GB751508A - Process for the production of hydrogen peroxide and the hydrogen peroxide so produced - Google Patents
Process for the production of hydrogen peroxide and the hydrogen peroxide so producedInfo
- Publication number
- GB751508A GB751508A GB442554A GB442554A GB751508A GB 751508 A GB751508 A GB 751508A GB 442554 A GB442554 A GB 442554A GB 442554 A GB442554 A GB 442554A GB 751508 A GB751508 A GB 751508A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- hydrogen peroxide
- heavy metal
- alcohol
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/026—Preparation from organic compounds from alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Catalysts (AREA)
Abstract
In the production of hydrogen peroxide by the oxidation with oxygen of a secondary alcohol according to the process of Specification 708,339, there is added to the alcohol undergoing oxidation (a) a heavy metal salt soluble therein in an amount such that the total concentration of heavy metal in the alcohol does not exceed 0.001 per cent of the alcohol and (b) a sequestrative hydrogen peroxide stabilizer in an amount at least equivalent to the total amount of heavy metal present. The heavy metal may be a metal of groups V-VIII of the Periodic Table e.g. cobalt, iron, chromium, manganese, nickel or vanadium and may be in the form of its chloride, sulphate, nitrate, carbonate, acetate, propionate, butyrate, laurate naphthenate, benzoate, acetylacetonate, isovalerylacetonate or butyrylacetonate. The stabilizer may be an alkali metal salt of an oxy acid of tin, antimony, silicon or aluminium, e.g. sodium stannate, aluminate, silicate, or meta-stannate, or a hydrous oxide thereof, e.g. aquo-stannic acid (H2Sn(OH)6) alpha-meta-stannic acid, hydrous antimony oxide, freshly precipitated alumina, or silica acid hydrosol, or an oxyacid of phosphorus e.g. ortho phosphoric acid or pyrophosphoric acid, or a salt thereof, e.g. sodium pyrophosphate. trisodium orthophosphate, disodium monohydrogen orthophosphate, sodium dihydrogen orthophosphate, potassium dihydrogen orthophosphate or sodium hexametaphosphate. Up to 0.05 per cent or more of stabilizer based on the reaction mixture, preferably about 0.01 per cent, may be employed. Specification 731,238 is also referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB442554A GB751508A (en) | 1954-02-15 | 1954-02-15 | Process for the production of hydrogen peroxide and the hydrogen peroxide so produced |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB442554A GB751508A (en) | 1954-02-15 | 1954-02-15 | Process for the production of hydrogen peroxide and the hydrogen peroxide so produced |
Publications (1)
Publication Number | Publication Date |
---|---|
GB751508A true GB751508A (en) | 1956-06-27 |
Family
ID=9776951
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB442554A Expired GB751508A (en) | 1954-02-15 | 1954-02-15 | Process for the production of hydrogen peroxide and the hydrogen peroxide so produced |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB751508A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4897252A (en) * | 1989-01-10 | 1990-01-30 | Arco Chemical Technology, Inc. | Production of hydrogen peroxide |
WO2008059182A1 (en) * | 2006-11-16 | 2008-05-22 | Arkema France | Method for producing ketones |
-
1954
- 1954-02-15 GB GB442554A patent/GB751508A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4897252A (en) * | 1989-01-10 | 1990-01-30 | Arco Chemical Technology, Inc. | Production of hydrogen peroxide |
WO2008059182A1 (en) * | 2006-11-16 | 2008-05-22 | Arkema France | Method for producing ketones |
FR2908765A1 (en) * | 2006-11-16 | 2008-05-23 | Arkema France | PROCESS FOR PRODUCING KETONES |
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