GB749550A - Neutral aliphatic phosphites - Google Patents
Neutral aliphatic phosphitesInfo
- Publication number
- GB749550A GB749550A GB31566/53A GB3156653A GB749550A GB 749550 A GB749550 A GB 749550A GB 31566/53 A GB31566/53 A GB 31566/53A GB 3156653 A GB3156653 A GB 3156653A GB 749550 A GB749550 A GB 749550A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reaction
- mixture
- ester
- aqueous phase
- complete
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 aliphatic phosphites Chemical class 0.000 title abstract 2
- 230000007935 neutral effect Effects 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- 239000008346 aqueous phase Substances 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract 2
- 239000011574 phosphorus Substances 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical class CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 abstract 1
- GPWHDDKQSYOYBF-UHFFFAOYSA-N ac1l2u0q Chemical compound Br[Br-]Br GPWHDDKQSYOYBF-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229960004592 isopropanol Drugs 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 abstract 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 abstract 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 abstract 1
- WRTMQOHKMFDUKX-UHFFFAOYSA-N triiodide Chemical compound I[I-]I WRTMQOHKMFDUKX-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/142—Esters of phosphorous acids with hydroxyalkyl compounds without further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
Tertiary aliphatic esters of phosphorous acid are obtained by mixing a phosphorus trihalide and an aliphatic alcohol at below about - 20 DEG C., preferably at between - 25 DEG and - 30 DEG C., and after the reaction between them is complete, neutralizing the reaction mixture with ammonia or an organic nitrogenous base containing at least one hydrogen atom attached to the N atom at a temperature below - 20 DEG C. Specified aliphatic alcohols are methanol, ethanol, normal- and iso-propanol, butanols and pentanols and the phosphorus trihalide may be the trichloride, tribromide, or tri-iodide. In an example phosphorus trichloride is added gradually while stirring at - 25 DEG C. to anhydrous ethanol and when the reaction is complete the mixture is neutralized at the same temperature by introducing gaseous ammonia. The ester is isolated by treating the neutralized mixture with water whilst ensuring that the pH of the aqueous phase does not fall below 5. The aqueous phase is then separated from the ester (triethyl phosphite) which can be purified by distillation under reduced pressure.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE749550X | 1952-12-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB749550A true GB749550A (en) | 1956-05-30 |
Family
ID=6649354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB31566/53A Expired GB749550A (en) | 1952-12-04 | 1953-11-13 | Neutral aliphatic phosphites |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB749550A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3036110A (en) * | 1958-08-05 | 1962-05-22 | Bayer Ag | Process for the production of monomeric neutral aliphatic esters of phosphorus having a coordination number of 3 |
| CN103374028A (en) * | 2012-04-18 | 2013-10-30 | 江苏大明科技有限公司 | Preparation method of triethyl phosphate |
-
1953
- 1953-11-13 GB GB31566/53A patent/GB749550A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3036110A (en) * | 1958-08-05 | 1962-05-22 | Bayer Ag | Process for the production of monomeric neutral aliphatic esters of phosphorus having a coordination number of 3 |
| CN103374028A (en) * | 2012-04-18 | 2013-10-30 | 江苏大明科技有限公司 | Preparation method of triethyl phosphate |
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