GB733129A - Process for the manufacture of bis-cyclopentadienyl iron and bis-cyclopentadienyl nickel and of alkyl and aryl derivatives thereof - Google Patents

Process for the manufacture of bis-cyclopentadienyl iron and bis-cyclopentadienyl nickel and of alkyl and aryl derivatives thereof

Info

Publication number
GB733129A
GB733129A GB26796/53A GB2679653A GB733129A GB 733129 A GB733129 A GB 733129A GB 26796/53 A GB26796/53 A GB 26796/53A GB 2679653 A GB2679653 A GB 2679653A GB 733129 A GB733129 A GB 733129A
Authority
GB
United Kingdom
Prior art keywords
bis
alkyl
cyclopentadienyl
iron
nickel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26796/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB733129A publication Critical patent/GB733129A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Bis-cyclopentadienyl iron and nickel and the alkyl and aryl substitution derivatives thereof are prepared by reacting an anhydrous halide of the corresponding metal with cyclopentadienyl sodium or an alkyl or aryl substitution derivative thereof. The reaction may be carried out in a solvent for the metal which is inert to the reaction, e.g. an ether such as diethyl and diamyl ether and anisole, and a tertiary amine such as diethylamine and dimethylaniline. The solvent may be diluted with hydrocarbons such as benzene or a petroleum fraction. The preferred halides are the chlorides and bromides, and a ferric or ferrous halide may be used. In the examples biscyclopentadienyl iron and nickel, bis(n-pentylcyclopentadienyl) iron and bis (2,3,4,5-tetraphenylcyclopentadienyl) iron are prepared. Cyclopentadienyl sodium and the alkyl and aryl substitution derivatives thereof are prepared by reacting cyclopentadiene or the required alkyl or aryl substituted cyclopentadiene with sodium acetylide.
GB26796/53A 1952-10-01 1953-09-30 Process for the manufacture of bis-cyclopentadienyl iron and bis-cyclopentadienyl nickel and of alkyl and aryl derivatives thereof Expired GB733129A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US322243XA 1952-10-01 1952-10-01

Publications (1)

Publication Number Publication Date
GB733129A true GB733129A (en) 1955-07-06

Family

ID=21863765

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26796/53A Expired GB733129A (en) 1952-10-01 1953-09-30 Process for the manufacture of bis-cyclopentadienyl iron and bis-cyclopentadienyl nickel and of alkyl and aryl derivatives thereof

Country Status (3)

Country Link
CH (1) CH322243A (en)
FR (1) FR1083936A (en)
GB (1) GB733129A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7157592B1 (en) 2005-12-30 2007-01-02 Property Development Corporation International Ltd., Inc. Method for producing organo-metallic compounds of cyclopentadiene
WO2009013536A2 (en) 2007-07-20 2009-01-29 Innospec Limited Improvements in or relating to hydrocarbon compositions
EP2287277A1 (en) 2005-07-07 2011-02-23 Innospec Deutschland GmbH Composition
US8870981B2 (en) 2007-01-11 2014-10-28 Innospec Limited Additive fuel composition, and method of use thereof
US9255233B2 (en) 2008-11-26 2016-02-09 Innospec Limited Fuel additive compositions

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB870949A (en) * 1958-12-17 1961-06-21 Ici Ltd Process of manufacture of ferrocene derivatives

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2287277A1 (en) 2005-07-07 2011-02-23 Innospec Deutschland GmbH Composition
US7157592B1 (en) 2005-12-30 2007-01-02 Property Development Corporation International Ltd., Inc. Method for producing organo-metallic compounds of cyclopentadiene
US8870981B2 (en) 2007-01-11 2014-10-28 Innospec Limited Additive fuel composition, and method of use thereof
WO2009013536A2 (en) 2007-07-20 2009-01-29 Innospec Limited Improvements in or relating to hydrocarbon compositions
US8876921B2 (en) 2007-07-20 2014-11-04 Innospec Limited Hydrocarbon compositions
US9255233B2 (en) 2008-11-26 2016-02-09 Innospec Limited Fuel additive compositions

Also Published As

Publication number Publication date
FR1083936A (en) 1955-01-13
CH322243A (en) 1957-06-15

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