GB727989A - Improvements in or relating to the production of benzene polycarboxylic acids or derivatives thereof - Google Patents
Improvements in or relating to the production of benzene polycarboxylic acids or derivatives thereofInfo
- Publication number
- GB727989A GB727989A GB8872/52A GB887252A GB727989A GB 727989 A GB727989 A GB 727989A GB 8872/52 A GB8872/52 A GB 8872/52A GB 887252 A GB887252 A GB 887252A GB 727989 A GB727989 A GB 727989A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxidized
- acid
- methyl
- give
- esterified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Benzene polycarboxylic acids and derivatives thereof are obtained by oxidizing alkyl benzenes and converting the relatively difficulty oxidizable intermediately-formed acids into esters, salts or anhydrides, which are further oxidized with oxygen or gases containing oxygen, by themselves, or in the mixtures containing them. In examples, the catalytic oxidation of methyl p-toluate with or without the catalyst and residue from a previous oxidation, methyl m-toluate, and methyl o-toluate to the corresponding mono-methyl terephthalate, isophthalate, or phthalate, the latter product also containing the acid, anhydride and diester, is described; xylene mixtures are catalytically oxidized, the mixture of acids separated is esterified with methanol, and further oxidized to give among the products mono- and di-methyl terephthalate; lead and other salts of p-toluic acid are oxidized to give isophthalic salts; m-toluic anhydride and p-toluic anhydride oxidized similarly give iso- and terephthalic acids, isolated by converting into their methyl esters; pseudo-cumene is oxidized, the acid product esterified and further oxidized, the process being repeated with the residues, mixed with fresh hydrocarbon, the products being repeatedly esterified, and oxidized to give as a final product trimellitic acid trimethyl ester. The acid oxidation products may be esterified with alcohols of up to 4 carbons, and with aromatic alcohols, especially those which on further oxidation give the same carboxylic acid group as the initial acid; all residues may be re-cycled.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE727989X | 1951-04-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB727989A true GB727989A (en) | 1955-04-13 |
Family
ID=6635583
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8872/52A Expired GB727989A (en) | 1951-04-13 | 1952-04-07 | Improvements in or relating to the production of benzene polycarboxylic acids or derivatives thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB727989A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0721931A1 (en) * | 1995-01-11 | 1996-07-17 | Mitsubishi Gas Chemical Company, Inc. | Process for producing 2,6-naphtalenedicarboxylic acid and ester thereof |
WO2000006530A1 (en) * | 1998-07-28 | 2000-02-10 | Mobil Oil Corporation | A process for producing terephthalic acid and/or dimethyl terephthalate |
-
1952
- 1952-04-07 GB GB8872/52A patent/GB727989A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0721931A1 (en) * | 1995-01-11 | 1996-07-17 | Mitsubishi Gas Chemical Company, Inc. | Process for producing 2,6-naphtalenedicarboxylic acid and ester thereof |
US5587508A (en) * | 1995-01-11 | 1996-12-24 | Mitsubishi Gas Chemical Company, Inc. | Process for producing 2,6-naphthalenedicarboxylic acid and ester thereof |
WO2000006530A1 (en) * | 1998-07-28 | 2000-02-10 | Mobil Oil Corporation | A process for producing terephthalic acid and/or dimethyl terephthalate |
US6133470A (en) * | 1998-07-28 | 2000-10-17 | Mobil Oil Corporation | Integration of p-xylene production and subsequent conversion process |
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