GB759346A - A process for the preparation of basic products containing polyvalent metals - Google Patents

A process for the preparation of basic products containing polyvalent metals

Info

Publication number
GB759346A
GB759346A GB31202/54A GB3120254A GB759346A GB 759346 A GB759346 A GB 759346A GB 31202/54 A GB31202/54 A GB 31202/54A GB 3120254 A GB3120254 A GB 3120254A GB 759346 A GB759346 A GB 759346A
Authority
GB
United Kingdom
Prior art keywords
alkyl
acids
water
polyvalent metal
xylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31202/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB759346A publication Critical patent/GB759346A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/414—Preparation of superbasic salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1828—Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/028—Overbased salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26—Overbased carboxylic acid salts
    • C10M2207/262—Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/101—Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/14—Group 7
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/16—Groups 8, 9, or 10
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)

Abstract

Basic polyvalent metal salts of aromatic hydroxycarboxylic acids or mixtures thereof with polyvalent metal phenolates are prepared by dissolving alkali-metal salts of aromatic hydroxycarboxylic acids, or mixtures thereof with alkali-metal phenolates, in an organic liquid which forms an azeotrope with water, adding an aqueous alkali-metal hydroxide solution containing at least 0.5 gm. mols. of hydroxide per gm. mol. of aromatic acid salt, heating to remove the water by azeotropic distillation, adding an aqueous inorganic polyvalent metal salt solution and removing the water by azeotropic distillation. The aromatic hydroxycarboxylic acids may be mono- or poly-nuclear carboxylic acids containing a phenolic hydroxy group, such as hydroxycarboxylic acids of benzene, naphthalene or diphenyl, in which the carboxylic group may be in a sidechain or nucleus and wherein the acids may contain further substituents in the sidechain or nucleus such as carboxylic, hydroxyl, halogen, amino, nitro or hydrocarbon. Specified acids and phenols are alkyl salicylic acids and alkyl phenols containing one or more alkyl groups of from 8 to 20 carbon atoms. Suitable mixtures of alkyl salicylic acids and alkyl phenols may be prepared by reacting alkyl phenols with carbon dioxide by the Kolke-Schmitt method using the modifications described in Specification 734,598. Organic azeotroping liquids specified are xylene, benzene, toluene and gasoline of b.p. 120-140 DEG C. Alkalimetal hydroxides specified are sodium and potassium hydroxides. Specified polyvalent metal salts are chlorides and nitrates of calcium, magnesium, zinc and cobalt, used in aqueous concentrations of 10 per cent to 30 per cent by weight and in quantities at least equivalent to the alkali metal content of the reaction mixture. After the second azeotropic distillation, the inorganic salts formed such as sodium chloride are removed by filtration or by extraction with water, an aliphatic alcohol of 1 to 3 carbon atoms or with a mixture of both. After replacing the xylene with lubricating oil, the products may be used as lubricating oil and anti-corrosion agent additives (see Group III). In an example, sodium alkyl phenolates containing alkyl groups of from 14 to 18 carbon atoms are carboxylated with carbon dioxide, treated with sodium hydroxide solution, recarboxylated and xylene added when the solution is treated with aqueous sodium hydroxide and the water removed by azeotropic distillation, filtered and aqueous calcium chloride added, the water azeotroped off, the residue filtered and lubricating oil added followed by xylene removal by steam distillation to obtain the product. Specification 729,376 also is referred to.ALSO:Lubricating oils and corrosion inhibitors are described containing additives which comprise polyvalent metal salts of aromatic hydroxycarboxylic acids or mixtures thereof with polyvalent metal phenolates prepared by dissolving alkalimetal salts of aromatic hydroxycarboxylic acids, or mixtures thereof with alkalimetal phenolates, in an organic liquid which forms an azeotrope with water, adding an aqueous alkali metal hydroxide solution containing at least 0.5 gm. moles of hydroxide per gm. mole of aromatic acid salt, removing the water by azeotropic distillation, adding an aqueous inorganic polyvalent metal salt solution and again removing the water by azeotropic distillation. The aromatic hydroxycarboxylic acid may be a mono- or polynuclear acid containing a phenolic hydroxy group; the carboxylic group may be in a side chain or nucleus and the acids may contain further substituents such as carboxylic, hydroxy, amino, nitro or hydrocarbon groups or halogen. Specified acids and phenols are alkyl salicylic acids and alkyl phenols containing one or more alkyl groups of from 8 to 20 carbon atoms. The additives are used in the lubricating oils in amounts of from 0.1 per cent to 15 per cent by weight and may be used in mineral lubricating oils, synthetic lubricating oils, lubricating oils containing fatty oils, lubricating greases and in light hydrocarbon mixtures used as anti-corrosion agents. The may be used in conjunction with detergents such as alkaline earth metal compounds of alkyl phenol-formaldehyde condensation products or alkaline earth metal salts of oil-soluble petroleum sulphonic acids, with antioxidants such as alkyl phenols and arylamines, and with other corrosion inhibitors and extreme pressure dopes. An example describes the preparation of an additive using calcium as polyvalent metal and di- and mono-sodium alkyl salicylates and alkyl phenols comprising mono- and di-alkyl compounds with alkyl groups of 14-18 carbon atoms; the xylene solution of the product is blended with a mineral lubricating oil and the xylene removed by steam distillation. Specifications 729,376 and 734,598 [Group IV(b)] are referred to.
GB31202/54A 1953-10-30 1954-10-28 A process for the preparation of basic products containing polyvalent metals Expired GB759346A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL759346X 1953-10-30

Publications (1)

Publication Number Publication Date
GB759346A true GB759346A (en) 1956-10-17

Family

ID=19825376

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31202/54A Expired GB759346A (en) 1953-10-30 1954-10-28 A process for the preparation of basic products containing polyvalent metals

Country Status (5)

Country Link
BE (1) BE532896A (en)
DE (1) DE1035156B (en)
FR (1) FR1120071A (en)
GB (1) GB759346A (en)
NL (1) NL81615C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0351052A2 (en) * 1988-06-14 1990-01-17 Bp Chemicals (Additives) Limited A process for the production of a lubricating oil additive concentrate

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2252662A (en) * 1938-06-11 1941-08-12 Socony Vacuum Oil Co Inc Metal salts of alkyl substituted hydroxyaromatic carboxylic acids
GB586526A (en) * 1944-06-29 1947-03-21 Bataafsche Petroleum Improvements in or relating to the manufacture of salts of di-isopropyl-salicylic acid
US2646402A (en) * 1950-02-11 1953-07-21 Texas Co Manufacture of zinc salts of high molecular weight alkylated hydroxy aromatic compounds

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0351052A2 (en) * 1988-06-14 1990-01-17 Bp Chemicals (Additives) Limited A process for the production of a lubricating oil additive concentrate
EP0351052A3 (en) * 1988-06-14 1990-05-23 Bp Chemicals (Additives) Limited A process for the production of a lubricating oil additive concentrate
US5451331A (en) * 1988-06-14 1995-09-19 Bp Chemicals (Additives) Limited Process for the production of a lubricating oil additive concentrate

Also Published As

Publication number Publication date
DE1035156B (en) 1958-07-31
NL81615C (en)
BE532896A (en)
FR1120071A (en) 1956-06-29

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