GB716234A - Retention of fillers in textile materials - Google Patents
Retention of fillers in textile materialsInfo
- Publication number
- GB716234A GB716234A GB7085/50A GB708550A GB716234A GB 716234 A GB716234 A GB 716234A GB 7085/50 A GB7085/50 A GB 7085/50A GB 708550 A GB708550 A GB 708550A GB 716234 A GB716234 A GB 716234A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reaction product
- filler
- bisulphite
- materials
- isocyanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 10
- 239000000945 filler Substances 0.000 title abstract 8
- 239000004753 textile Substances 0.000 title abstract 3
- 230000014759 maintenance of location Effects 0.000 title abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 10
- -1 gums Polymers 0.000 abstract 4
- 238000010438 heat treatment Methods 0.000 abstract 4
- 239000012948 isocyanate Substances 0.000 abstract 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 3
- 150000002513 isocyanates Chemical class 0.000 abstract 3
- 150000002540 isothiocyanates Chemical class 0.000 abstract 3
- 239000000243 solution Substances 0.000 abstract 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 abstract 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 229920003086 cellulose ether Polymers 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 2
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 abstract 2
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 abstract 2
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 abstract 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 2
- GWEHVDNNLFDJLR-UHFFFAOYSA-N 1,3-diphenylurea Chemical compound C=1C=CC=CC=1NC(=O)NC1=CC=CC=C1 GWEHVDNNLFDJLR-UHFFFAOYSA-N 0.000 abstract 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 abstract 1
- 229920002125 Sokalan® Polymers 0.000 abstract 1
- 229920002472 Starch Polymers 0.000 abstract 1
- 229920002494 Zein Polymers 0.000 abstract 1
- 229920000615 alginic acid Polymers 0.000 abstract 1
- 235000010443 alginic acid Nutrition 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001409 amidines Chemical class 0.000 abstract 1
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical compound NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 abstract 1
- 230000002421 anti-septic effect Effects 0.000 abstract 1
- 229940064004 antiseptic throat preparations Drugs 0.000 abstract 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 1
- AVMJCTGOPDSBHH-UHFFFAOYSA-N benzenesulfonamide;4-methylbenzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1.CC1=CC=C(S(N)(=O)=O)C=C1 AVMJCTGOPDSBHH-UHFFFAOYSA-N 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 239000005018 casein Substances 0.000 abstract 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 1
- 235000021240 caseins Nutrition 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000012766 organic filler Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000004584 polyacrylic acid Substances 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 239000001103 potassium chloride Substances 0.000 abstract 1
- 235000011164 potassium chloride Nutrition 0.000 abstract 1
- 235000018102 proteins Nutrition 0.000 abstract 1
- 102000004169 proteins and genes Human genes 0.000 abstract 1
- 108090000623 proteins and genes Proteins 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 239000004627 regenerated cellulose Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 abstract 1
- 239000004289 sodium hydrogen sulphite Substances 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical compound N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
- 239000005019 zein Substances 0.000 abstract 1
- 229940093612 zein Drugs 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/11—Isocyanate and carbonate modification of fibers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2965—Cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2971—Impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2762—Coated or impregnated natural fiber fabric [e.g., cotton, wool, silk, linen, etc.]
- Y10T442/277—Coated or impregnated cellulosic fiber fabric
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
In example IV the potassium bisulphite reaction product of phenyl isocyanate is prepared by stirring a mixture of phenyl isocyanate and aqueous sodium bisulphite at 5 DEG C., adding water at 35 DEG C., filtering warm, cooling to 5 DEG C. when diphenyl urea is precipitated and filtered off, and adding potassium chloride to the solution when the potassium bisulphite reaction product is precipitated.ALSO:The retention of hydrophilic, non-fibrous, polymeric organic fillers in fibrous textile materials is improved by applying to the fibrous material a reaction product of an alkali metal bisulphite and an organic isocyanate or isothiocyanate, before, during or after the application of the filler, the materials containing the filler and the reaction product then being heated, e.g., to 100 DEG -200 DEG C. for 1-15 minutes. The filler and the reaction product are preferably applied in the same or different aqueous solution or dispersion. The reaction product may be formed in situ on the material by either applying, in any order, an aqueous solution of the bisulphite and an organic solvent solution of the isocyanate or isothiocyanate, or by applying an emulsion of the isocyanate in