p-alkoxythiophenols. Methyl, carboxy and chloro- and bromo-substituted phenyl and benzyl-thioethylene derivatives of similar type are obtained by the reaction between the corresponding thiophenols or benzyl mercaptans with trichloroethylene, and a corresponding b -naphthyl derivative from b -thionaphthol.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB936054A GB763986A (en) | 1954-03-30 | 1954-03-30 | New ethylene derivatives and compositions containing the same |
ES0220952A ES220952A1 (en) | 1954-03-30 | 1955-03-29 | New ethylene derivatives and compositions containing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB936054A GB763986A (en) | 1954-03-30 | 1954-03-30 | New ethylene derivatives and compositions containing the same |
Publications (1)
Publication Number | Publication Date |
---|---|
GB763986A true GB763986A (en) | 1956-12-19 |
Family
ID=9870437
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB936054A Expired GB763986A (en) | 1954-03-30 | 1954-03-30 | New ethylene derivatives and compositions containing the same |
Country Status (2)
Country | Link |
---|---|
ES (1) | ES220952A1 (en) |
GB (1) | GB763986A (en) |
-
1954
- 1954-03-30 GB GB936054A patent/GB763986A/en not_active Expired
-
1955
- 1955-03-29 ES ES0220952A patent/ES220952A1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
ES220952A1 (en) | 1955-09-16 |
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