an aqueous bisulphite solution, and to any of these liquids the filler may be added. Specified fillers are starches, gums, alginates, cellulose ethers, proteins such as albumen, casein and zein, polyvinyl alcohol, partially hydrolysed polyvinyl acetate and polyacrylic acid and its soluble salts. Loading and delustring agents, e.g., china clay, lithopone, barytes and titanium dioxide may be applied with the filler. The heating operation, which may be combined with a pre-drying step, may be effected with hot air, infra-red radiation, molten metal or steam. Enhanced effects are obtained if the heating step is effected in the presence of an amide, amidine or aminotriazine, e.g., urea, thiourea, acetamide, benzene sulphonamide p-toluene sulphonamide, dicyandiamide, guanidine, amino guanidine and malamine. The treated materials may be subsequently dyed and the filler may act as a mordant for a dye which will normally not dye the materials or which is easily removed therefrom. The treated materials, prior to or simultaneously with the heating step, may have mechanical finishers applied thereto, as described in Specification 716,232, the finishes including mechanically enforced shrinking or stretching by the machines of Specifications 359,759 and 372,803, [both in Group VIII]. Local or pattern effects may be obtained by printing the reaction product on the material, or alternatively by the pre-application of resists or by the subsequent application of a discharge paste prior to the heat treatment. Softening, lubricating and anti-crease agents and antiseptics may be applied to the materials before, after or simultaneously with the reaction product. Reaction products of bisulphites with both aliphatic and aromatic isocyanates and isothiocyanates may be employed, the specified reaction products being those specified in Specification 716,233. The treatment is especially applicable to textile materials of natural or regenerated cellulose, cellulose esters or ethers, wool and natural silk, particularly fabrics or yarns. Numerous examples are given.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE501972D BE501972A (en) | 1950-03-21 | ||
| GB7085/50A GB716234A (en) | 1950-03-21 | 1950-03-21 | Retention of fillers in textile materials |
| US215378A US2710816A (en) | 1950-03-21 | 1951-03-13 | Process for improving retention of fillers in fibrous material |
| FR1042795D FR1042795A (en) | 1950-03-21 | 1951-03-19 | Process for improving the retention of water-sensitive fillers in fibrous materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB7085/50A GB716234A (en) | 1950-03-21 | 1950-03-21 | Retention of fillers in textile materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB716234A true GB716234A (en) | 1954-09-29 |
Family
ID=9826322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7085/50A Expired GB716234A (en) | 1950-03-21 | 1950-03-21 | Retention of fillers in textile materials |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US2710816A (en) |
| BE (1) | BE501972A (en) |
| FR (1) | FR1042795A (en) |
| GB (1) | GB716234A (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE501793A (en) * | 1950-03-10 | |||
| US2923594A (en) * | 1958-05-29 | 1960-02-02 | Ethicon Inc | Method of tanning |
| US3011861A (en) * | 1959-03-26 | 1961-12-05 | Kurashiki Rayon Co | Wet spinning polyvinyl alcohol process |
| US3103437A (en) * | 1959-04-10 | 1963-09-10 | Hardening | |
| US3233962A (en) * | 1966-01-25 | 1966-02-08 | Dennison Mfg Co | Method of treating cellulose fibers and composition resulting therefrom |
| AU499789B2 (en) * | 1973-04-16 | 1979-05-03 | Commonwealth Scientific And Industrial Research Organisation | (poly)carbamoyl sulphonate containing composition |
| US4194024A (en) * | 1973-12-24 | 1980-03-18 | Hoechst Aktiengesellschaft | Method of making hydrophilic articles of water-insoluble polymers |
| US4186238A (en) * | 1973-12-24 | 1980-01-29 | Hoechst Aktiengesellschaft | Hydrophilic articles of water-insoluble polymers |
| DE2414470B2 (en) * | 1974-03-26 | 1977-01-13 | Bayer Ag, 5090 Leverkusen | Aqueous solution of a bisulfite-blocked polyisocyanate prepolymer |
| US4144268A (en) * | 1976-02-11 | 1979-03-13 | Commonwealth Scientific And Industrial Research Organization | Preparation of bisulphite adducts of biruet-polyisocyanates |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB189708042A (en) * | 1897-03-29 | 1898-03-12 | Alexander Mitscherlich | Process for the Manufacture of Glutinous Substances or Sizes. |
| US2123562A (en) * | 1934-10-12 | 1938-07-12 | Ici Ltd | Treating textile materials and articles made therefrom |
| US2305006A (en) * | 1939-02-08 | 1942-12-15 | Robert S Holt | Method of delustering textile material and resulting product |
| BE440404A (en) * | 1940-01-31 | |||
| US2430479A (en) * | 1941-07-23 | 1947-11-11 | Du Pont | Bonding of laminates by means of isocyanates |
-
0
- BE BE501972D patent/BE501972A/xx unknown
-
1950
- 1950-03-21 GB GB7085/50A patent/GB716234A/en not_active Expired
-
1951
- 1951-03-13 US US215378A patent/US2710816A/en not_active Expired - Lifetime
- 1951-03-19 FR FR1042795D patent/FR1042795A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US2710816A (en) | 1955-06-14 |
| BE501972A (en) | 1900-01-01 |
| FR1042795A (en) | 1953-11-03 |
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